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Anti-explosion impact-resistant polyurea coating for foamed aluminum and preparation method thereof

A technology of aluminum foam and impact resistance, which is applied in the field of preparation of functional coating materials, can solve the problems of weak interfacial bonding force, large difference between soft and hard, and poor energy absorption effect of polyurea coating materials, and achieve good impact resistance, Improve the interface bonding force, high strength effect

Active Publication Date: 2021-02-02
SOUTHWEAT UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because the polyurea molecular chain can be adjusted from the rubber state to the glass state, the existing polyurea coating materials have a large difference in hardness and softness, and are mainly waterproof, and the energy absorption effect is poor.
At the same time, due to the existence of foamed aluminum cells, the interface between the existing polyurea coating materials and foamed aluminum has weak bonding force and poor adhesion.

Method used

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  • Anti-explosion impact-resistant polyurea coating for foamed aluminum and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0027] This example provides an anti-explosion and impact-resistant polyurea coating material for foamed aluminum. The preparation raw materials and proportions are: A component by mass percentage, Wanhua isocyanate MDI-50 51 parts, Haian Petrochemical Co., Ltd. Polyoxypropylene glycol PPG-200046 parts, Qilu Petrochemical alkylene carbonate 3 parts; B component by mass percentage, amino-terminated polyether Jeffamine D-200060 parts, amino-terminated polyether Jeffamine T-5000 5 parts, ten thousand Hua 3,5-diethyltoluenediamine E100 22 parts, Wanhua 4,4,-bis-sec-butylaminodiphenylmethane W6200 9 parts, leveling agent BYK-354 1 part, defoamer BYK-066N 0.8 1 part, wetting and dispersing agent BYK-164 1 part, Dow Corning coupling agent KH-550 0.7 part, BASF antioxidant 1135 0.5 part.

[0028] The preparation method of the polyurea coating material used in this embodiment is as follows:

[0029] (1) Add polyoxypropylene glycol PPG-2000 to the reactor in parts by mass, dehydrate un...

Embodiment 2

[0033] This example provides an anti-explosion and impact-resistant polyurea coating material for foamed aluminum. The preparation raw materials and proportions are: A component by mass percentage, Wanhua isocyanate MDI-50 50 parts, Mitsubishi polyurea Tetrahydrofuran diol PTMG-1000 45 parts, Qilu Petrochemical alkylene carbonate 5 parts; B component by mass percentage, amino-terminated polyether Jeffamine D-2000 58 parts, amino-terminated polyether Jeffamine T-5000 5 parts, ten thousand Hua 3,5-diethyltoluenediamine E100 20 parts, Wanhua 4,4,-bis-sec-butylaminodiphenylmethane W6200 13 parts, leveling agent BYK-354 1 part, defoamer BYK-066N 0.8 1 part, wetting and dispersing agent BYK-164 1 part, Dow Corning coupling agent KH-550 0.7 part, BASF antioxidant 1135 0.5 part.

[0034]The preparation method of the polyurea coating material used in this embodiment is as follows:

[0035] (1) Add polytetrahydrofuran glycol PTMG-1000 to the reaction kettle in parts by mass, dehydrate ...

Embodiment 3

[0039] This example provides an anti-explosion and impact-resistant polyurea coating material for foamed aluminum. The preparation raw materials and proportions are: A component by mass percentage, Wanhua isocyanate MDI-50 47 parts, Bayer polyurea Ether polyol Acclaim 4200 50 parts, Qilu Petrochemical alkylene carbonate 3 parts; B component by mass percentage, amino-terminated polyether Jeffamine D-2000 53 parts, amino-terminated polyether Jeffamine T-5000 6 parts, Wanhua 17 parts of 3,5-diethyltoluenediamine E100, 20 parts of Wanhua 4,4,-bis-sec-butylaminodiphenylmethane W6200, 1 part of leveling agent BYK-354, 0.8 parts of defoamer BYK-066N , 1 part of wetting and dispersing agent BYK-164, 0.7 part of Dow Corning coupling agent KH-550, 0.5 part of BASF antioxidant 1135.

[0040] The preparation method of the polyurea coating material used in this embodiment is as follows:

[0041] (1) Add polyether polyol Acclaim 4200 to the reaction kettle in parts by mass, dehydrate under...

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Abstract

The invention provides an anti-explosion impact-resistant polyurea coating capable of being well adhered to the surface of foamed aluminum and a preparation method of the anti-explosion impact-resistant polyurea coating, belonging to the crossing field of polymer synthesis and explosion impact dynamics. The coating is formed by spraying an isocyanate semi-prepolymer component A and a component B composed of amine-terminated polyether, an amine chain extender and an auxiliary agent through a high-temperature high-pressure collision atomization mixing process. The component A is prepared from 47-53 parts by mass of isocyanate, 45-50 parts by mass of polyether polyol and 3-5 parts by mass of an active diluent through the processes of heating, vacuum dehydration and the like; and the componentB is prepared by stirring and mixing 58-66 parts by mass of amine-terminated polyether, 30-38 parts by mass of a liquid amine chain extender and 3-5 parts by mass of an auxiliary agent and carrying out vacuum dehydration. The synthesized polyurea coating has the advantages of high strength, good toughness, good impact resistance and strong interface adhesion with a foamed aluminum material, can coat the surface of foamed aluminum to form a composite protective armor structure, and has wide application space in lightweight weapon preparation and military and civil dual-purpose engineering protection facilities.

Description

technical field [0001] The invention belongs to the field of preparation of functional coating materials, in particular to an anti-explosion and impact-resistant polyurea coating applied to foamed aluminum and a preparation method thereof. Background technique [0002] Due to natural disasters or wars, common structures in people's lives are often subjected to explosive impact loads, such as building structures, automobile structures, and aircraft structures. The acting time of these loads is very short, usually causing rapid changes in the structural response in a short period of milliseconds, microseconds, or even nanoseconds, thus causing huge damage to the structure. Sudden damage to structures will cause a large number of casualties and property losses. Improving the protection performance of structures under the impact of explosions has become a hot and difficult research topic in the field of disaster prevention and mitigation. In today's society, most protective str...

Claims

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Application Information

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IPC IPC(8): C09D175/02C08G18/76C08G18/66C08G18/48C08G18/50C08G18/32C08G18/12B05D7/16
CPCC09D175/02C08G18/7671C08G18/6666C08G18/4825C08G18/4854C08G18/48C08G18/12C08G18/5024B05D7/16B05D2518/00C08G18/324C08G18/3243
Inventor 郭辉卢春江陈玉顾蒙蒋林志凌星鹏姜欣怡
Owner SOUTHWEAT UNIV OF SCI & TECH