Neodymium-doped bismuth zinc borate self-frequency-doubling crystal material, cut shape and preparation method and application thereof

A technology of neodymium zinc borate and crystal materials, which is applied in the field of laser and nonlinear optics, can solve the problems of inability to directly output green light, low thermal conductivity of crystal materials, and inability to apply high-power devices, and achieve good thermal properties and thermal conductivity. High efficiency and wide application range

Active Publication Date: 2020-05-05
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In view of the current situation that there are few practical laser self-frequency doubling crystals, especially the low thermal conductivity of the current crystal materials, it cannot be used in high-power devices, and the current crystal cut cannot directly output green light. insufficient

Method used

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  • Neodymium-doped bismuth zinc borate self-frequency-doubling crystal material, cut shape and preparation method and application thereof
  • Neodymium-doped bismuth zinc borate self-frequency-doubling crystal material, cut shape and preparation method and application thereof
  • Neodymium-doped bismuth zinc borate self-frequency-doubling crystal material, cut shape and preparation method and application thereof

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Experimental program
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Effect test

Embodiment 1

[0035] a Nd x Bi 2-x ZnB 2 O 7 crystal, where Nd 3+ By replacing Bi 3+ Doping growth, Nd 3+ The doping concentration is 2 mol%. The preparation method includes the following steps:

[0036] (1) The stoichiometric ratio is adopted, and the ingredients are carried out according to the chemical equation:

[0037] (x / 2)Nd 2 O 3 +(1-x / 2)Bi 2 O 3 +ZnO+2H 3 BO 3 =Nd x Bi 2-x ZnB 2 O 7 +3H 2 O

[0038] The prepared raw materials are fully ground, and in order to improve the contact area and uniformity of the raw material particles, the raw materials are put into a mixing bottle for mechanical mixing. After mixing, the raw materials are pressed into a dense cylindrical mass.

[0039] Put the pressed cylindrical block into a clean corundum crucible, and place it in a muffle furnace for high temperature sintering, the sintering temperature is 650 ° C, and the sintering time is more than 10 hours. x Bi 2-x ZnB 2 O 7 Polycrystalline raw material.

[0040] (2) Nd is...

Embodiment 2

[0047] A kind of Nd as described in embodiment 1 x Bi 2-x ZnB 2 O 7 crystal, where Nd 3+ By replacing Bi 3+ Doping growth, the difference is: Nd 3+ The doping concentration is 5 mol%.

Embodiment 3

[0049] A kind of Nd as described in embodiment 1 x Bi 2-x ZnB 2 O 7 crystal, where Nd 3+ By replacing Bi 3+ Doping growth, the difference is: Nd 3+ The doping concentration is 8 mol%.

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Abstract

The invention relates to a neodymium-doped bismuth zinc borate self-frequency-doubling crystal material, a cut shape and a preparation method and application thereof. The growth of NdxBi2-xZnB2O7 crystals with different doping concentrations is carried out by adopting a kyropoulos method and replacing Bi < 3 + > with an activated ion Nd < 3 + >. The invention also provides an application of the NdxBi2-xZnB2O7 crystal, employs semiconductor laser pumping with the central wavelength of 808nm, and the laser and nonlinear optical properties of the NdxBi2-xZnB2O7 crystal are utilized to obtain self-frequency doubling green light output with the output wavelength of 533nm. The laser has the advantages of compact structure, small size, high conversion efficiency, long service life, low cost, highthermal conductivity and the like, and can be used for high-power lasers.

Description

technical field [0001] The invention relates to a neodymium-doped zinc-bismuth borate self-frequency doubling crystal material, a cutting type, a preparation method and application thereof, and belongs to the technical field of laser and nonlinear optics. Background technique [0002] Functional crystalline materials are an important basis for optoelectronic devices. At present, functional crystals are developing in the direction of functionalization, compounding and integration of materials and devices. When two or more functional properties act on the same crystal, a composite functional crystal material is formed. The laser self-frequency doubling crystal is an important composite functional crystal. It uses the nonlinear optical effect of the matrix crystal to convert the stimulated emission of the activated ions into the second harmonic, so that it has the stimulated emission performance of the laser crystal at the same time. And the frequency doubling performance of ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C30B28/02C30B17/00C30B29/22H01S3/16H01S3/109
CPCC30B17/00C30B28/02C30B29/22H01S3/1095H01S3/1666
Inventor 赵显陈菲菲于法鹏姜超樊梦迪田世伟程秀凤
Owner SHANDONG UNIV
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