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Modifier for improving stability of steel slag aggregate and preparation method thereof

A technology of stability and modifier, applied in the field of modifier for improving the stability of steel slag aggregate and its preparation, can solve the problems of cracking of asphalt mixture, affecting driving safety, forming grooves on the road surface, etc., to prevent the asphalt layer Peeling, good physical properties, the effect of preventing the intrusion of external water

Pending Publication Date: 2021-10-29
CHANGAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the research and actual engineering, it is found that when steel slag is used in asphalt mixture instead of aggregate, the asphalt coated on the surface will peel off under long-term load, and the exposed steel slag will experience volume expansion and other adverse phenomena when it meets water. It is caused by the hydration reaction of free calcium oxide contained in steel slag when it encounters water. The volume expansion will generate expansion stress, which will easily cause the asphalt mixture to crack from the inside, thereby causing damage to the road surface and affecting driving safety; untreated steel slag It replaces the aggregate to prepare asphalt mixture. Since there are tiny pores on the surface of the steel slag, it cannot be fully covered by the asphalt, so the adhesion with the asphalt is poor, and it is easy to cause the asphalt to peel off during use and the steel slag is exposed, and the road surface is oxidized by the steel slag. However, redness, grooves on the road surface and other undesirable phenomena

Method used

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  • Modifier for improving stability of steel slag aggregate and preparation method thereof
  • Modifier for improving stability of steel slag aggregate and preparation method thereof
  • Modifier for improving stability of steel slag aggregate and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A method for preparing a modifier for improving the stability of steel slag aggregates, comprising the following steps:

[0032] Step 1, place 45% ethanol at room temperature, add 20% epoxy resin, 10% silane coupling agent KH550, 5% AEP curing agent, 5% GR-928 curing accelerator, 5% ACR toughening agent and PVC composite lead salt stabilizer, shear at a speed of 5000r / min for 30min at room temperature to obtain a primary shear mixture;

[0033] Step 2, add 3% boron nitride in the described primary shearing mixture, shear 12min, then add 2% 2-hydroxyl-4-methoxy benzophenone and PVC compound lead salt stabilizer, continue shearing Cut for 18 minutes to obtain a secondary shear mixture; wherein, the shear speed is 5000r / min; boron nitride is conventional industrial hexagonal boron nitride; the standard for 2-hydroxy-4-methoxybenzophenone is content≥ 99%, loss on drying ≤0.2%, ash content ≤0.1%. The total consumption of the PVC composite lead salt stabilizer in the step 1...

Embodiment 2

[0040] Adopt the modifying agent gained in embodiment 1 to prepare modified steel slag asphalt mixture, specifically:

[0041] Apply 500mL modifier to 5kg steel slag (including 3-10mm coarse steel slag and 0-3mm fine steel slag) by mixing method, and then mix with 1kg asphalt, 4.1kg stone (including 10-15mm limestone, 10-13mm limestone and 5- 10mm limestone), 0.9kg ore powder and mix to obtain. Among them, the asphalt adopts straight run 70# asphalt for road; the aggregate gradation in the modified steel slag asphalt mixture is 10-15mm limestone: 10-13mm limestone: 5-10mm limestone: 3-10mm coarse steel slag: 0-3mm fine steel slag : Mineral powder = 12:7:22:20:30:9.

Embodiment 3

[0043] Adopt the modifying agent gained in embodiment 1 to prepare modified steel slag asphalt mixture, specifically:

[0044] Apply 200mL modifier to 5kg steel slag (including 3-10mm coarse steel slag and 0-3mm fine steel slag) by mixing method, and then mix with 1kg asphalt, 4.1kg stone (including 10-15mm limestone, 10-13mm limestone and 5- 10mm limestone), 0.9kg ore powder and mix to obtain. Among them, the asphalt adopts straight run 70# asphalt for road; the aggregate gradation in the modified steel slag asphalt mixture is 10-15mm limestone: 10-13mm limestone: 5-10mm limestone: 3-10mm coarse steel slag: 0-3mm fine steel slag : Mineral powder = 12:7:22:20:30:9.

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Abstract

The invention belongs to the field of road building materials, and discloses a modifier for improving stability of steel slag aggregate and a preparation method thereof, the modifier comprises the following preparation raw materials: ethanol, resin, a silane coupling agent, a curing agent, a curing accelerator, a flexibilizer, a stabilizer, boron nitride, and 2-hydroxy-4-methoxybenzophenone. The modifier is an oil-soluble interface modifier, a layer of micron-level film can be plated on the surface of the steel slag and is compact and uniform, and the prepared modified steel slag is low in water absorption rate and good in volume stability; the obtained modified steel slag is mixed with asphalt, the effect of improving the adhesion performance of the aggregate and the asphalt is achieved through physical and chemical changes, the adhesion level can reach level 5, and the pavement performance of the obtained modified steel slag asphalt mixture is superior to that of an asphalt mixture with stone as the aggregate; and the preparation method is simple and easy to operate and implement.

Description

technical field [0001] The invention relates to the field of road building materials, in particular to a modifier for improving the stability of steel slag aggregates and a preparation method thereof. Background technique [0002] Nowadays, with the continuous development of my country's road industry, the increasing amount of road construction drives the rapid consumption of natural stone, which directly leads to the frequent occurrence of bad phenomena such as the destruction of the mountain ecological environment and the shortage of natural resources. As one of the industrial by-products of the steelmaking industry, steel slag has a low secondary utilization rate, resulting in a large amount of steel slag accumulation, making steel slag an industrial waste that is difficult to handle. In view of the above two problems, it is proposed to use steel slag instead of natural stone as aggregate in asphalt mixture. Steel slag has good angularity, high hardness and high rigidity...

Claims

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Application Information

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IPC IPC(8): C08L63/00C08L33/04C08K3/38C08K5/132C04B20/10
CPCC08L63/00C04B20/1055C08K2003/385C08L33/04C08K3/38C08K5/132C04B20/1051C04B20/1037C04B20/1022C04B20/1033C04B18/142
Inventor 黄山陈惠坤刘凯赵晨昊牛冬瑜田耀刚耿九光陈星宇郭佳乐
Owner CHANGAN UNIV
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