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Corrosion-resistant plastic rope and production process thereof

An anti-corrosion and anti-corrosion agent technology, applied in the field of plastic ropes, can solve the problems of reduced tensile strength and short service life

Inactive Publication Date: 2021-08-20
安徽乙纤新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] (1) By adding ethylene into the reactor, adding a catalyst to control the pressure and temperature reaction, adding hydroquinone as a polymerization inhibitor, and obtaining polyethylene with a low degree of polymerization, adding ethylene into the reactor, and adding cinnamic acid to the reactor to generate Reaction, intermediate E is obtained, intermediate E is added to polyethylene with a low degree of polymerization, an initiator is added, temperature and pressure are controlled, and it is soaked in a threonine solution to obtain a modified polyethylene. Benzene ring and carboxyl functional groups are introduced into the chain. The introduction of benzene ring can enhance the rigidity of the polyethylene molecular chain, thereby improving the strength and wear resistance of the modified polyethylene, and the carboxyl functional group interacts with the hydroxyl and amino groups on the threonine molecule. The threonine molecule is grafted on the polyethylene molecular chain, and various functional groups in the threonine molecule can interact with the polyethylene molecule to increase the molecular binding force, so that the intermolecular branch chains are not easy to shift, and the tensile properties are enhanced. It solves the problems of reduced tensile strength and short service life of existing plastic ropes;

Method used

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  • Corrosion-resistant plastic rope and production process thereof
  • Corrosion-resistant plastic rope and production process thereof
  • Corrosion-resistant plastic rope and production process thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0051] This embodiment is a corrosion-resistant plastic rope, comprising the following steps:

[0052] S1: 70 parts of modified polyethylene, 15 parts of plant cellulose fibers, 16 parts of plasticizer, 1 part of foaming agent, 2 parts of corrosion inhibitor and 1 part of dispersant are mixed to obtain a blend;

[0053] Wherein the preparation process of modified polyethylene is as follows:

[0054] S21: Add ethylene to the reactor, add catalyst, control the pressure at 0.1MPa and temperature at 65°C, react for 1 hour, add hydroquinone to obtain polyethylene with low polymerization degree;

[0055] S22: adding ethylene into the reactor, and at the same time adding cinnamic acid into the reactor, reacting for 2 hours under the pressure of 0.2MPa and temperature of 70°C to obtain intermediate E;

[0056] S23: Add intermediate E to oligomeric polyethylene, add Ziegler-Natta initiator, control the pressure at 0.3MPa, react at 60°C for 3h, soak it in threonine solution for 12h, an...

Embodiment 2

[0065] This embodiment is a corrosion-resistant plastic rope, comprising the following steps:

[0066] S1: 75 parts of modified polyethylene, 15 parts of plant cellulose fiber, 18 parts of plasticizer, 1 part of foaming agent, 2 parts of corrosion inhibitor and 1 part of dispersant are mixed to obtain a blend;

[0067] Wherein the preparation process of modified polyethylene is as follows:

[0068] S21: Add ethylene to the reactor, add catalyst, control the pressure at 0.2MPa and temperature at 65°C, react for 2 hours, add hydroquinone to obtain polyethylene with low polymerization degree;

[0069] S22: Add ethylene into the reactor, and at the same time add cinnamic acid into the reactor, and react for 2 hours under the pressure of 0.2 MPa and temperature of 75° C. to obtain intermediate E;

[0070] S23: Add intermediate E to oligomeric polyethylene, add Ziegler-Natta initiator, control the pressure at 0.3MPa, react at 70°C for 3h, soak it in threonine solution for 12h, and ...

Embodiment 3

[0079] This embodiment is a corrosion-resistant plastic rope, comprising the following steps:

[0080] S1: 80 parts of modified polyethylene, 20 parts of plant cellulose fiber, 20 parts of plasticizer, 2 parts of foaming agent, 3 parts of corrosion inhibitor and 2 parts of dispersant are mixed to obtain a blend;

[0081] Wherein the preparation process of modified polyethylene is as follows:

[0082] S21: Put ethylene into the reactor, add a catalyst, control the pressure at 0.5 MPa and the temperature at 75°C, react for 3 hours, add hydroquinone to obtain polyethylene with low polymerization degree;

[0083] S22: adding ethylene into the reactor, and at the same time adding cinnamic acid into the reactor, reacting for 3 hours under the pressure of 0.3MPa and temperature of 80°C to obtain intermediate E;

[0084] S23: Add intermediate E to oligomeric polyethylene, add Ziegler-Natta initiator, control the pressure at 0.4MPa, react at 80°C for 4 hours, soak it in threonine solu...

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Abstract

The invention discloses a corrosion-resistant plastic rope and a production process thereof. The production process comprises the steps of mixing modified polyethylene, plant cellulose fibers, a plasticizer, a foaming agent, a corrosion inhibitor and a dispersing agent to obtain a blended material, putting the blended material into a film blowing machine to prepare a plastic film, cutting the plastic film into a plurality of plastic tapes, twisting the plastic tapes by a twisting machine, obtaining a plastic rope, baking the plastic rope, cooling the plastic rope to the room temperature through cold air cooling, and obtaining the anti-corrosion plastic rope. By baking the twisted plastic rope added with the plasticizer, the connection strength between plastic tapes is enhanced, gaps in the plastic rope are reduced, the compactness of the plastic rope is improved, the breaking strength of the plastic rope is improved, and alkyl active free radicals generated in oxidative degradation of modified polyethylene are captured by adding the corrosion inhibitor, so that chain reaction is inhibited to achieve the anti-corrosion effect.

Description

technical field [0001] The invention relates to the technical field of plastic ropes, in particular to a corrosion-resistant plastic rope and a production process thereof. Background technique [0002] As a common tool, rope has been widely used in many fields. With the rapid development of industry and commerce today, people have higher and higher quality requirements for rope. Plastic rope is a low-cost and easy-to-process rope. It has been favored by people in many fields; [0003] However, due to the limitation of the raw material properties of the existing plastic rope, plastic deformation will occur when the external force is applied. After the external force disappears, due to the offset of the intermolecular functional groups, it is difficult to achieve the original recovery, resulting in a decrease in the tensile strength of the plastic rope and a long service life. Shorter, and the plastic rope is prone to corrosion and aging under the influence of light, resultin...

Claims

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Application Information

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IPC IPC(8): C08L87/00C08L1/02C08K5/3432C08J9/10C08J9/00D07B1/14
CPCC08J9/0028C08J9/0061C08J9/103C08J2387/00C08J2401/02C08K5/3432D07B1/141D07B2205/2014D07B2401/2025
Inventor 李云飞李新新郭之全刘磊
Owner 安徽乙纤新材料科技有限公司
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