Copper alloy material and preparation method and application thereof

A copper alloy and bar technology, applied in the field of additive manufacturing, can solve the problems of poor high temperature mechanical properties, high temperature creep, cooling channel degradation and failure, etc.

Active Publication Date: 2020-12-04
HEBEI LIEN NEW MATERIAL TECH CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, in the actual thermal tests of the hydrogen-oxygen rocket engine, it is often found that comb-like cracks appear on the inner wall of the thrust chamber of the hydrogen-oxygen rocket engine after multiple thermal tests, and the cracks expand slightly in the subsequent thermal tests, and the inner wall of the channel bulges into the combustion chamber. Since then, high-temperature creep occurs on the inner wall, and the cooling channel suffers from coil-shaped degradation and failure, which eventually leads to fracture and damage to the inner wall of the combustion chamber.
It can be seen that the high-temperature mechanical properties of existing copper alloy materials are poor and need to be further improved

Method used

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  • Copper alloy material and preparation method and application thereof
  • Copper alloy material and preparation method and application thereof
  • Copper alloy material and preparation method and application thereof

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preparation example Construction

[0035] The present invention also provides a preparation method for the copper alloy material described in the above technical solution, comprising the following steps:

[0036] Mixing Cu source, Cr source, Nb source, Zr source, Ag source and RE source, followed by vacuum induction melting and casting to obtain copper alloy rods;

[0037] After machining the copper alloy rod, a copper alloy electrode rod is obtained;

[0038] Using the copper alloy electrode rod as an anode, conduct plasma spheroidization rotating electrode atomization under vacuum and protective atmosphere to obtain the copper alloy material.

[0039] In the invention, Cu matrix, Cr, Nb, Zr, Ag and RE alloy elements are mixed, followed by vacuum induction melting and pouring to obtain copper alloy rods.

[0040] In the present invention, the Cu matrix is ​​preferably electrolytic copper, and the present invention has no special limitation on the source of the electrolysis, which can be produced by convention...

Embodiment 1~8

[0060] According to the mass percentage ratio of each metal element in the copper alloy material (see Table 1 for specific content), weigh electrolytic copper powder, CuCr alloy powder (Cu70%-Cr30%), CuNb alloy powder (Cu80%-Nb20%), CuZr alloy powder (Cu85%-Zr15%), industrial pure Ag powder, RE alloy powder (La90%-Ce8%-Pr1.7%-Nd0.3%), add the above powder into the vacuum induction furnace;

[0061] After evacuating the vacuum induction furnace to 0.01Pa, fill it with an inert gas (mixed gas of argon and helium, the volume ratio is 1:1), raise the temperature from room temperature to 1250°C at 10°C / min, and keep it warm for 10min; 7°C / min, heat up from 1250°C to 1300°C, hold for 8 minutes; at 7°C / min, heat up from 1300°C to 1550°C, conduct vacuum induction melting to obtain melt, cast the melt to obtain copper alloy rods, Diameter 55~85mm, length 900~1300mm;

[0062] Using a lathe to remove the skin of the copper alloy rod to a depth of 1-2 mm from the prepared copper alloy ro...

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Abstract

The invention provides a copper alloy material and a preparation method and application thereof, and belongs to the technical field of additive manufacturing. The copper alloy material is prepared from the following components in percentage by mass: 2.0%-7.0% of Cr, 1.0%-5.0% of Nb, 0.1%-2.0% of Ag, 0.1%-0.7% of Zr, 0.02%-0.3% of RE and the balance of Cu; and the RE is prepared from the followingcomponents in percentage by mass: 88%-93% of La, 6%-9% of Ce, 1.5%-1.9% of Pr and less than or equal to 0.3% of Nd, and the sum of the mass percent is 100%. According to the copper alloy material, through the synergistic effect of RE, Cr, Nb, Ag, Zr and Cu, the heat-conducting property, high-temperature creep property, high-temperature strength and high-temperature fatigue of the copper alloy material are effectively improved, and the problem that in the prior art, the high-temperature mechanical property of the copper alloy material is poor is solved.

Description

technical field [0001] The invention belongs to the technical field of additive manufacturing, and in particular relates to a copper alloy material and a preparation method and application thereof. Background technique [0002] Modern aerospace grade components require high thermal conductivity, high temperature creep resistance, high temperature strength, high temperature fatigue and high mechanical properties. At present, there are few high-temperature-resistant copper alloy grades that meet the requirements of aerospace-grade components, such as: CuZr copper alloy, its chemical composition is Cu-Zr0.15-0.3%, and the chemical composition of CuAgZr copper alloy is Cu-Ag3.0%- Zr0.5%. These high-temperature-resistant copper alloy materials are binary alloys or ternary alloys, which are mostly produced by traditional centrifugal casting or forging spinning methods, and are mainly used in thrust chamber combustion chamber linings. [0003] However, in the actual thermal tests...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/00B22F9/14B33Y70/00
CPCC22C9/00B22F9/14B33Y70/00
Inventor 杨桂香杨景周杨景浩马明杨东娜陈海深杨东华余小芳王梦珂
Owner HEBEI LIEN NEW MATERIAL TECH CO LTD
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