Catalyst for synthesizing 1-octylene and application thereof
A catalyst and main catalyst technology, applied in catalytic reaction, organic compound/hydride/coordination complex catalyst, physical/chemical process catalyst, etc., can solve the problems of low possibility of implementation and high cost of raw materials, and achieve the The effect of backward and cumbersome process, high catalyst activity and high yield
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[0051] In the present invention, the preparation method of the ligand, that is, a compound containing P and C, preferably includes:
[0052] After mixing the P-containing compound, the solvent and triethylamine, adding the C-containing compound and mixing to obtain a mixed solution;
[0053] reacting the mixed solution to obtain the ligand;
[0054] The molar ratio of the C-containing compound to the P-containing compound is 1: (1.1-3);
[0055] The solvent is at least one selected from n-hexane, cyclohexane, tetrahydrofuran, dichloromethane and toluene.
[0056] In the present invention, the P-containing compound is preferably selected from at least one of chlorodiphenylphosphine, phenylphosphine dichloride, di-p-tolylphosphine chloride, dicyclohexylphosphine chloride and trialkylphosphine kind.
[0057] In the present invention, the C-containing compound is preferably at least one selected from ethane, propane, n-butane, isobutane, cyclopentane, cyclohexane and phenyl alk...
Embodiment 1
[0102] Put 6ml of phenylphosphine dichloride, 60ml of dichloromethane and 15ml of triethylamine in an anaerobic and anhydrous flask filled with high-purity nitrogen, mix well at 0-20°C, add 1.2ml of ethyl alcohol alkane, stirred at 0-20°C for 0.2-2h to obtain a mixed solution; adjusted the temperature of the mixed solution to -35°C, stirred and reacted for 2h, and then suction-filtered the obtained reaction product under normal temperature and vacuum conditions, If the solution is not clear and transparent after suction filtration, it should be repeatedly suction filtered until it becomes clear; use a rotary evaporator to carry out rotary evaporation of the above clarified solution after suction filtration at 40-100°C under vacuum until the liquid is in the shape of quicksand; The steamed product was recrystallized with methanol to obtain the ligand of the compound containing P and C; the yield of the ligand was 75%.
[0103] The calculation method of ligand yield is:
[0104...
Embodiment 2
[0107]Put 15ml of diphenylphosphine chloride, 60ml of dichloromethane and 15ml of triethylamine in an anaerobic and anhydrous flask filled with high-purity nitrogen, mix well at 0-20°C, add 2.0ml of iso butane, stirred at 0-20°C for 0.2-2h to obtain a mixed solution; adjusted the temperature of the mixed solution to -20°C, stirred and reacted for 4h, and then suction-filtered the obtained reaction product under normal temperature and vacuum conditions, If the solution is not clear and transparent after suction filtration, it should be repeatedly suction filtered until it becomes clear; use a rotary evaporator to carry out rotary evaporation of the above clarified solution after suction filtration at 40-100°C under vacuum until the liquid is in the shape of quicksand; The steamed product was recrystallized with methanol to obtain the ligand of the compound containing P and C; the yield of the ligand was 77%.
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