Ammonia gas adsorbent and preparation method thereof

An adsorbent and ammonia technology, applied in the field of environmental purification, can solve the problems of difficulty in forming porous materials, expansion, pulverization and agglomeration, and small contact area of ​​ammonia, so as to increase the adsorption capacity, avoid pulverization and falling, The effect of increasing the contact area

Pending Publication Date: 2021-08-10
上海国瓷新材料技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the adsorption materials used for ammonia adsorption and recycling at home and abroad mainly include zeolite, activated carbon, graphene oxide, alumina, silica gel and porous organic polymers, etc., but these materials are difficult to form stable porous materials. Small, its adsorption capacity is often not hig

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0027] The present invention provides a method of preparing a ammonia adsorbent according to the above scheme, comprising the steps of:

[0028] Metal chloride is dissolved in a solvent to give a metal chloride solution;

[0029] Mix the molecular sieve with a metal chloride solution, dried to give an active component;

[0030] The active group was dispensed into a slurry coated on cordierite honeycomb ceramic to obtain ammonia absorbent.

[0031] The present invention dissolves the metal chloride in a solvent to obtain a metal chloride solution. In the present invention, the solvent is preferably water, methanol, ethanol. In the present invention, the concentration of the metal chloride solution is preferably 5% to 20%, more preferably 10% to 15% by weight, and more preferably 10% to 15% by weight.

[0032] After the metal chloride solution was obtained, the molecular sieve was mixed with a metal chloride solution to obtain an active component. In the present invention, the mixin...

Example Embodiment

[0036] Example 1

[0037] Active component preparation

[0038] The 20 g of ZSM-5 molecular sieves were mixed in a copper chloride solution having a concentration of 80 g of a mass concentration of 5%, and the molecular sieve was taken out in an oven at 80 ° C for 5 h at an oven at 80 ° C, then placed in chlorine after drying. Adsorption in the copper copper solution, repeat the above operation until the adsorption is completed, resulting in an active component.

[0039] 2. Application

[0040] The active component is uniformly dispersed in deionized water, and an aluminum sol binder (active component: binder: water mass ratio is 1: 1: 8), stirring at a rotational speed of 100 R / min for 2 h, then immersed in Bluestone honeycomb ceramics (active components are 30% of cordierite honeycomb ceramics), vacuum adsorption (vacuum is 0.5 MPa) 2min, take-out, purged, 100 ° C for 3 h, to obtain ammonia absorbent.

Example Embodiment

[0041] Example 2

[0042] Active component preparation

[0043] The 20 g of SAPO-34 molecular sieves were mixed in a calcium chloride solution having a concentration of 5 g of a concentration of 20%, and stirred at a rotational speed of 100 R / min for 2 h, and then dried in an oven at 70 ° C for 6 h to obtain an active component.

[0044] 2 coated

[0045] The active component is uniformly dispersed in deionized water, adding a silica sol binder (active component: binder: water mass ratio of 1: 0.5: 8.5), stirred at a speed of 100 r / min for 2 h, then immerse Bluestone honeycomb ceramics (active components are 25% of cordierite honeycomb ceramics), vacuum adsorption (vacuum is 0.1 MPa) 5 min, take it, purged, 110 ° C for 2.5 h, to obtain ammonia adsorbents.

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Abstract

The invention provides an ammonia gas adsorbent and a preparation method thereof, and belongs to the technical field of environment purification. The ammonia gas adsorbent comprises an active component and cordierite honeycomb ceramic; and the active component comprises a molecular sieve and a metal chloride. The ammonia gas adsorbent can be applied to the aspect of ammonia gas adsorption.

Description

technical field [0001] The invention belongs to the technical field of environmental purification, and in particular relates to an ammonia adsorbent and a preparation method thereof. Background technique [0002] Ammonia (NH 3 ) is an important chemical raw material, which is widely used in industry. At the same time, ammonia is also a polluting and highly corrosive air pollutant, which will have a great impact on human health and the ecological environment. On the one hand, ammonia can irritate the respiratory tract and other human tissues; on the other hand, ammonia can interact with atmospheric NO x and SO 2 Combined, and through a series of chemical transformations to form particulate matter, causing smog. According to the indoor air quality standard, the maximum indoor ammonia concentration is 0.2635ppm. Therefore, how to reduce the emission of ammonia and reduce the content of ammonia in the environment has become an urgent problem to be studied and solved. [00...

Claims

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Application Information

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IPC IPC(8): B01J20/18B01J20/30B01D53/02F24F8/15
CPCB01J20/186B01J20/12B01J20/0237B01J20/0288B01J20/046B01D53/02B01D2257/406Y02A50/20
Inventor 刘欢李智林德宝彭冲宋锡滨
Owner 上海国瓷新材料技术有限公司
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