A kind of lithium battery explosion-proof gasket material and preparation method thereof
A lithium battery and gasket technology, which is applied in the field of lithium battery explosion-proof gasket materials and its preparation, can solve the problems of poor mechanical properties such as tensile strength and tear resistance, performance stability that needs to be further improved, oil resistance, and solvent resistance. To achieve the effect of excellent water repellency, low preparation cost and good comprehensive performance
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Embodiment 1
[0031] A lithium battery explosion-proof gasket material is characterized in that it is made of the following raw materials in parts by weight: 10 parts of fluorinated phosphazene rubber, 5 parts of polydiphenylsilaboroxane, and 80 parts of vinyl-terminated fluorosilicone rubber , 1 part of azobisisobutyronitrile, 0.5 parts of phosphorus pentoxide, 10 parts of vinyl modified thermally conductive fillers, 2 parts of silane coupling agent KH5502, 2-(2-[(3-ethyl-5-methyl- 2(3H)-Benzothiazolyl)methyl]-1-butenyl)-1-(3-sulfonic acid)naphtho[1,2-d]azole hydroxide inner salt 3 parts, 1,3 - 1 part of adamantanediol monoacrylate, 1 part of 1-allyl-2-(trifluoromethyl)-1H-benzo[D]imidazole.
[0032] The preparation method of the vinyl-modified thermally conductive filler comprises the following steps: adding the thermally conductive filler and vinyltriethoxysilane to ethanol, stirring and reacting at 30°C for 4 hours, and then rotary evaporating to remove the solvent to obtain vinyl Modi...
Embodiment 2
[0036] A lithium battery explosion-proof gasket material is characterized in that it is made of the following raw materials in parts by weight: 11 parts of fluorinated phosphazene rubber, 6 parts of polydiphenylsilaboroxane, and 85 parts of vinyl-terminated fluorosilicone rubber , 1.5 parts of azobisisoheptanonitrile, 0.7 parts of phosphorus pentoxide, 12 parts of vinyl modified thermally conductive fillers, 2.5 parts of silane coupling agent KH560, 2-(2-[(3-ethyl-5-methyl 4 parts of base-2(3H)-benzothiazolyl)methyl]-1-butenyl)-1-(3-sulfonic acid)naphtho[1,2-d]azole hydroxide inner salt, 1 , 1.5 parts of 3-adamantanediol monoacrylate, 1.5 parts of 1-allyl-2-(trifluoromethyl)-1H-benzo[D]imidazole.
[0037] The preparation method of the vinyl-modified thermally conductive filler includes the following steps: adding thermally conductive filler and bis(triethoxysilyl)ethylene into methanol, stirring and reacting at 35°C for 5 hours, and then rotary evaporating to remove the solven...
Embodiment 3
[0041] A lithium battery explosion-proof gasket material, characterized in that it is made of the following raw materials in parts by weight: 13 parts of fluorinated phosphazene rubber, 8 parts of polydiphenylsilaboroxane, and 90 parts of vinyl-terminated fluorosilicone rubber , 2 parts of azobisisobutyronitrile, 1 part of phosphorus pentoxide, 15 parts of vinyl modified thermally conductive filler, 3.5 parts of silane coupling agent KH570, 2-(2-[(3-ethyl-5-methyl 4.5 parts, 1 , 2 parts of 3-adamantanediol monoacrylate, 2 parts of 1-allyl-2-(trifluoromethyl)-1H-benzo[D]imidazole.
[0042] The preparation method of the vinyl-modified thermally conductive filler comprises the following steps: adding the thermally conductive filler and vinyltrimethoxysilane into ethylene glycol, stirring and reacting at 40°C for 5.5 hours, and then rotary evaporating to remove the solvent to obtain ethylene Base modified thermally conductive filler; the mass ratio of the thermally conductive fil...
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