Method for recycling transparent conductive electrode of organic solar cell

A technology of transparent conductive electrodes and solar cells, which is applied in recycling technology, electronic waste recycling, chemical instruments and methods, etc., can solve the problems of expensive preparation costs and device performance differences, and achieve reduced surface roughness, poor stability, and combination good effect

Active Publication Date: 2020-02-14
CHONGQING UNIV OF ARTS & SCI +1
View PDF8 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, its preparation cost is relatively expensive (for example, indium in ITO is a rare metal, and ITO, FTO, and AZO metal oxide transparent conductive electrodes are usually prepared by magnetron sputtering)
For this reason, people try to replace metal oxide transparen

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for recycling transparent conductive electrode of organic solar cell
  • Method for recycling transparent conductive electrode of organic solar cell
  • Method for recycling transparent conductive electrode of organic solar cell

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0027] Example 1

[0028] A method for recycling and reusing transparent conductive electrodes of organic solar cells is carried out as follows:

[0029] (1) Select the used ITO / ZnO / PBDB-T-2F: IT-4F / MoO 3 The / Ag device is placed in a chloroform solvent and oscillated for 15 minutes under 53KHz ultrasonic conditions to fully remove the active layer PBDB-T-2F:IT-4F and the upper interface layer MoO 3 And the metal top electrode Ag.

[0030] (2) Then place it in a lactic acid solution with a volume concentration of 3%, and oscillate for 15 minutes under 53KHz ultrasonic conditions to remove ZnO and residual Ag on the ITO surface.

[0031] (3) Put the recovered ITO transparent conductive electrode in deionized water containing a small amount of detergent for ultrasonic cleaning for 15 minutes, and then gently rub the transparent conductive electrode to remove impurities such as grease, dust, dirt and ions on the surface; Then place them in deionized water for ultrasonic cleaning for 15 m...

Example Embodiment

[0034] Example 2

[0035] A method for recycling and reusing transparent conductive electrodes of organic solar cells is carried out as follows:

[0036] (1) Select the used FTO / PEDOT:PSS / P3HT:PCBM / LiF / Al device as the object, place it in a chlorobenzene solvent and oscillate for 20 minutes under 53KHz ultrasonic conditions to fully remove the active layer, LiF and Al on the device ;

[0037] (2) Place it in an acetic acid solution with a volume concentration of 5%, oscillate for 15 minutes under 53KHz ultrasonic conditions to remove PEDOT:PSS and residual Al on the FTO surface.

[0038] (3) Put the recovered FTO transparent conductive electrode in deionized water containing a small amount of detergent for ultrasonic cleaning for 15 minutes, and then gently rub the transparent conductive electrode to remove impurities such as grease, dust, dirt and ions on the surface; Then place them in deionized water for ultrasonic cleaning for 10 minutes; then place the recovered conductive glass...

Example Embodiment

[0040] Example 3

[0041] A method for recycling and reusing transparent conductive electrodes of organic solar cells is carried out as follows:

[0042] (1) Select the used ITO / ZnO / CuPc:PCBM / LiF / Al device as the object, place it in a chlorobenzene solvent and vibrate for 20 minutes under 53KHz ultrasonic conditions to fully remove the active layer, LiF and Al on the device;

[0043] (2) Place it in a mixed solution of 1% acetic acid and acetic acid volume, oscillate for 15 minutes under 53KHz ultrasonic conditions, and perform ultrasonic treatment to remove ZnO and residual Al on the ITO surface.

[0044] (3) Put the recovered ITO transparent conductive electrode in deionized water containing a small amount of detergent for ultrasonic cleaning for 10 minutes, and then gently rub the transparent conductive electrode to remove impurities such as grease, dust, dirt and ions on the surface; Then place them in deionized water for ultrasonic cleaning for 15 minutes; then place the recovere...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a method for recycling a transparent conductive electrode of an organic solar cell. The method is characterized by comprising the following steps: putting a waste organic photovoltaic device into an organic solvent to remove a top electrode, an interface material and a photoactive layer of the device; putting the device into a dilute acid solution to remove the residual metal electrode and interface material so as to obtain a recyclable metal oxide type transparent conductive electrode; and preparing an organic photovoltaic device by taking the recyclable metal oxide type transparent conductive electrode as a bottom electrode. According to the method, the metal oxide type transparent conductive electrode is recycled from the used photovoltaic device for multiple times, so that the problems of indium scarcity in ITO and high price are solved, re-preparation of the bottom electrode is avoided, and the material cost and the preparation cost are reduced. Under the same preparation condition, the prepared cell device achieves photoelectric conversion efficiency exceeding that of the device under the first use condition, and the stability of the cell device is notinfluenced.

Description

technical field [0001] The invention belongs to the technical field of organic photovoltaic devices, and in particular relates to a method for recycling transparent conductive electrodes of organic photovoltaic devices. Background technique [0002] As a new type of energy device, polymer solar cells have unique advantages in wet processing, large area and flexibility. Recently, polymer solar cells have made important breakthroughs in energy conversion. It has been reported that the efficiency of such cells has exceeded 16%, reflecting a good application trend. However, compared with commercial silicon-based solar cells, polymer solar cells still have a large gap in terms of photoelectric conversion efficiency, device stability, and service life. Therefore, in order to expand its application, in addition to strengthening the research work in these three aspects, work should also be carried out on the optimization of device preparation and cost control. In traditional polym...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): H01L51/48H01L51/44B09B3/00
CPCB09B3/80H10K71/60H10K30/82Y02E10/549Y02W30/20Y02W30/82
Inventor 胡荣张伟柳红东刘玉荣
Owner CHONGQING UNIV OF ARTS & SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap