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Hydroprocessing method and system for low-quality oil

A low-quality oil and hydrogen processing technology, which is applied in the petroleum industry, hydroprocessing process, and hydrocarbon oil treatment, can solve the problems of non-hydroprocessing methods that are difficult to meet the requirements, the yield of refined oil is low, and acid residues are difficult to handle. , to achieve the effect of reduced weight ratio, good quality and short adsorption time

Active Publication Date: 2021-11-16
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Non-hydrogenation treatment mainly adopts acid-base refining, such as patent CN201010520957.0, acid-base refining will not only produce a large amount of acid residue that is difficult to handle, pollute the environment, but also have a low yield of refined oil; although some researchers have explored the use of single solvent or Multi-solvent extraction and refining method, such as patent CN200510114740.9, but there are still shortcomings such as large solvent consumption and high energy consumption
With the improvement of environmental protection requirements, the emission standards for light fuel oil combustion exhaust at home and abroad continue to increase, and the restrictions on the sulfur, nitrogen and aromatic content of light fuel oil for vehicles are lower, so it is very easy to use non-hydrogenation treatment. Difficult to meet

Method used

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  • Hydroprocessing method and system for low-quality oil
  • Hydroprocessing method and system for low-quality oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0101] This example follows figure 1 The flow process of the experiment was carried out, and the shale oil in Table 1 was used as inferior oil, and the test was carried out on a small-scale continuous regeneration double-riser reactor. The bottom of the first riser is injected with 40°C gasoline accounting for 22.5% by weight of the shale oil feed as the cooling medium. The lifting medium flows from bottom to top; after the reaction, the denitrified oil gas enters the second riser, and the second riser is transported into the high-temperature thermal regenerant as the second catalytic cracking catalyst; CAT-1 catalyst is used, and the balancer MAT=65. The specific reaction process is as follows: shale oil A enters the bottom of the first riser reactor after being preheated at 260°C, and at a reaction pressure of 4.3 MPa, H 2 The volume ratio of / shale oil is 500, with the hydrogen-containing fluidized medium flowing from bottom to top, the adsorption temperature is 300°C, the...

Embodiment 2

[0110] This example follows figure 1 The flow process of coking gas oil B and vacuum gas oil C in Table 1 are used as raw materials for catalytic cracking, coking gas oil B is used as inferior oil, and the test is carried out on a small-scale continuous regeneration double riser reactor. The first riser faces hydrogen feed, and the first riser introduces a cold regenerant that takes heat from outside as the first catalytic cracking catalyst, with 85% hydrogen as the pre-lift medium flowing from bottom to top; denitrification after reaction Oil gas and vacuum gas oil C as a high-quality catalytic cracking raw material are fed into the second riser, and the second riser is transported into a high-temperature thermal regenerant as the second catalytic cracking catalyst; CAT-1 catalyst is used, and the balancer MAT=65. The specific reaction process is: the coker wax oil B enters the bottom of the first riser reactor after being preheated at 300 ° C, and under the reaction pressure...

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Abstract

The present invention relates to a method and system for hydrogenation processing of inferior oil, the method comprising: introducing inferior oil into a first riser reactor to contact with a first catalytic cracking catalyst and performing hydrogenation adsorption reaction under the condition of hydrogen-containing gas , the obtained oil agent is separated to obtain the adsorption product and the first spent catalyst; the obtained adsorption product is introduced into the second riser reactor to contact the second catalytic cracking catalyst and carry out the catalytic cracking reaction, and the obtained oil agent is separated to obtain the reaction product and the second catalytic cracking catalyst. Secondary catalyst. The present invention adopts a double-riser reactor to first absorb and remove impurities such as nitrogen-containing compounds of inferior oil and then catalytic cracking, thereby greatly increasing the conversion rate of inferior oil and increasing the yield of liquid products, especially the yield of liquefied gas and gasoline, and reducing dry gas and coke, so as to realize the efficient utilization of petroleum resources.

Description

technical field [0001] The invention relates to a hydroprocessing method and system for inferior oil. Background technique [0002] With the shortage of petroleum resources and the increasing demand for high-quality gasoline, diesel oil and low-carbon olefins, the processing technology of inferior oil such as inferior raw materials, coal liquefied oil, oil sand oil and inferior and heavy petroleum has been paid more and more attention. Inferior raw materials, coal liquefied oil, oil sand oil, etc., are similar to natural petroleum, but contain more unsaturated hydrocarbons than natural petroleum, and contain non-hydrocarbon organic compounds such as nitrogen, sulfur, oxygen, etc., which not only affect their secondary processing and utilization , but also affect the color and stability of gasoline and diesel products, with high sulfur and nitrogen content. At present, except for a small amount of production of chemicals, most of the low-quality oil is directly sold as light...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G69/02
CPCC10G69/02C10G2300/1037C10G2300/1048C10G2300/202C10G2300/70
Inventor 唐津莲张执刚龚剑洪
Owner CHINA PETROLEUM & CHEM CORP