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Nickel-based alloy powder for high-speed laser cladding and cladding method of nickel-based alloy powder

A technology of laser cladding and nickel-based alloys, which is applied in the coating process and coating of metal materials, can solve the problems of cracks in the cladding layer, poor bonding force, and different properties of the cladding layer, and achieve significant economic benefits. and social benefits, improved wear resistance and corrosion resistance, and good machinability

Pending Publication Date: 2021-01-29
ANHUI MA STEEL SURFACE TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the widely used copper crystallizer generally adopts electroplating method for surface treatment and surface modification to improve the wear resistance and corrosion resistance of the copper plate of the crystallizer, but the electroplating technology has the following shortcomings: It is a physical bond rather than a metallurgical bond. Frequent cold and heat fatigue, impact and friction of molten steel and billets often cause peeling and peeling of the coating during casting of the mold; 2) The coating has low hardness and poor wear resistance
In recent years, relevant institutions have been studying supersonic spraying and ordinary laser cladding coatings. Although supersonic spraying coatings have higher wear resistance than electroplating, they have defects such as poor bonding, easy cracking and easy peeling; ordinary laser cladding The advanced surface strengthening technology can obtain a well-bonded, wear-resistant and high-temperature-resistant alloy cladding layer on the surface of the copper substrate to solve the defects of poor bonding, easy cracking and easy peeling of other surface strengthening layers. Larger heating will lead to large deformation of the copper plate. It is only suitable for use when the copper plate is newly made, and cannot be used when the copper plate is repaired.
And because the materials selected for laser cladding are different, the properties of the cladding layer obtained on the surface of the copper substrate are different, which cannot meet the technical effects of applying different environments in different areas of the copper plate working surface of the crystallizer, and the cladding layer is prone to cracks

Method used

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  • Nickel-based alloy powder for high-speed laser cladding and cladding method of nickel-based alloy powder
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  • Nickel-based alloy powder for high-speed laser cladding and cladding method of nickel-based alloy powder

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Select the repaired crystallizer copper plate, pretreat the surface of the substrate, remove oxides and stains, etc., and then fix the crystallizer copper substrate on the alloy steel bottom plate of the special tooling for preheating, and the pretreated surface faces the high-speed laser The laser head of the cladding equipment; take an appropriate amount of nickel-based alloy powder for drying, the composition of the nickel-based alloy powder is Ni: 83wt%, Al: 10wt%, Si: 4wt%, WC: 2wt%, the balance is unavoidable impurities, nickel-based alloy powder particle size distribution between 20 ~ 53μm, after drying, put it into the powder feeder of high-speed laser cladding equipment for use; turn on the high-speed laser cladding equipment, set the laser power to 3000W, and the laser spot Adjust to a suitable position, use the robot to drive the laser head of the high-speed laser cladding equipment, and set the scanning speed to 1m 2 / h, the laser overlap rate is 30%, and th...

Embodiment 2

[0045] Select the repaired crystallizer copper plate, pretreat the surface of the substrate, remove oxides and stains, etc., and then fix the crystallizer copper substrate on the alloy steel bottom plate of the special tooling for preheating, and the pretreated surface faces the high-speed laser The laser head of the cladding equipment; take an appropriate amount of nickel-based alloy powder for drying, the composition of the nickel-based alloy powder is 80wt% Ni, Al: 12wt%, Si: 6wt%, WC: 1wt%, the balance is unavoidable impurities, the particle size of the nickel-based alloy powder is between 20 and 53 μm, and after drying, put it into the powder feeder of the high-speed laser cladding equipment for use; turn on the high-speed laser cladding equipment, set the laser power to 4000W, and the laser spot Adjust to a suitable position, use the robot to drive the laser head of the high-speed laser cladding equipment, and set the scanning speed to 0.5m 2 / h, the laser overlap rate i...

Embodiment 3

[0047] Select the new crystallizer copper plate, pre-treat the surface of the substrate, remove oxides and stains, etc., then fix the crystallizer copper plate substrate on the alloy steel base plate of the special tooling for preheating, and the pretreated surface faces the high-speed laser The laser head of the cladding equipment; take an appropriate amount of nickel-based alloy powder for drying, the composition of the nickel-based alloy powder is Ni: 81wt%, Al: 10wt%, Si: 5wt%, WC: 3wt%, the balance is unavoidable impurities, nickel-based alloy powder particle size distribution between 20 ~ 53μm, after drying, put it into the powder feeder of high-speed laser cladding equipment for use; turn on the high-speed laser cladding equipment, set the laser power to 3000W, and the laser spot Adjust to a suitable position, use the robot to drive the laser head of the high-speed laser cladding equipment, and set the scanning speed to 1m 2 / h, the laser overlap rate is 30%, and the po...

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Abstract

The invention provides nickel-based alloy powder for high-speed laser cladding and a cladding method of the nickel-based alloy powder, and relates to the technical field of inorganic materials. The nickel-based alloy powder comprises the components of 80wt%-83wt% of Ni, 10wt%-12wt% of Al, 4wt%-6wt% of Si, 1wt%-3wt% of WC, and the balance inevitable trace impurities. The invention further providesthe cladding method of the nickel-based alloy powder on a crystallizer copper plate base body. The cladding method mainly comprises the steps that the pretreated crystallizer copper plate base body ispreheated, and heat preservation is carried out on the crystallizer copper plate base body in the cladding process. A laser cladding layer coating obtained through the cladding mode of the nickel-based alloy powder on a crystallizer copper plate is high in binding force and good in compactness, and the crystallizer copper plate is heated lightly, so that the deformation amount is small; the crystallizer copper plate has good machinable machining performance, so that the abrasion resistance, corrosion resistance and cladding efficiency of a crystallizer are greatly improved; and the cladding method can be suitable for new manufacturing and repairing of the crystallizer copper plate, and has remarkable economic benefits and social benefits.

Description

technical field [0001] The invention relates to the technical field of inorganic materials, in particular to a nickel-based alloy powder for high-speed laser cladding and a cladding method thereof. Background technique [0002] The crystallizer is a water-cooled steel ingot mold, which is a very important part of the continuous casting machine, called the "heart" of the continuous casting equipment. Its function is to continuously condense high-temperature molten steel in the crystallizer to a billet of specified size and geometry, and pull it out at a certain speed. Indicators such as speed and production efficiency. With the continuous increase of my country's steel production, the development of continuous casting production is advancing by leaps and bounds, and the consumption of crystallizers in the continuous casting process is increasing. During the working process, the copper plate of the crystallizer suffers from severe friction and wear due to the erosion of high...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C24/10B22F1/00C22C19/03
CPCB22F1/0003C23C24/103C22C19/03
Inventor 王硕煜曹辉郑志成周永商莹
Owner ANHUI MA STEEL SURFACE TECH CO LTD
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