Novel degradable packaging material and preparation method thereof
A packaging material and a new type of technology, applied in the field of degradation, can solve the problems of decreased tensile strength of composite materials, limited improvement of overall degradation performance, holes and grooves, etc., to improve the interface bonding force, increase the crystallization temperature, and reduce the degree of crystallinity. Effect
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[0021] A novel degradable packaging material and a preparation method thereof, comprising the following raw materials: PBAT, polylactic acid (PLA), compatibilizer, lubricant, chain extender, polyalcohol, polyester polymer, and catalyst, the raw materials according to The parts by mass are: 60-65 parts of PBAT, 35-40 parts of polylactic acid (PLA), 1phr of compatibilizer, 1phr of lubricant, 0.5phr of chain extender, 2-4phr of polyalcohol and polyester polymer, 1phr of catalyst ~2phr.
[0022] The lubricant adopts nanoscale lubricants such as PTFE, molybdenum disulfide, and graphite.
[0023] Described polyalcohol, polyester polymer are represented by polyethylene glycol (PEG) and polycaprolactone (PCL), and the weight part of described polyethylene glycol (PEG) and polycaprolactone (PCL) Both are 2 to 4phr.
[0024] The chain extender uses hexamethylene diisocyanate (HDI), and the catalyst uses stannous octoate.
[0025] The compatibilizer is ethylene methyl acrylate grafted...
Embodiment
[0032]Embodiment: Prepare the required raw materials: PBAT, polylactic acid (PLA), compatibilizer, lubricant, chain extender, polyalcohol, polyester polymer, catalyst, and the raw materials are calculated in parts by mass: PBAT60~65 parts , polylactic acid (PLA) 35-40 parts, compatibilizer 1phr, lubricant 1phr, chain extender 0.5phr, polyalcohol, polyester polymer 2-4phr, catalyst 1-2phr, lactic acid is fermented by biological method After making polylactic acid (PLA), blend PBAT and polylactic acid (PLA), and add 0.5 parts of chain extender to PLA / In PBAT blends, or ethylene butyl acrylate grafted glycidyl methacrylate (EBA-GMA), ethylene methyl acrylate grafted glycidyl methacrylate (EMA-GMA) and dibenzoyl peroxide (BPO) is added as a compatibilization modification of PLA / PBAT composite materials, using hexamethylene diisocyanate (HD) as a chain extender, and under the action of the catalyst stannous octoate, the polyester is sealed with -OH or -COOH End treatment, adding ...
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