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Preparation method of graphene oxide coating metal laminated composite material

A composite material, graphene technology, applied in metal layered products, chemical instruments and methods, coatings, etc., can solve problems such as complex interface bonding, improve corrosion resistance, structure and function integration, high densification, improve The effect of space utilization

Active Publication Date: 2020-01-10
NORTHWEST INSTITUTE FOR NON-FERROUS METAL RESEARCH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The method obtains a graphene oxide-coated metal layered composite material by sequentially laminating and sintering metal sheets with a graphene oxide coating layer, and the graphene oxide-coated metal layered composite material of the graphene oxide-coated metal layered composite material obtained The layer and the metal sheet are tightly combined, realizing the structure-function integration and high densification of the graphene oxide-coated metal layered composite material, and overcoming the lack of complex interface bonding of conventional sheet-layer structure materials

Method used

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  • Preparation method of graphene oxide coating metal laminated composite material
  • Preparation method of graphene oxide coating metal laminated composite material
  • Preparation method of graphene oxide coating metal laminated composite material

Examples

Experimental program
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Embodiment 1

[0036] This embodiment includes the following steps:

[0037] Step 1. Cut the titanium plate into circular titanium sheets with a thickness of 0.5mm and a diameter of 50mm by wire cutting, and then perform vacuum stress relief annealing treatment; the conditions for the vacuum stress relief annealing treatment are: under the condition of -0.1MPa, heating Keep warm for 4 hours after reaching 550°C;

[0038] Step 2. Put the titanium sheet after the vacuum stress relief annealing treatment in step 1 into the surface treatment solution for pickling for 3 minutes, then place it in acetone and ultrasonicate for 20 minutes at 42° C., and then perform drying treatment; the surface treatment solution It consists of 1mL hydrofluoric acid solution with a mass concentration of 20%, 1.5mL nitric acid solution with a mass concentration of 60%, and 5000mL deionized water;

[0039] Step 3, place the graphene oxide prepared by the Hummers method in the surface treatment solution described in ...

Embodiment 2

[0045] This embodiment includes the following steps:

[0046] Step 1. Cut the TC4 titanium alloy plate into circular TC4 titanium alloy sheets with a thickness of 1 mm and a diameter of 50 mm by wire cutting, and then perform vacuum stress relief annealing treatment; the conditions for the vacuum stress relief annealing treatment are: at -0.1MPa , heated to 570°C and then kept for 3 hours;

[0047] Step 2. Put the TC4 titanium alloy sheet after the vacuum stress relief annealing treatment in step 1 into the surface treatment solution for pickling for 4 minutes, then place it in acetone and ultrasonicate for 30 minutes at 50° C., and then perform drying treatment; the surface The treatment solution is composed of 1.5mL hydrofluoric acid solution with a mass concentration of 20%, 3mL nitric acid solution with a mass concentration of 60%, and 2000mL deionized water;

[0048] Step 3, place the graphene oxide prepared by the Hummers method in the surface treatment solution describ...

Embodiment 3

[0053] This embodiment includes the following steps:

[0054] Step 1. Cut the aluminum sheet into circular aluminum sheets with a thickness of 0.1mm and a diameter of 10mm by wire cutting, and then perform vacuum stress relief annealing treatment; the conditions for the vacuum stress relief annealing treatment are: under the condition of -0.1MPa, heating Keep warm at 400°C for 1 hour;

[0055] Step 2. Put the aluminum sheet after the vacuum stress relief annealing treatment in step 1 into the surface treatment solution for pickling for 3 minutes, then place it in acetone and ultrasonicate for 10 minutes at 30° C., and then perform drying treatment; the surface treatment solution It consists of 1mL hydrofluoric acid solution with a mass concentration of 20%, 1mL nitric acid solution with a mass concentration of 60%, and 1000mL deionized water;

[0056] Step 3, place the graphene oxide prepared by the Hummers method in the surface treatment solution described in step 2 and pick...

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Abstract

The invention discloses a preparation method of a graphene oxide coating metal laminated composite material. The method includes: dripping graphene oxide on the surface of a metal sheet, then carryingout vacuum drying treatment to obtain a metal sheet with a graphene oxide coating, then putting the metal sheet with a graphene oxide coating in a spark plasma sintering furnace, and conducting lamination and sintering treatment sequentially, thus obtaining the graphene oxide coating metal laminated composite material. According to the invention, by conducting lamination and sintering treatment on the metal sheet with a graphene oxide coating in a spark plasma sintering furnace sequentially, the graphene oxide coating and the metal sheet can generate a carbide under high temperature and highpressure conditions, so that the graphene oxide coating and the metal sheet can be tightly combined, thus realizing the structural function integration and high densification of the graphene oxide coating metal laminated composite material, and overcoming the defect of complex interface combination of conventional lamellar structure materials.

Description

technical field [0001] The invention belongs to the technical field of preparation of coatings and heterogeneous structures, and in particular relates to a preparation method of graphene oxide-coated metal layered composite materials. Background technique [0002] Metal materials are an important material basis for the development of human society, and have been widely used in aerospace, biomedicine, marine ships, chemical engineering and other fields. The application in related fields not only requires high specific strength, high specific modulus, good biocompatibility and other properties, but also hopes for higher development in corrosion resistance. [0003] Graphene or graphene oxide is a new type of carbon material with excellent properties. Graphene or graphene oxide has been reported to have ultrahigh strength, excellent corrosion resistance, and excellent biological properties. Therefore, the application of graphene and its derivatives in the fields of anti-corro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B15/01B32B37/06B32B37/10C22F1/02B05D7/14B05D3/10B05D3/04
CPCB05D3/0493B05D3/102B05D7/14B32B15/01B32B37/06B32B37/10B32B2255/06B32B2255/24B32B2307/714C22F1/02
Inventor 董龙龙张于胜霍望图张波卢金文刘跃李亮
Owner NORTHWEST INSTITUTE FOR NON-FERROUS METAL RESEARCH
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