For efficient catalytic conversion of co 2 The preparation method of the microbial coupled catalytic system
A catalytic system and catalytic conversion technology, applied in the methods of using microorganisms, catalyst activation/preparation, preparation of organic compounds, etc., can solve the problems of inability to meet the requirements of industrialization, slow speed, etc., to relieve environmental pressure, and efficient catalytic conversion. Effect
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Embodiment 1
[0063] A high-efficiency catalytic conversion of CO 2 The preparation method of the microbial coupling catalytic system comprises the steps:
[0064] 1) ferric oxide was dried at 120°C for 12 hours;
[0065] 2) dissolving the auxiliary salt sodium nitrate in the solvent methanol to obtain a sodium nitrate methanol solution;
[0066] 3) Sodium nitrate methanol solution was impregnated on the dried ferric oxide powder, stirred evenly, and dried at 120° C. for 12 hours to obtain a catalyst;
[0067] 4) The catalyst is compressed at 10MPa, and then granulated to 20-40 mesh to obtain the catalyst;
[0068] 5) Load 3.0g of catalyst, first use pure H 2 Carry out reduction, wherein the specific reduction conditions are 350°C and the gas velocity is 4500h -1 (V / V), reduction time 10h, after reduction finishes, catalyst is lowered room temperature with nitrogen;
[0069] 6) Grinding the reduced catalyst to 100 mesh and uniformly mixing with methanogenic microorganisms to obtain a c...
Embodiment 2
[0074] Repeat Example 1, the only difference is: in step S12, the auxiliary salt is potassium nitrate, and the solvent is ethanol; in step 5), the reducing gas is pure CO gas. The selectivity results are shown in Table 2 below.
[0075] Table 2: Catalyst reaction results
[0076] Initial amount / mL Final volume / mL Consumption(mL) / Output(mL) Raw material CO 2 amount
Embodiment 3
[0078] Repeat embodiment 1, its difference is only: in step S12, auxiliary agent salt is lithium nitrate, and solvent is acetone; In step 5), described reducing gas is synthesis gas (H 2 / CO). The selectivity results are shown in Table 3 below.
[0079] Table 3: Catalyst reaction results
[0080] Initial amount / mL Final volume / mL Consumption(mL) / Output(mL) Raw material CO 2 amount
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