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A coating for high temperature chlorine corrosion protection and preparation method thereof

A chlorine corrosion and coating technology, which is applied in the high-temperature chlorine corrosion protection coating and its preparation field, can solve the problems of limited applicable positions, no post-heat treatment, and low processing speed of surfacing technology, and achieves wide adjustment range and melting The effect of improving coating efficiency and improving high temperature chlorine corrosion resistance

Active Publication Date: 2022-05-13
XIAN THERMAL POWER RES INST CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Aiming at the problem that the corrosion resistance of Inconel series NiCrMo cladding layer for high-temperature chlorine corrosion protection of hot-end parts of waste incineration boiler needs to be further improved, and the processing rate of surfacing technology is extremely low and the applicable position is limited, the purpose of the present invention is to consider coating Based on the characteristics of the rapid solidification of the cladding layer material during the cladding process and the post-heat treatment is not allowed, a coating for high-temperature chlorine corrosion protection and its preparation method are disclosed, which can significantly improve the high-temperature chlorine corrosion resistance of the coating. and processing rate and location suitability

Method used

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  • A coating for high temperature chlorine corrosion protection and preparation method thereof

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Embodiment 1

[0027]Using argon as the carrier gas, the chemical composition is Ni 53.5wt.%, Cr 37.5wt.%, Mo 4.5wt.%, Nb 2.5wt.%, B1.98 wt.%, C, Si The content is equal to 0.02wt.%. NiCrMoNbB-based alloy powder is prepared, and the alloy powder with a particle size of 15-50 μm is selected as the raw material for preparing the cladding layer. Use an angle grinder wire brush to treat the surface of the TP347 heat-resistant steel pipe row. After completion, use compressed air to blow the surface of the pipe row to remove surface dust and other attachments. Ultra-high-speed laser cladding is used as the cladding layer preparation process. Before cladding, the alloy powder is dried at 80°C for later use. Nitrogen is used as the powder feeding gas. The powder feeding rate is 35g / min, and the laser power is 4kW. The coating is prepared under the condition that the moving speed of the head is 600mm / s. After cladding, the surface roughness of the coating can be as low as 4.5μmRa, and the cladding ra...

Embodiment 2

[0029] The chemical composition is Ni 47.8wt.%, Cr 42.05wt.%, Mo 4.5wt.%, Nb 3.1wt.%, B 2.5wt.%, C, Si content equal to 0.05wt.%. NiCrMoNbB-based alloy powder, the alloy powder with particle size of 45-100 μm is selected as the raw material for preparing cladding layer. Use corundum sand with a particle size of 16 mesh to sandblast the surface of the TP347 heat-resistant steel pipe row under the condition of compressed air pressure of 0.7MPa. After sandblasting, use compressed air to blow the surface of the pipe row to remove sand inclusions on the surface. The cladding layer is prepared by row-type automatic plasma transfer arc surfacing. Before cladding, the powder is dried at 80°C for standby use. Nitrogen is used as the powder feeding gas, the powder feeding rate is 25g / min, and the plasma power is 32kW. , the coating was prepared under the condition that the moving speed of the cladding head was 15mm / s, and the cladding rate reached 0.65m 2 / h, no macroscopic defects suc...

Embodiment 3

[0031] The chemical composition is Ni 52wt.%, Cr 38.5 wt.%, Mo4.0wt.%, Nb 3.0wt.%, B 2.47wt.%, and the content of C and Si is equal to 0.03wt.%. NiCrMoNbB-based alloy powder is prepared, and the alloy powder with a particle size of 45-120 μm is screened as a raw material for preparing a cladding layer. Use corundum sand with a particle size of 16 mesh to sandblast the surface of the Q235 carbon steel pipe row under the condition of compressed air pressure of 0.7MPa. After sandblasting, use compressed air to blow the surface of the pipe row to remove sand inclusions on the surface. First, flame spraying is used to prefabricate the coating on the surface of Q235 carbon steel pipe row. Before spraying, the powder is dried at 80°C for standby use. Dry compressed air is used as the powder feeding gas, and the powder feeding rate is 45g / min. The oxygen flow rate is 430L / h, the acetylene flow rate is 800L / h, and the flame gun moving speed is 300mm / s to prepare the coating. Under the ...

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Abstract

The invention discloses a coating for high temperature chlorine corrosion protection and a preparation method thereof. The chemical composition of the coating is: Cr 32.0-45.0wt.%, Mo 4-5.5wt.%, Nb 2.0-3.5wt.%. , B 1.7‑3.3wt.%, C<0.03wt.%, Si<0.05wt.%, Ni is the balance. The preparation of the coating includes: firstly, the powder of the above components is prepared in a water environment, an inert atmosphere or a vacuum condition by means of melt atomization, and the particle size of the powder is between 15-120 μm; The surface of the metal component to be coated is enhanced to enhance the bonding force between the coating and the construction surface; finally, the prepared alloy powder is melted on the surface of the component after sandblasting by using laser, plasma, flame, and induction energy high-energy beam technology, and the coating The thickness is between 0.1mm‑2mm. It has the characteristics of significantly improved cladding coating efficiency and wider application positions.

Description

technical field [0001] The invention belongs to the technical field of high temperature corrosion protection, in particular to a coating for high temperature chlorine corrosion protection and a preparation method thereof. Background technique [0002] Since waste incineration power generation is the best way to "reduce, harmless, and recycle" domestic waste, it has been widely developed in developed countries such as Europe, America, and Japan. In recent years, the rapid expansion of my country's urban scale has made my country's large and medium-sized cities also face the dilemma of "garbage siege". Therefore, my country has incorporated waste incineration power generation into the national energy development plan. It is expected that by 2020, the urban domestic waste incineration treatment capacity will account for More than 50% of the total harmless treatment capacity. As of the end of 2017, my country had a total of 278 municipal solid waste incineration power generation...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C24/10C23C4/129C23C4/06C22C19/05B22F9/08B22F9/14
CPCC23C24/103C23C4/129C23C4/06C22C19/053C22C19/052B22F9/082B22F9/14B22F2009/0828
Inventor 杨二娟刘福广米紫昊李勇王博刘刚王艳松韩天鹏张周博
Owner XIAN THERMAL POWER RES INST CO LTD