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Negative plate, preparation method of negative plate, and lithium ion battery

A technology of negative electrode sheet and conductive agent, applied in electrode manufacturing, battery electrodes, secondary batteries, etc., can solve problems such as increasing the contact distance between the underlying active material and the electrolyte, the battery capacity cannot function normally, and prolonging the migration path of lithium ions. , to improve the liquid absorption efficiency, reduce the phenomenon of lithium precipitation, and improve the peel strength.

Pending Publication Date: 2021-12-03
HUBEI JINQUAN NEW MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, one way to increase the energy density of batteries is to increase the mass percentage of active materials or increase the thickness of the pole piece to increase the mass percentage of active materials, but the design of the thick pole piece increases the gap between the bottom active material and the electrolyte. The contact distance prolongs the migration path of lithium ions, so that during the charging and discharging process of the battery, lithium ions cannot reach the bottom of the pole piece smoothly and quickly, forming a large concentration polarization, which in turn causes the battery capacity to fail to function normally and the pole piece to peel off A series of problems such as strength decline, poor rate performance, low-temperature lithium precipitation, cycle capacity fading, etc.

Method used

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  • Negative plate, preparation method of negative plate, and lithium ion battery
  • Negative plate, preparation method of negative plate, and lithium ion battery
  • Negative plate, preparation method of negative plate, and lithium ion battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] The current collector 11 of the negative electrode sheet 1 is made of copper foil, and the thickness of the copper foil is 10um;

[0051] The active main material, conductive agent, thickener, and binding agent of the first slurry are 90%:1%:4.5%:4.5% according to mass ratio, and the active main material, conductive agent, thickener of the second slurry , binder is 95%: 1%: 2%: 2% according to mass ratio, wherein, the active main material of the first slurry adopts the graphite of particle diameter 4um, the active main material of the second slurry adopts the graphite of particle diameter 15um. Graphite, the conductive agent of the first slurry and the second slurry adopts spherical conductive carbon black, and the binder content of the first slurry is 2.25 times of the binder content of the second slurry;

[0052] The thickness of the first coating 12 of the negative electrode sheet 1 is 90um, and the thickness of the first coating 12 is 50% of the coating thickness of...

Embodiment 2

[0059] The current collector 11 of the negative electrode sheet 1 is made of copper foil, and the thickness of the copper foil is 10um;

[0060] The active main material, conductive agent, thickener, and binding agent of the first slurry are 90%:1%:4.5%:4.5% according to mass ratio, and the active main material, conductive agent, thickener of the second slurry , binder is 95%: 1%: 2%: 2% according to mass ratio, wherein, the active main material of the first slurry adopts the graphite of particle diameter 4um, the active main material of the second slurry adopts the graphite of particle diameter 15um. Graphite, the conductive agent of the first slurry and the second slurry adopts spherical conductive carbon black, and the binder content of the first slurry is 2.25 times of the binder content of the second slurry;

[0061] The thickness of the first coating 12 of the negative electrode sheet 1 is 90um, and the thickness of the first coating 12 is 30% of the coating thickness of...

Embodiment 3

[0068] The current collector 11 of the negative electrode sheet 1 is made of copper foil, and the thickness of the copper foil is 10um;

[0069] The active main material, conductive agent, thickener, and binding agent of the first slurry are 92%:1%:4%:3% according to the mass ratio, and the active main material, conductive agent, thickener of the second slurry , binder according to mass ratio is 96.5%: 0.5%: 1.5%: 1.5%, wherein, the active main material of the first slurry adopts the graphite of particle diameter 4um, the active main material of the second slurry adopts the graphite of particle diameter 20um Graphite, the conductive agent of the first slurry and the second slurry adopts spherical conductive carbon black, and the binder content of the first slurry is 2 times of the binder content of the second slurry;

[0070] The thickness of the first coating 12 of the negative electrode sheet 1 is 90um, and the thickness of the first coating 12 is 50% of the coating thicknes...

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Abstract

The invention discloses a negative plate, a preparation method of the negative plate, and a lithium ion battery. The negative plate comprises a current collector and a coating structure, the coating structure is at least arranged on one side surface of the current collector, the coating structure comprises a first coating and a second coating, the first coating is located between the current collector and the second coating, the first coating is made of first slurry, the second coating is made of second slurry, and the particle size of the first slurry is smaller than that of the second slurry. According to the negative plate, the first slurry and the second slurry are simultaneously coated to form the coating structure, the coating thickness of the slurries is uniform, the resistance of the negative plate can be remarkably reduced, the peel strength can be improved, the particle size of the inner layer is smaller than that of the outer layer, the porosity of the surface layer of the negative plate can be remarkably improved, and the liquid absorption efficiency of the electrolyte of the negative plate is improved.

Description

technical field [0001] The invention relates to the technical field of batteries, in particular to a negative electrode sheet, a preparation method of the negative electrode sheet and a lithium ion battery. Background technique [0002] Lithium-ion batteries have the advantages of high operating voltage, high energy density, long cycle life and environmental protection, and are widely used in electric vehicles. With the development of electric vehicles, the requirements for the cruising range, charging speed and safety performance of electric vehicle batteries are getting higher and higher. It is imminent to develop a high-energy, high-power and safe lithium-ion battery. [0003] At present, one way to increase the energy density of the battery is to increase the mass percentage of the active material or increase the thickness of the pole piece to increase the mass percentage of the active material, but the design of the thick pole piece increases the gap between the bottom ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/13H01M4/139H01M4/36H01M4/04H01M10/0525H01M10/058
CPCH01M4/13H01M4/366H01M4/139H01M10/058H01M10/0525H01M4/0435H01M4/0404H01M4/0471Y02E60/10Y02P70/50
Inventor 孙伟兵杜双龙师渝滔伍山松陈思熊后高
Owner HUBEI JINQUAN NEW MATERIALS CO LTD
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