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Non-gel and non-precipitation high-concentration laundry detergent and preparation method thereof

A high-concentration, laundry detergent technology, used in the field of daily chemicals, can solve the problems of poor performance at low temperature, affecting production efficiency, and high water content, and achieve the effects of good low-temperature rheology, improved sebum detergency, and smooth viscosity changes.

Active Publication Date: 2020-09-22
ZHONGSHAN LANJU DAILY CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Concentrated laundry detergent must be cautious in the selection of raw materials because the concentration of effective substances is as high as 45%. Most anionic surfactants have high water content and are not suitable for formulations. Sodium fatty alcohol polyoxyethylene ether sulfate (AES ) generally has a concentration of 70%, and is widely used in liquid detergents, but when the dosage is high, the dissolution will be too slow, which will affect the production efficiency;
[0004] For nonionic surfactants, the most cost-effective and widely used nonionic surfactant is fatty alcohol polyoxyethylene ether (AEO-9). AEO-9 has good emulsifying and detergency properties, but its There will be serious gelation during the dissolution process, making the whole system unable to continue compounding due to too high viscosity and poor fluidity, which is a major technical problem for concentrated laundry detergent;
[0005] In addition, concentrated laundry detergent products are prone to system collapse due to the evaporation of surface water and the precipitation of content during production, storage and use due to their high content of effective substances and low process water content. The viscosity of the laundry detergent is easily affected by temperature, and fluctuates greatly due to the influence of temperature. Generally, the viscosity of laundry detergent is below 1000mPa s at room temperature, but it may be as high as 6000 or even 10000mPa s at low temperature, and the performance at low temperature is poor. If the above-mentioned technical problems are not solved well, it will become the main restrictive factor for the further development of concentrated laundry detergent

Method used

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  • Non-gel and non-precipitation high-concentration laundry detergent and preparation method thereof
  • Non-gel and non-precipitation high-concentration laundry detergent and preparation method thereof
  • Non-gel and non-precipitation high-concentration laundry detergent and preparation method thereof

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Experimental program
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preparation example Construction

[0059] A kind of preparation method of the highly concentrated laundry liquid that does not gel and does not separate out, comprises the following steps:

[0060] A. Take anionic surfactant, nonionic surfactant, 2-methyl-2,4-pentanediol, enzyme preparation, essence, preservative and water according to the formula quantity;

[0061] B. Add 2-methyl-2,4-pentanediol, fatty acid methyl ester ethoxylate and isomeric fatty alcohol polyoxyethylene ether into the water of formula quantity and stir evenly, then add nonionic surfactant and stir evenly Finally, add anionic surfactant and stir evenly;

[0062] C. Selectively add enzyme preparation, essence and preservatives, and stir evenly to prepare a highly concentrated laundry detergent that does not gel or separate out.

[0063] The introduction of the 2-methyl-2,4-pentanediol and the compounding of the fatty acid methyl ester ethoxylate (FMEE) and isomerized fatty alcohol polyoxyethylene ether (CA-60) eliminated all The gel proble...

Embodiment 1、2、4 and comparative example 1-6

[0070] A kind of highly concentrated laundry detergent, prepared according to the following steps:

[0071] (1) Calculated according to mass percentage, each raw material is taken by weighing the raw material component content of Table 2 for subsequent use (wherein potassium cocoate is prepared by potassium hydroxide and coconut oil acid, calculated according to mass percentage, the consumption of potassium hydroxide accounts for the total amount of raw materials 0.9% of the consumption, the consumption of coconut oleic acid accounts for 3% of the total consumption of raw materials)

[0072] (2) Preparation of Potassium Coconut Oleate: Add the 2-methyl-2,4-pentanediol and potassium hydroxide weighed in the step (1) to the water of the formula and stir evenly, then slowly add coconut oleic acid for neutralization React until the pH value of the liquid reaches 8.0, and the reaction is complete;

[0073] (3) Add fatty acid methyl ester ethoxylate (FMEE) and isomeric fatty alcoho...

Embodiment 3

[0076] A kind of highly concentrated laundry detergent, prepared according to the following steps:

[0077] (1) Calculate according to mass percentage, and each raw material is taken by weighing the raw material component content of Table 2 for subsequent use (wherein the active substance content of potassium cocoate is 30%);

[0078] (2) Add the 2-methyl-2,4-pentanediol, fatty acid methyl ester ethoxylate (FMEE) and isomerized fatty alcohol polyoxyethylene ether (CA-60) weighed in step (1) Stir evenly in the water of formula quantity, then add nonionic surfactant and stir evenly, then add anionic surfactant and stir evenly;

[0079] (3) Add enzyme preparation, stir well and make a kind of highly concentrated laundry detergent, then take samples for performance test.

[0080] Table 2 - Raw material component content

[0081]

[0082]

[0083] Table 2 (continued) - Raw material component content

[0084]

[0085]

[0086] Table 3-embodiment and comparative example ...

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Abstract

The invention discloses a non-gel and non-precipitation high-concentration laundry detergent and a preparation method thereof. The non-gel and non-precipitation high-concentration laundry detergent isprepared from the following raw materials: an anionic surfactant, a nonionic surfactant and 2-methyl-2, 4-pentanediol, the anionic surfactant comprises fatty alcohol-polyoxyethylene ether sodium sulfate; the nonionic surfactant is prepared from fatty alcohol-polyoxyethylene ether, fatty acid methyl ester ethoxylate and isomeric fatty alcohol-polyoxyethylene ether. According to the non-gel and non-precipitation high-concentration laundry detergent and the preparation method thereof, the prepared high-concentration laundry detergent has the characteristics of good economy, excellent rinse property, no gel in ingredients, rapid dissolution, no precipitation after long-term placement, no layering and good low-temperature rheological property.

Description

technical field [0001] The invention relates to the technical field of daily chemicals, in particular to a highly concentrated laundry liquid without gelation and precipitation and a preparation method thereof. Background technique [0002] Ordinary laundry detergent refers to a liquid laundry detergent with an active substance content higher than 15.0% but lower than 25.0%, and a concentrated laundry detergent with an effective substance content higher than 25.0%. Concentrated laundry detergent has the advantages of strong detergency, saving packaging, storage, and low transportation costs due to its high content of effective substances and less water or fillers. In today's increasingly prominent problems of resources, environment, and energy, it is necessary to develop concentrated laundry detergent. Products are conducive to energy conservation and emission reduction, construction resource conservation, and the promotion of sustainable economic and social significance. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C11D1/83C11D3/20C11D3/386C11D3/50C11D3/60
CPCC11D1/83C11D3/2048C11D3/38627C11D3/38618C11D3/38645C11D3/50C11D3/0073C11D1/662C11D1/04C11D1/12C11D1/14C11D1/74C11D1/667C11D1/29
Inventor 骆建华伍尤春
Owner ZHONGSHAN LANJU DAILY CHEM IND CO LTD
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