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Rust remover and preparation method and application thereof

A rust remover and polyoxyethylene ether technology, applied in the field of iron and steel rust removal, can solve the problems of low rust removal efficiency, accelerated rust removal efficiency, metal surface corrosion, etc., to improve rust removal efficiency and rust removal speed, waste liquid The effect of reducing the amount of production and increasing the deposition rate

Active Publication Date: 2020-06-26
TIANJIN GONGDA GALVANIZING EQUIP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Exhaust gas, waste liquid, and waste pickling water have caused serious pollution in pickling and rust removal, which is increasingly restricted under the current high pressure of environmental protection
At present, the existing environmentally friendly phosphoric acid rust remover has a very low rust removal efficiency. In order to accelerate the rust removal efficiency, it is necessary to add long-term ultrasonic waves or heat to a high temperature of 50°C, which not only consumes high energy, but also prolongs the treatment time. certain corrosion
[0003] CN105018947A discloses a rust remover, which is made of 17-25% citric acid, 0.5-10% oxalic acid, 15-45% phosphoric acid, 0.5-2% sodium alkylbenzenesulfonate, 0.5-4% emulsified Composed of corrosion inhibitor, 3.5-5.5% corrosion inhibitor and the rest of deionized water, the rust remover has a good rust removal effect on light rust, but it takes a long time to treat scales with heavy rust, and it is easy to Rusty parts damage its surface
This invention will not cause corrosion or other damage to steel, and can eliminate rust on steel. However, to accelerate the efficiency of rust removal, it is necessary to add a long time of ultrasonic or heating to a high temperature of 50°C, which not only consumes high energy, but also prolongs the treatment time. Corrosion to the metal surface

Method used

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  • Rust remover and preparation method and application thereof
  • Rust remover and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] This embodiment provides a rust remover, which includes: 20% phosphoric acid, 5% hypophosphorous acid, 0.4% sodium fluoride, 1% sodium nitrate, 0.8% OP-10, isomerized ten Alcohol polyoxyethylene ether 0.4% and nitric acid 0.6%, the balance is deionized water.

[0048] The preparation method of the rust remover is as follows: according to the formula, phosphoric acid, hypophosphorous acid, sodium fluoride, sodium nitrate, OP-10, isomeric decanol polyoxyethylene ether, nitric acid and water are mixed at 20°C at 400r / min The speed of rotation is mixed and stirred for 20min to prepare the rust remover.

Embodiment 2

[0050] This embodiment provides a rust remover, which includes: 25% phosphoric acid, 3% hypophosphorous acid, 0.6% sodium fluoride, 2% sodium nitrate, 1.0% OP-10, isomerized ten Alcohol polyoxyethylene ether 0.2% and nitric acid 0.4%, the balance is deionized water.

[0051] The preparation method of the rust remover is as follows: according to the formula, phosphoric acid, hypophosphorous acid, sodium fluoride, sodium nitrate, OP-10, isomeric decanol polyoxyethylene ether, nitric acid and water are mixed at 10°C at 600r / min The speed of rotation is mixed and stirred for 10 minutes to prepare the rust remover.

Embodiment 3

[0053] This embodiment provides a rust remover, which includes: 22% phosphoric acid, 4% hypophosphorous acid, 0.5% sodium fluoride, 1.5% sodium nitrate, 0.9% OP-10, isomerized ten Alcohol polyoxyethylene ether 0.3% and nitric acid 0.5%, the balance is deionized water.

[0054] The preparation method of the rust remover is as follows: according to the formula, phosphoric acid, hypophosphorous acid, sodium fluoride, sodium nitrate, OP-10, isomeric decanol polyoxyethylene ether, nitric acid and water are mixed at 30°C at 300r / min The rotating speed, mix and stir 30min, make described rust remover.

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Abstract

The invention provides a rust remover and a preparation method and application thereof. The rust remover comprises the following components in percent by mass: 15-30% of phosphoric acid, 1-10% of hypophosphorous acid, 0.1-5% of sodium salt, 0.1-5% of a compound surfactant and the balance water. The compound surfactant comprises alkylphenol ethoxylates, isomeric alcohol ethoxylate and nitric acid.The rust remover can remove rust efficiently and quickly, is high in rust removal efficiency, short in rust removal time and simple in application method and corrodes a matrix material lightly, and the glossiness of the surface of a product after rust removal is high.

Description

technical field [0001] The invention belongs to the technical field of iron and steel rust removal, and in particular relates to a rust remover and its preparation method and application. Background technique [0002] At present, the rust removal of steel products is mainly hydrochloric acid pickling. Traditional chemical rust removal usually uses strong acid, which can chemically react with rust and metal oxides to generate soluble salts, so as to achieve the purpose of rust removal. While removing rust, the acid can react with the base metal to release hydrogen, hydrogen It can exert pressure on rust and insoluble scale, which is beneficial to their peeling and reduction of high-valent iron, and accelerates the pickling process. However, the traditional acid solution treatment method also has obvious defects. During the pickling process, irritating and corrosive acid gas will be produced; the acid solution will fail due to the rapid increase of iron ions, and waste acid w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23G1/08
CPCC23G1/083
Inventor 曹晓明毕嘉容胡世豪范永哲赵雪
Owner TIANJIN GONGDA GALVANIZING EQUIP CO LTD
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