Quantum dot composite material and preparation method, light-emitting film and display device
A technology of composite materials and quantum dots, which is applied in the field of light-emitting thin films and display devices, quantum dot composite materials and their preparation, can solve the problems that the light-emitting performance is easily affected by environmental changes, and the quantum dots are easy to agglomerate, so as to ensure the light stability and luminous performance, good photostability and luminous performance, and the effect of improving luminous performance
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preparation example Construction
[0020] A kind of preparation method of quantum dot composite material, please refer to figure 1 ,include:
[0021] S01. Obtain a mixed solution containing a metal organic framework material, a sensitizer, and a quantum dot, wherein the metal organic framework material has a porous structure and an unsaturated metal site, and the sensitizer is at least partially combined with the unsaturated Saturated metal site coordination connection;
[0022] S02. Heating the mixed solution, so that the quantum dots are at least partially loaded in the porous structure.
[0023] In the preparation method of the quantum dot composite material provided in the embodiment of the present invention, the metal organic framework material, the sensitizer and the quantum dot liquid phase system are mixed and heated, so that the sensitizer and the quantum dot are supported on the metal organic framework material, On the one hand, loading quantum dots in the porous structure of metal organic framework...
Embodiment approach
[0027] As an embodiment, the quantum dots include quantum dots of group II-VI compounds, quantum dots of group III-V compounds or quantum dots of group IV-VI compounds. Further, the quantum dots include: binary phase, ternary phase and quaternary phase quantum dots. Wherein, the binary phase quantum dots include but not limited to CdSe, ZnSe, PbSe, CdTe, ZnO, InP, GaN, GaP, AlP, InN, ZnTe, InAs, GaAs, CaF 2 etc., the ternary phase quantum dots include but not limited to Cd 1-x Zn x S / ZnS, Cd 1-x Zn x Se / ZnSe, CdSe 1-x S x / CdSe y S 1-y / CdS, Cd 1-x Zn x S, Cd 1-x Zn x Se, CdSeyS 1-y , PbSe y S 1-y , CdSe / Cd 1-x Zn x Se / CdyZn 1-y Se / ZnSe, Zn x Cd 1-X Te, Cd1-x Zn x Se / CdyZn 1-y Se / ZnSe, CdS / Cd 1-x Zn x S / Cd y Zn 1-y S / ZnS, NaYF 4 , CdS / ZnS, NaCdF 4 etc., the quaternary phase quantum dots include but not limited to Cd 1-x wxya 1-y , CdSe / ZnS, Cd 1- x Zn x Se / ZnS, CdSe / CdS / ZnS, CdSe / ZnSe / ZnS, etc. Furthermore, the particle size of the quantum dots...
Embodiment 1
[0059] This embodiment provides a quantum dot composite material, which specifically includes the following steps:
[0060] 2mmol Zn 4 O(CO 2 ) 6 and 0.5 mmol of isophthalic acid were dissolved in 15 mL of N,N-dimethylformamide, 7 mmol of ruthenium terpyridine was added, and after ultrasonic dissolution, the mixed solution was transferred to a 50 mL polytetrafluoroethylene stainless steel autoclave. Heat to 120°C in a programmed oven for 10 hours, then cool down to room temperature naturally. After the reaction is finished, filter to obtain MOF-5 compounded with ruthenium terpyridine;
[0061] Disperse 1mL of 3-(2-aminoethylamino)propyltrimethoxysilane, 1mg of MOF-5 complexed with ruthenium terpyridine and 6mg of CdSe in ethanol, stir and mix at 45°C for 2h, after standing still, wash and dry Dry to obtain CdSe@terpyridylruthenium / MOF-5.
[0062] The quantum efficiency of the quantum dot composite material prepared in this embodiment is 80%, and the quantum dot efficiency...
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