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Molybdenum-aluminum compatible etching solution and etching method

A technology compatible with etching, molybdenum and aluminum, applied in the field of etching solution, can solve the problems of excessive etching rate of molybdenum on the upper layer, residual material in the back layer, affecting product quality, etc., and achieve smooth etching angle, balanced etching, and easy operation Effect

Inactive Publication Date: 2020-06-12
江苏中德电子材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In actual production, one kind of etching solution is often corresponding to multiple metal film layers at the same time. After the etching is completed, the corresponding slope angle may sometimes be abnormal. For example, the etching rate of the upper metal molybdenum is too fast, resulting in macro defects and subsequent processes. It will produce corresponding optical defects or cause residues in the back layer, which will affect product quality

Method used

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  • Molybdenum-aluminum compatible etching solution and etching method
  • Molybdenum-aluminum compatible etching solution and etching method
  • Molybdenum-aluminum compatible etching solution and etching method

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Embodiment 1

[0026] A kind of molybdenum-aluminum compatible etchant provided by the present invention, according to percentage by weight, measure respectively the phosphoric acid of 60%, the nitric acid of 2.8%, the content of acetic acid is 19%, the content of chloric acid is 3.5%, 4.5g potassium chlorate; 6% Surfactant, wherein the surfactant includes 1.5% cocoic acid monoethanolamide, 1.5% cocoic acid diethanolamide, 1.5% lauryl amidopropyl betaine, 1.5% tricitric acid Butyl ester; 1% metal inhibitors, including 0.4% sodium molybdate, 0.3% sodium tolyltriazole, 0.3% dimercaptothiadiazole disodium salt; 2.5% P-hydroxybenzoic acid additive and the remaining water; add 1 / 3 of the required pure water to the batching tank, add the required amount of nitric acid under stirring, and mix the chloric acid evenly; add it to the mixed solution while stirring Add phosphoric acid and acetic acid and mix evenly, then add 1 / 3 of the required pure water and stir thoroughly; then add surfactants, metal...

Embodiment 2

[0028] The difference between embodiment 2 and the molybdenum-aluminum compatible etching solution of embodiment 1 is that 3% nitric acid, 2% chloric acid, 3g potassium chlorate, comprise 0.4% sodium molybdate, 0.2% methyl Sodium benzotriazole and 0.2% disodium dimercaptothiadiazole; additives are 1.5% p-hydroxybenzoic acid and 1% sodium citrate.

Embodiment 3

[0030] The difference between embodiment 3 and embodiment 1 is that 3% nitric acid, 3% chloric acid, 6g potassium chlorate comprise 0.4% sodium molybdate, 0.4% tolyltriazole sodium in the metal inhibitor and 0.4% dimercaptothiadiazole disodium salt; additives are 1.5% p-hydroxybenzoic acid and 2% sodium citrate.

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Abstract

The invention discloses a molybdenum-aluminum compatible etching solution. The etching solution is prepared from 60%-68% of phosphoric acid, 2.5%-3% of nitric acid, 19%-25% of acetic acid, 2%-5% of chloric acid, 2%-10% of surfactant, 0.8%-1.2% of metal inhibitors, 2%-5% of auxiliary agent and the balance water; and the metal inhibitor comprises at least one of molybdate, sodium methylbenzotriazoleand dimercaptothiodiazole disodium salt. The invention further discloses an etching method. According to the molybdenum-aluminum compatible etching solution, the chloric acid is added, and the etching rate of the molybdenum aluminum is controlled; and the metal inhibitor is added, the ionization balance of the phosphate ion is controlled, and the etching rate of the metal molybdenum is further reduced. The etching method is simple in process, easy to operate and higher in efficiency.

Description

technical field [0001] The invention relates to the technical field of etching solution, in particular to a molybdenum-aluminum compatible etching solution and an etching method. Background technique [0002] In recent years, the liquid crystal display industry has developed rapidly, and the products tend to be large-scale, high-quality, and high-functional. While people's demand for liquid crystal displays continues to increase, higher requirements are placed on product quality and picture accuracy. [0003] In the field of TFT-LCD or LED panels, the aluminum-molybdenum multilayer structure has gradually become the mainstream technology. The technical difficulty of the aluminum-molybdenum etching solution is that the electrochemical properties of aluminum and molybdenum are greatly different, and the oxidation ability is different, that is, there is a big difference in the etching rate. . In actual production, it is often an etching solution that corresponds to multiple m...

Claims

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Application Information

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IPC IPC(8): C23F1/44
CPCC23F1/44
Inventor 戈士勇
Owner 江苏中德电子材料科技有限公司
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