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Polysulfone-based photothermal conversion composite membrane for solar water evaporation and preparation method thereof

A light-to-heat conversion and light-to-heat conversion layer technology, which is applied in the steam generation method using solar energy, solar thermal energy, solar thermal power generation, etc., can solve the problem of large footprint of heat insulation materials, limited equipment use range, lack of integrity, etc. problems, to achieve excellent mechanical properties, excellent oxidation resistance, and increase the effect of absorption rate

Active Publication Date: 2020-12-25
QINGDAO UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this design will lead to the lack of integrity and limit the scope of use of the equipment, and the heat insulation material used has a large footprint and is not convenient to carry

Method used

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  • Polysulfone-based photothermal conversion composite membrane for solar water evaporation and preparation method thereof
  • Polysulfone-based photothermal conversion composite membrane for solar water evaporation and preparation method thereof
  • Polysulfone-based photothermal conversion composite membrane for solar water evaporation and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Add 10 parts by mass of polysulfone particles and 90 parts by mass of dimethylacetamide into a round bottom flask, heat at 70°C and dissolve at 450 rpm for 18 hours until a homogeneous solution is formed, and then stand at constant temperature for defoaming. After defoaming, cast the casting solution on a rough glass plate, spread the casting solution with a scraper to form a primary film, place the primary film in the air for 10 hours to let the solvent evaporate naturally, and transfer it into deionized water to remove it after curing. Excess solvent remaining in the membrane matrix. The obtained polysulfone-based membrane has a cellular pore structure with a pore size of 18 μm, a membrane thickness of 150 μm, and a thermal conductivity of 0.055 W m -1 K -1 , has excellent thermal insulation properties.

[0038] Put 2.0g PS in 20mL of dichloromethane, and stir to make it completely dissolved into a homogeneous solution; put 2.0g of PVP in 50mL of deionized water, an...

Embodiment 2

[0041] Add 20 parts by mass of polysulfone particles and 80 parts by mass of dimethyl sulfoxide into a round bottom flask, heat at 80°C and dissolve at 450 rpm for 22 hours until a homogeneous solution is formed, and then stand at constant temperature for defoaming. After defoaming, cast the casting solution on a rough glass plate, spread the casting solution with a scraper to form a primary film, place the primary film in the air for 8 hours to volatilize naturally, and then move it into deionized water to remove the residue in the film matrix excess solvent. The obtained polysulfone-based membrane has a cellular pore structure with a pore size of 5 μm, a membrane thickness of 500 μm, and a thermal conductivity of 0.042 W m -1 K -1 , has excellent thermal insulation properties.

[0042] Put 1.0g PS in 20mL of dichloromethane, and stir to make it completely dissolved into a homogeneous solution; put 1.0g of PVP in 40mL of deionized water, and heat at 35°C until completely di...

Embodiment 3

[0045] Add 15 parts by mass of polysulfone particles and 85 parts by mass of dimethyl sulfoxide into a round bottom flask, heat at 75°C and dissolve at 400rpm for 10h until a homogeneous solution is formed, and then stand at constant temperature for defoaming. After degassing, cast the casting solution on a rough glass plate, spread the casting solution with a scraper to form a primary film, place the primary film in the air for 15 hours to volatilize naturally, and then move it into deionized water to remove the residue in the film matrix excess solvent. The obtained polysulfone-based membrane has a cellular pore structure with a pore size of 12 μm, a membrane thickness of 380 μm, and a thermal conductivity of 0.04 W m -1 K -1 , has excellent thermal insulation properties.

[0046] Put 4g of PS in 50mL of dichloromethane, and stir to make it completely dissolved into a homogeneous solution; put 4g of PVP in 100mL of deionized water, and heat at 50°C until completely dissolv...

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Abstract

The invention discloses a polysulfone-based photothermal conversion composite membrane for solar water evaporation and a preparation method thereof, and relates to the field of solar water evaporation. The composite membrane comprises a heat insulation layer and a photo-thermal conversion layer on the upper surface of the heat insulation layer, a water conveying channel is distributed in the photo-thermal conversion layer. The preparation method comprises the steps that firstly, a polysulfone (PSf) membrane with a cell-cavity-shaped closed-pore structure is prepared by adopting a solvent evaporation phase inversion method to serve as the heat insulation layer, wherein the cell-cavity-shaped structure endows the membrane with excellent heat insulation performance; and then the polystyrene microsphere (PS) photo-thermal conversion layer coated with reduced graphene oxide (rGO) is deposited on the surface of the membrane through a vacuum assisted suction filtration process, wherein the photo-thermal conversion layer not only shows excellent high-broadband sunlight absorption capacity, but also can provide the continuous water conveying channel. The prepared rGO / PS@PSf composite photo-thermal conversion membrane shows excellent photo-thermal conversion efficiency in the solar water evaporation process, the light absorption efficiency can reach 95%, the temperature of the membrane interface can be increased to 80 DEG C from the room temperature, and the energy conversion efficiency can reach 69%.

Description

technical field [0001] The invention relates to a preparation method of a light-to-heat conversion film used in solar water evaporation process, in particular to a preparation method of a double-layer light-to-heat conversion composite film with a rough interface structure. Background technique [0002] Solar energy and water are two of the most abundant resources on Earth. It can be used to address many of the challenges facing humanity, such as energy and water scarcity. Solar evaporation is a technology that combines these two resources, and is considered to be one of the most attractive and simplest methods in solar thermal energy technology, which can be used in steam production process and is of great significance in many engineering applications. Generating steam and clean water from wastewater or seawater is a fundamental application of solar evaporation technology, which is one of the most promising green and sustainable solutions to the pressing global water scarc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F24S20/55F22B1/00C08J5/18C08J7/04C08L81/06
CPCF24S20/55F22B1/006C08J5/18C08J7/0427C08J2381/06Y02E10/40Y02P20/10
Inventor 高爱林闫业海范慧琴张广法赵帅崔健
Owner QINGDAO UNIV OF SCI & TECH