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Reversible thermosensitive color-changing transformer early-warning insulating sheath material and preparation method thereof

An insulating sheath, heat-sensitive discoloration technology, applied in the direction of rubber insulators, organic insulators, etc., can solve the problems of poor high and low temperature resistance, easy to decompose, economic losses, etc., achieve good flame retardant effect, adjustable color, considerable economy benefit effect

Inactive Publication Date: 2020-07-10
戴文忠
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the existing transformer sheath materials are poor in high and low temperature resistance. They are prone to decomposition at high temperatures, and even ignited. They are prone to embrittlement and peeling off at low temperatures, resulting in short circuits, electric leakage, power outages and other accidents, resulting in huge economic losses.

Method used

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  • Reversible thermosensitive color-changing transformer early-warning insulating sheath material and preparation method thereof
  • Reversible thermosensitive color-changing transformer early-warning insulating sheath material and preparation method thereof

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preparation example Construction

[0040] The present invention also provides a preparation method of the above-mentioned reversible thermochromic transformer early warning insulating sheath material, comprising the following steps:

[0041] (1) Use filling oil to fill the styrene-based thermoplastic elastomer with oil, and let it stand for 15-20min;

[0042] (2) adding the oil-filled styrene-based thermoplastic elastomer and the remaining components in the high-speed mixer through step (1) and mixing;

[0043] (3) step (2) gained mixture is added in Banbury mixer to carry out Banbury;

[0044] (4) feeding the mixture after the banburying in step (3) into a twin-screw extruder for pulling and dicing, to obtain a reversible thermochromic transformer early warning insulating sheath material.

[0045] In order to further optimize the above technical solution, the extrusion temperature in step (4) is 160-200°C.

Embodiment 1

[0047] An early warning insulating sheath material for a reversible thermochromic transformer, the sheath material includes the following raw material components and parts by weight:

[0048] 50 parts of silicone rubber, 15 parts of polypropylene resin, 10 parts of styrene thermoplastic elastomer, 15 parts of dioctyl maleate, 30 parts of fumed silica, 15 parts of nano wollastonite, 20 parts of reversible thermochromic material, 5 parts of white oil, 20 parts of ammonium polyphosphate, 20 parts of molybdenum trioxide, 3 parts of oxidized polyethylene wax, 5 parts of triallyl isocyanurate, 5 parts of antioxidant DLTP;

[0049] The preparation method of the reversible thermochromic material is as follows: firstly, according to the molar ratio of 1:5, weigh the required amount of cetyltrimethylammonium chloride C. 19 H 42 ClN and CoCl 2 ; Secondly, the hexadecyl trimethyl ammonium chloride C that will be weighed 19 H 42 ClN and metal cobalt salt are dissolved in ethanol or wat...

Embodiment 2

[0051] An early warning insulating sheath material for a reversible thermochromic transformer, the sheath material includes the following raw material components and parts by weight:

[0052] 80 parts of silicone rubber, 10 parts of polypropylene resin, 30 parts of styrene thermoplastic elastomer, 10 parts of dioctyl maleate, 40 parts of fumed silica, 20 parts of nano wollastonite, 10 parts of reversible thermochromic material, 3 parts of white oil, 10 parts of hypophosphite, 10 parts of magnesium hydroxide, 2 parts of SEBS grafted maleic anhydride, 3 parts of PP grafted maleic anhydride, 1 part of dicumyl peroxide, 1 part of antioxidant CPL ;

[0053] The preparation method of the reversible thermochromic material is as follows: firstly, according to the molar ratio of 1:6, weigh the required amount of cetyltrimethylammonium chloride C. 19 H 42 ClN and CoSO 4 ; Secondly, the hexadecyl trimethyl ammonium chloride C that will be weighed 19 H 42 ClN and metal cobalt salt ar...

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Abstract

The invention discloses a reversible thermosensitive color-changing transformer early-warning insulating sheath material and a preparation method thereof. The sheath material is prepared from the following raw material components in parts by weight: 50 to 80 parts of silicone rubber, 10 to 15 parts of polypropylene resin, 10 to 30 parts of a styrene thermoplastic elastomer, 10 to 15 parts of dioctyl maleate, 30 to 40 parts of fumed silica, 15-20 parts of nano wollastonite, 10-20 parts of a reversible thermochromic material, 3 to 5 parts of filling oil, 20 to 40 parts of a flame retardant, 3 to5 parts of a compatilizer, 1 to 5 parts of a vulcanizing agent and 1 to 5 parts of an antioxidant. The sheath material prepared by the invention is a transformer insulation sheath material capable ofinstantly and reversibly changing color in a relatively large temperature range, so that an early warning function is achieved, and the sheath material has excellent mechanical and physicochemical properties.

Description

technical field [0001] The invention relates to the technical field of sheath material preparation, in particular to an early warning insulating sheath material for a reversible thermochromic transformer and a preparation method thereof. Background technique [0002] The transformer insulating sheath is used for the shielding and insulating protection of the surface of the transformer busbar bridge tube, which can effectively prevent the exposed transformer busbar bridge from being accidentally touched by humans, birds and beasts and other small animals or foreign objects. Electrical accidents caused by dew flashover, pollution flashover, and icicle sticking to snow, and prevent power outage accidents caused by salt spray, acid rain and chemical gas corrosion damage to the transformer inlet and outlet lines. [0003] However, the existing transformer sheath materials have poor high and low temperature resistance, and are prone to decomposition or even ignite at high temperat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08L23/12C08K13/04C08K5/19C08K3/16C08K7/26C08K3/34C08K3/30C08K3/26C08K3/28H01B3/28
CPCC08K2003/3045C08K2201/011C08L83/04C08L2201/02C08L2201/08C08L2203/20C08L2205/035C08L2207/04H01B3/28C08L23/12C08K13/04C08K5/19C08K3/16C08K7/26C08K3/34C08K3/30C08K3/26C08K3/28
Inventor 戴章戴冕戴文忠李亮
Owner 戴文忠
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