Gypsum plaster board and preparation method thereof

A technology of paper surface gypsum board and gypsum clinker, which is applied in the field of gypsum board and its preparation, and can solve the problems of influence, reduction of mechanical properties of gypsum board, poor performance of gypsum products, etc.

Active Publication Date: 2021-04-27
CHINA NAT BUILDING MATERIALS TECHCAL INNOVATION & RES INST LIMITED
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to expand the ability of the gypsum board to adjust the temperature and humidity of the environment, the existing gypsum is usually mixed with humidity control and energy storage materials. However, when the humidity control and energy storage materials are mixed, the mechanical properties of the gypsum board are often greatly reduced. This limits the development and use of functional paper-faced gypsum boards
[0003] As an industrial by-product gypsum, some flue gas desulfurization gypsum contains a certain amount of soluble impurities such as sodium ions, magnesium ions and chloride ions. Desulfurization gypsum with high content of impurity ions has adverse effects on the performance of gypsum products, for example, The paper-faced gypsum board prepared with desulfurized gypsum with high content of impurity ions is prone to problems such as separation of the board core from the paper core, frosting on the surface, and increased dosage of modified starch.
In recent years, many scientific research institutes in China have successively carried out research on the treatment and purification of industrial by-product gypsum (desulfurization gypsum, phosphogypsum, fluorogypsum, etc.). When controlling raw materials, there is relatively much understanding of the impact of chloride ions, but Magnesium ions are often not paid enough attention, and there are few reports on the use of low-quality desulfurized gypsum with high impurity ion content to prepare functional plates

Method used

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  • Gypsum plaster board and preparation method thereof
  • Gypsum plaster board and preparation method thereof
  • Gypsum plaster board and preparation method thereof

Examples

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preparation example Construction

[0052] In yet another aspect, the embodiment of the present application provides a method for preparing the above-mentioned gypsum board, comprising the following steps:

[0053] The raw materials of the board core are mixed evenly to form a gypsum slurry. After the gypsum slurry is formed, it is lapped and bonded with the face paper to form a wet board. The wet board is at 15°C to 30°C and the humidity is 50%. Curing at 70% medium temperature for 1 to 7 days, the wet board curing temperature does not exceed 40°C, and finally the wet board is dried to obtain a gypsum board.

[0054] In the embodiment of the present application, the thickness of the gypsum board substrate is 9.5 mm to 12 mm.

[0055] In the examples and comparative examples of the present application, magnesium oxide was purchased from Hebei Meisheng Chemical Technology Co., Ltd., with a purity of ≥99%, 1000 mesh, d 50 3μm to 5μm, d 90 10μm to 15μm.

[0056] In the examples and comparative examples of the pr...

Embodiment 1

[0080] The gypsum clinker is selected, the magnesium ion content in the gypsum clinker is 0.1wt.%, and the chloride ion content is 200ppmw. Pass 1000 grams of gypsum clinker through an 80-mesh sieve. Choose an appropriate amount of citric acid gypsum (the calcium sulfate dihydrate in the citric acid gypsum is 99wt.%, and the residual citric acid in the citrate gypsum is 0.3wt.%). After drying (45°C), grind to a particle size of 400nm to 800nm, Weigh 10g for later use. Take by weighing magnesia 8g (magnesia and impurity ion Mg 2+ The molar ratio is 4.8:1). Mix magnesium oxide, gypsum clinker, 10g expanded vermiculite nanosheets, 5g polyvinyl alcohol, 5g starch, 5g rubber powder and 0.5g water reducer evenly, and then mix evenly with citrate gypsum. Determine the mixing water content according to the water consumption of the standard consistency, add 0.2g foaming agent to the mixing water and stir evenly. The mixed powder is added to the mixing water to prepare a slurry, and...

Embodiment 2

[0082] The gypsum clinker is selected, the magnesium ion content in the gypsum clinker is 0.15wt.%, and the chloride ion content is 1000ppmw. Pass 1000 grams of gypsum clinker through an 80-mesh sieve. Choose an appropriate amount of citric acid gypsum (the calcium sulfate dihydrate in the citric acid gypsum is 99wt.%, and the residual citric acid in the citrate gypsum is 0.3wt.%). After drying (45°C), grind to a particle size of 400nm to 800nm, Weigh 8g for later use. Take by weighing magnesium oxide 12.5g (magnesium oxide and impurity ion Mg 2+ The molar ratio is 5:1). Mix magnesium oxide, gypsum clinker, 10g expanded vermiculite nanosheets, 5g polyvinyl alcohol, 5g starch, 5g rubber powder and 0.5g water reducer evenly, and then mix evenly with citrate gypsum. Determine the mixing water content according to the water consumption of the standard consistency, add 0.2g foaming agent to the mixing water, and stir evenly. The mixed powder is added to the mixing water to prep...

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Abstract

The invention provides a gypsum plaster board. The gypsum plaster board is composed of a board core and surface protection paper. The board core comprises the following raw materials: gypsum clinker containing impurity ions, wherein the impurity ions comprise Mg<2+>, or comprise Mg<2+> and Cl<->; and magnesium oxide and expanded vermiculite nanosheets, wherein a molar ratio of magnesium oxide to the impurity ions Mg<2+> is 4-7, a weight ratio of the gypsum clinker to the expanded vermiculite nanosheet is (90-100): (0.5-12), and optionally, the content of the Mg<2+> in the gypsum clinker is 0.05 wt.% to 1.5 wt.% while the content of Cl<-> in the gypsum clinker is less than or equal to 0.2 wt.%. According to the method, Mg<2+> and Cl<-> impurity ions in the low-quality desulfurized gypsum are solidified in the hydrated salt, and the hydrated salt has the capabilities of humidity regulation, temperature control, flame retardance and the like in a gypsum-based material, so the mechanical properties and the water resistance of the gypsum plaster board are enhanced, and the toughness of the board is improved.

Description

technical field [0001] This article relates to but not limited to a construction material technology, especially to a gypsum board and its preparation method. Background technique [0002] As we all know, gypsum is a porous building material, and gypsum board is a kind of building decoration material with good performance, which has the function of fine-tuning the temperature and humidity of the environment. In order to expand the ability of the gypsum board to adjust the temperature and humidity of the environment, the existing gypsum is usually mixed with humidity control and energy storage materials. However, when the humidity control and energy storage materials are mixed, the mechanical properties of the gypsum board are often greatly reduced. This limits the development and use of functional paper-faced gypsum boards. [0003] As an industrial by-product gypsum, some flue gas desulfurization gypsum contains a certain amount of soluble impurities such as sodium ions, m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/14C04B38/10C04B111/52
CPCC04B28/144C04B2111/52C04B2111/0062C04B2201/50C04B14/304C04B14/204C04B20/008C04B20/0008C04B24/2623C04B24/38C04B22/146C04B24/06C04B2103/302C04B2103/0057C04B2103/42C04B38/10Y02W30/91
Inventor 王兵杨正波王丽陈红霞刘文君
Owner CHINA NAT BUILDING MATERIALS TECHCAL INNOVATION & RES INST LIMITED
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