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Polymer coating with orange peel like structure and preparation method thereof

A kind of structural polymer and polymer technology, which is applied in the direction of coating, polyurea/polyurethane coating, wax coating, etc., can solve the problems of complex preparation method, poor durability, and limited effect of surface performance improvement, and achieve simple and durable preparation method Good performance and low cost

Active Publication Date: 2020-02-28
BEIHANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem solved by the present invention lies in the poor durability of the anti-icing and anti-fouling coatings in the prior art, the limited effect on improving the surface performance, and the complicated preparation method, so as to provide a kind of anti-icing and anti-fouling coating with good durability and the effect on improving the surface performance. Excellent, easy-to-prepare polymer coatings with orange-peel-like structure

Method used

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  • Polymer coating with orange peel like structure and preparation method thereof
  • Polymer coating with orange peel like structure and preparation method thereof

Examples

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Embodiment 1

[0035] The orange-peel-like structure polymer coating described in this embodiment is prepared from a polymer matrix, a foaming aid, and an oily substance. Wherein, the polymer matrix is ​​polyurethane, and in this embodiment, the polyurethane is prepared from polyurethane TDI prepolymer and polyol. The foaming aid is water, in this embodiment, it is deionized water. The oily substance is formed by mixing liquid paraffin and safflower oil in a weight ratio of 1:1.

[0036] The preparation method of class orange peel structure polymer coating described in the present embodiment is specifically as follows:

[0037] Mix and stir 100 parts of polyurethane TDI prepolymer A component, 83 parts of polyol B component, 2 parts of foaming aid, and 28 parts of oily substance, and then drop-coat it on a clean glass plate to form a film , the thickness of the film layer is about 0.75mm, and it is cured at 20°C for 24h.

[0038] In the polymer coating with an orange peel-like structure p...

Embodiment 2

[0045] The orange-peel-like structure polymer coating described in this embodiment is prepared from a polymer matrix, a foaming aid, and an oily substance. Wherein, the polymer matrix is ​​an epoxy resin. In this embodiment, the epoxy resin is a polyurethane modified epoxy resin, which is catalyzed by dibutyltin dilauric acid, polyether polyol, polyamethylene It is prepared by reacting methyl polyphenyl polyisocyanate with epoxy resin. The foaming aid is formed by mixing water and silicone oil at a weight ratio of 1:2. As a preferred implementation of this embodiment, the silicone oil is AK8882, which has a good effect as a foam stabilizer. The oily substance is formed by mixing normal alkanes with 12 carbon atoms and normal alkanes with 14 carbon atoms in a weight ratio of 1:1.

[0046] The preparation method of class orange peel structure polymer coating described in the present embodiment is specifically as follows:

[0047] Mix 100 parts of polyether polyol, 65 parts of ...

Embodiment 3

[0052] The orange peel-like structure polymer coating described in this embodiment is prepared from a polymer matrix, a curing agent, a foaming aid, and an oily substance. Wherein, the polymer matrix is ​​a phenolic resin. In this embodiment, the phenolic resin is a polyurethane-modified phenolic resin prepared by isocyanate, a polyurethane prepolymer and a phenolic resin. The curing agent is formed by mixing phosphoric acid and benzene methanesulfonic acid in a weight ratio of 1:2. The foaming aid is a mixture of Tween-80 and n-pentane, and the oily substance is safflower oil.

[0053] The preparation method of class orange peel structure polymer coating described in the present embodiment is specifically as follows:

[0054] Add 10 parts of curing agent, 5 parts of Tween-80, 3 parts of n-pentane, 6 parts of isocyanate, polyurethane prepolymer with a mass content of 9%, and 20 parts of safflower oil in 100 parts of phenolic resin, mix and stir evenly Finally, it is drip-coa...

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Abstract

The invention provides a polymer coating with an orange peel like structure. The polymer coating comprises a surface layer, a sponge layer, and a liquid capsule. The surface layer is covered on the surface of the sponge layer. The liquid capsule is arranged in the sponge layer. An oily substance is filled in the liquid capsule. The invention also provides a preparation method of the polymer coating with an orange peel like structure. The oily substance, which is not compatible with the surface layer and the sponge layer, is stored in the liquid capsule; the loss of the oily substance is greatly reduced; the coating can be stably and continuously used, the durability of the coating is good, and in a long term, the coating has a good anti-freeze and anti-fouling effect.

Description

technical field [0001] The invention belongs to the technical field of coating materials, and in particular relates to a polymer coating with an orange peel structure and a preparation method thereof. Background technique [0002] Common citrus peels in daily life are composed of hard epidermis, white sponge layer and tiny oil sacs. When subjected to a certain squeezing force, the sponge layer pushes outward, forming tiny cracks in the epidermis, and sprays out phytotoxic and Antibacterial fragrance oil to protect against predators and bacterial infections. In 2018, Nicholas M et al. studied the micro-jet phenomenon when the orange peel composite layered structure was subjected to twisting force, which inspired potential applications such as drug atomization and bridge self-diagnosis. [0003] In 2014, Wong TS et al., inspired by the predation effect of Nepenthes, locked the lubricating liquid in the porous texture of the micro-nanostructured surface, and constructed a supe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/04C09D163/00C09D161/14C09D179/08C09D183/04C09D5/16C09D7/63C09D7/65C09D191/06C09D191/00C08J9/08C08J9/10C08J9/14C08L75/04C08L63/00C08L61/14C08L79/08C08L83/04C08L91/06C08L91/00C08K5/01
CPCC08J9/0014C08J9/0061C08J9/08C08J9/105C08J9/141C08J2203/02C08J2203/04C08J2203/14C08J2361/14C08J2363/00C08J2375/04C08J2379/08C08J2383/04C08J2483/04C08J2491/00C08J2491/06C08L2205/02C08L2205/025C08L2205/03C09D5/1625C09D5/1637C09D5/1681C09D5/1693C09D161/14C09D163/00C09D175/04C09D179/08C09D183/04C09D7/63C09D7/65C08L91/06C08L91/00C08K5/01C08L83/04
Inventor 杨光朱舒燕
Owner BEIHANG UNIV
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