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A wear-resistant high-elastic copper alloy socket material and its preparation method

A copper alloy, high elasticity technology, used in metal rolling, manufacturing tools, heat treatment equipment and other directions, can solve the problems of poor stress relaxation resistance, high tensile strength and Vickers hardness, large opening size of the socket, etc. Improve the comprehensive properties of materials, refine the original grain size, and improve the effect of comprehensive properties

Active Publication Date: 2021-07-13
BULL GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The tin phosphor bronze socket has a certain degree of elastic deformation while carrying current during use. After tens of thousands of plugging and unplugging, the surface of the socket will have serious wear and deformation.
On the one hand, the effective contact area between the socket and the pin will become smaller, causing the contact resistance to rise, resulting in problems such as excessive temperature rise of the socket during use, and there are potential safety hazards
On the other hand, the sleeve is constantly worn during the insertion and extraction process of the pin, resulting in an excessively large opening size of the sleeve, and the pull-off force of the pin will decline rapidly, which cannot meet the requirements for safe use.
There are also some sockets made of brass (such as H62) and copper (such as T2), but brass and copper have poor stress relaxation resistance and low fatigue life
[0006] A large number of existing technologies have been reported for improving the performance of copper alloys, such as Chinese patent CN106987738B, which discloses a Cu-Ni-Si-Co-Ti-RE copper alloy, including the following components in weight percentage: 0.5% ~2.0% Ni, 0.2%~0.9% Si, 0.5%~2.0% Co, 0.1%~0.5% Ti, 0.05%~0.2% RE, the rest is Cu, where RE is Ce, La and Y One or more of them, the tensile strength σ b It can reach 800-1000MPa, the plastic elongation δ is 3-10%, the electrical conductivity is 45-55% IACS, the stress relaxation resistance (working at 200°C for 1000h) is ≥80%, the tensile strength and dimension of the copper alloy material The hardness is too high, the elongation is low, and the bending and forming of the strip is difficult, so it is not suitable for stamping parts with complex shapes.
Chinese patent application CN 110629070A discloses a Cu-Ni-Sn alloy composition, including Ni 15-17%, Sn 8.5-10.5%, Mn 0.3-1.0%, Cr 0.03%-0.3%, Nb 0.03%- 0.3%, Si 0.03% ~ 0.3%, Zr 0.03% ~ 0.3%, Ti 0.03% ~ 0.3, the balance is Cu, the content of Ni and Sn in this patent is too high, and the electromagnetic stirring link is added in the preparation process. However, the comprehensive production cost of raw materials will increase, and the alloy composition cannot fully form a hard phase with high microhardness, so it cannot effectively improve the wear resistance.

Method used

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  • A wear-resistant high-elastic copper alloy socket material and its preparation method
  • A wear-resistant high-elastic copper alloy socket material and its preparation method
  • A wear-resistant high-elastic copper alloy socket material and its preparation method

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preparation example Construction

[0036] The preparation method of wear-resistant high-elasticity copper alloy socket material in some examples of the present invention comprises the following steps:

[0037] (1) batching, smelting, and casting are carried out according to the mass percentage to form ingots;

[0038] (2) Milling and hot rolling process: the starting rolling temperature is 870°C-950°C, the final rolling temperature is greater than 700°C, and the total processing rate of hot rolling is 80%-90%;

[0039] (3) Rough rolling - the first annealing process: rolling with a total cold working rate of 80%-90%, the first annealing process is heated to 500°C-550°C at a rate of 15-20°C / min, and kept for 4 -6 hours;

[0040] (4) Intermediate rolling-the second annealing process: cold rolling with a total cold processing rate of 60%-80%, the second annealing process is heated to 460°C-510°C at a rate of 15-20°C / min, and kept for 5- 8 hours;

[0041] (5) Finish rolling - the third annealing process: cold ro...

Embodiment 1

[0053] Using T2 electrolytic copper as raw material, it is smelted in a non-vacuum intermediate frequency induction melting furnace. The order of adding the alloy is: first add electrolytic copper, then add nickel, copper-manganese intermediate alloy, copper-silicon intermediate alloy, pure aluminum, metal Tin and zinc, after the composition is qualified, add copper-phosphorus master alloy for deoxidation, the melting temperature is 1250-1300 ℃, and the casting temperature is about 1210 ℃. An ingot of 85mm (thickness) x 145mm (width) x 450mm (length) is cast in an iron mold. The contents of Cu, Ni, Mn, Si, Al, Sn, Zn, and P are shown in Table 1.

[0054] The ingot is milled, the amount of single-side milling is 1.5mm in the first pass, and the amount of single-side milling in the second pass is 1.0mm, and the head and tail are cut off; the ingot is machined and milled and then placed in a resistance furnace and heated to 920°C for 4 hours. Afterwards, hot rolling is carried o...

Embodiment 2-17

[0058]The composition of the samples of Examples 2-17 is shown in Table 1. According to the same process as in Example 1, they were made and processed into 0.6mm thick copper strips, which were respectively marked as 2# sample-17# sample. Measure content such as tensile strength, yield strength Rp0.2, elongation, modulus of elasticity, Vickers hardness (HV5), electrical conductivity, mass wear rate according to the same test method as Example 1, and the measurement results are shown in Table 2.

[0059] It can be seen from Table 2 that the 2#-17# samples of the present invention have excellent performance, and all meet the scope specified by the socket material. Among them, the content of Ni and Sn in the 2#-6# sample has increased compared with the 1# sample, and the strength and elasticity of the material have increased slightly, while the elongation and electrical conductivity have decreased, and the quality wear rate has also decreased slightly. Compared with the 1# sample...

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Abstract

The invention belongs to the technical field of copper alloy materials, and relates to a wear-resistant elastic copper alloy socket material and a preparation method thereof. The material comprises 2.0-5.0% by mass of Zn, 0.6-1.4% by mass of Sn, 1.2-2.5% by mass of Ni, 0.4-0.8% by mass of Si, 0.2-0.4% by mass of Al, 0.2-0.4% by mass of Mn, 0.03-0.10% by mass of P, 89.0-95.4% by mass of copper; may also include Mg and / or Cr in a total amount not exceeding 0.3% by mass. The preparation method includes: smelting, milling, hot rolling process, rough rolling-first annealing process, intermediate rolling-second annealing process, finish rolling-third annealing process. The copper alloy socket material prepared by composition regulation and process control has excellent high elasticity and high wear resistance.

Description

technical field [0001] The invention belongs to the technical field of copper alloy materials, and relates to a wear-resistant elastic copper alloy socket material and a preparation method thereof. Background technique [0002] Socket refers to the insertable seat of one or more circuit connections, can insert various wiring by it, is convenient to connect with other circuits like this. The connection and disconnection of this part of the circuit is achieved through the connection and disconnection between the line and the copper parts. With the development of society and the improvement of people's living standards, the types of sockets are more diverse, and the usage scenarios and environments are becoming more and more complex and changeable. It is widely used in different environments such as airports, stations, shopping malls, offices and other places with heavy traffic, dry north, humid south, and salty coastal areas. [0003] The socket is the core current-carrying ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C9/04C22C9/06C22F1/08C21D9/52C22C1/03B21B3/00
CPCB21B3/00B21B2003/005C21D9/52C22C1/03C22C9/04C22C9/06C22F1/08
Inventor 向紫琪申会员何洋
Owner BULL GRP CO LTD