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A kind of non-woven material and its application

A non-woven fabric, cellulose technology, applied in non-woven fabrics, textiles and papermaking, cellulose/protein conjugated rayon, etc. Effectively adsorbing dye molecules and other problems to achieve the effect of increasing color absorption capacity and excellent pigment adsorption effect

Active Publication Date: 2021-10-08
广州浪奇日用品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the color-absorbing sheet based on this idea has two serious defects: the first, in the actual washing process, the distance between the fabrics is very small, and even often the surfaces of the two fabrics are closely attached, while the above-mentioned The electrostatic adsorption relied on in the thinking is a passive adsorption method, which acts like a filter, and can only absorb the dye molecules near the color-absorbing film, but cannot effectively absorb the dye molecules far away from the color-absorbing film; therefore, from the fabric The dyes that come off on the top are often cross-dyed on the fabrics that are closer to each other before being absorbed by the color-absorbing sheet
When the color-absorbing sheet absorbs the surfactant instead of the target dye, the color-absorbing ability of the color-absorbing sheet will decrease, reducing its anti-cross-color effect
In addition, the color-absorbing sheet absorbs the surfactant, resulting in a decrease in the concentration of the effective substance of the detergent, which will also reduce the decontamination effect of the detergent.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • A kind of non-woven material and its application
  • A kind of non-woven material and its application
  • A kind of non-woven material and its application

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0039] One, the preparation of modified cellulose A

[0040] One), the preparation of (4-vinylphenyl-4'-methylenecarboxyphenyl) iodonium

[0041] 1. Using molecular sieves as a catalyst, diphenyliodonium salt reacts with ethylene to obtain 4,4'-divinyldiphenyliodonium (as shown in formula (I)) (embodiment 1-1-1, 1 The reaction conditions of -1-2 and 1-1-3 are shown in Table 1), 4,4'-divinyldiphenyliodonium is partially oxidized through the supported palladium (Pd) heteropolyacid catalyst system Obtain 4-vinylphenyl-4'-methylenecarboxyphenyl) iodonium (as shown in formula (II)) (embodiment 1-1-1, 1-1-2, 1-1-3 reaction The conditions are shown in Table 2):

[0042]

[0043] Among them, the molecular sieve is sodium ZSM-5 molecular sieve exchanged by magnesium, calcium or barium.

[0044] Table 1 Diphenyliodonium salt and ethylene reaction conditions and substance consumption

[0045]

[0046]

[0047] Table 2 Reaction conditions and amounts of substances used in par...

Embodiment 1-2-1

[0051] 1. Synthesis of (4-vinylphenyl-4'-methylenecarboxyphenyl)iodonium-terminated polyvinylpyrrolidone

[0052] The monomer vinylpyrrolidone (NVP) is configured into an aqueous solution with a mass fraction of 45%, using a small amount of hydrogen peroxide (0.2% of NVP) as a catalyst, under the action of azobisisobutyronitrile (0.3% of NVP), in Initiate polymerization at 40-50°C, react for 2 hours, and the monomer polymerization conversion rate is 93-95%. Add (4-vinylphenyl-4'-methylenecarboxyphenyl) iodonium (amount of 0.5% NVP) prepared in Example 1-1-1, react for 0.2 hours, and seal the polymer terminal to obtain (4-vinylphenyl-4'-methylenecarboxyphenyl)iodonium-terminated polyvinylpyrrolidone.

[0053] Then add 0.2% ammonia water to the polymer to decompose the remaining azobisisobutyronitrile. The polymer is spray-dried under hot air at 120-135°C to obtain powdery (4-vinylphenyl-4'-methylenecarboxyphenyl)iodonium-terminated polyvinylpyrrolidone. (4-vinylphenyl-4'-m...

Embodiment 1-2-2

[0065] 1. Synthesis of (4-vinylphenyl-4'-methylenecarboxyphenyl)iodonium-terminated polyvinylpyrrolidone

[0066] The monomer vinylpyrrolidone (NVP) was configured into an aqueous solution with a mass fraction of 50%. Use a small amount of hydrogen peroxide (0.3% NVP) as a catalyst, under the action of azobisisobutyronitrile (0.4% NVP), initiate polymerization at 50-60°C, react for 3 hours, and the monomer polymerization conversion rate is 96~98%.Add ((4-vinylphenyl-4-methylenecarboxyphenyl) iodonium (consumption is the NVP of 0.8%) that embodiment 1-1-1 makes, reacted 0.5 hour, Capping the polymer yields (4-vinylphenyl-4-methylenecarboxyphenyl)iodonium-capped polyvinylpyrrolidone.

[0067] Add 0.3% ammonia water to the polymer to decompose the remaining azobisisobutyronitrile. The polymer is spray-dried under hot air at 135-150°C to obtain powdery (4-vinylphenyl-4-methylenecarboxyphenyl)iodonium-terminated polyvinylpyrrolidone. (4-vinylphenyl-4'-methylenecarboxyphenyl) i...

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Abstract

The invention discloses a non-woven fabric material and its application. Wherein the non-woven material is prepared through the following steps: S1, oxidizing cellulose to obtain 2,3-dicarboxy cellulose, and under the action of heating and dehydrating agent and (4-vinylphenyl-4'- Methylene carboxyphenyl) iodonium-terminated polyvinylpyrrolidone undergoes a condensation reaction to obtain modified cellulose A; S2, oxidize the cellulose to obtain 6-carboxy cellulose, and then undergo cationic modification to obtain modified cellulose B ; S3, mixing modified cellulose A and modified cellulose B to obtain mixed fibers, which are obtained after pretreatment, netting, reinforcement, and chemical finishing. The non-woven fabric material increases the color absorbing ability of the color absorbing fiber without affecting the decontamination effect of the detergent, thereby effectively preventing the color crossing problem during the washing process of the fabric.

Description

technical field [0001] The invention belongs to the field of textile engineering, and in particular relates to a nonwoven material and its application. Background technique [0002] During the washing process of the fabrics that people wear every day, the dyes on the surface of the fabrics will fall off and enter the washing solution. With the agitation of the washing operation, they will transfer to the surface of other fabrics in the washing solution, causing the cross-color phenomenon we see with the naked eye. Generally speaking, dyes used in fabrics have a strong affinity for fabrics, and dyes can be combined with fabric fibers through van der Waals forces, hydrogen bonds, and chemical bonds, so that dye molecules are fixed on the fibers, which is the so-called dyeing process. The dyeing process is reversible. During the washing process, some of the links between the dyes and the fabric fibers can be untied, and the dye molecules return to free molecules, but the free d...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D04H1/4382D04H1/425C08B15/04D01F8/02C08F8/18C08F126/10
CPCC08B15/04C08F8/18D01F8/02D04H1/425D04H1/4382C08F126/10
Inventor 陆业昌甘静姚泽伟蔡熙扬郭晓丹黄煜璇卢志敏张世林刘保
Owner 广州浪奇日用品有限公司
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