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High-flowability flame-retardant nylon slice for thin-wall glass fabric composite material as well as preparation method and application of high-flowability flame-retardant nylon slice

A composite material and flame-retardant nylon technology, which is applied in the field of high-flow flame-retardant nylon chips for thin-wall glass fiber cloth composite materials and their preparation, which can solve the problem of low flame-retardant efficiency, decreased mechanical properties of finished products, easy moisture absorption, etc. problem, to achieve the effect of good flame retardancy, good dispersion and high mechanical strength

Active Publication Date: 2021-12-28
上海安凸塑料添加剂有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] For red phosphorus, the advantages are high flame retardant efficiency and small amount of addition, so it has little impact on product performance, but it faces two problems: one is the color of red phosphorus, which limits its application range, and is usually only used in black products; Second, it is easy to produce highly toxic substances such as phosphine during the processing process, which brings environmental protection and safety problems. Therefore, red phosphorus is not the best choice for glass fiber reinforced nylon materials
The main disadvantage is that it is easy to absorb moisture, which causes inconvenience in use. At the same time, due to the low efficiency of melamine polyphosphate in charring and low flame retardancy, the addition of melamine polyphosphate is relatively large, resulting in a decline in the mechanical properties of the finished product.

Method used

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  • High-flowability flame-retardant nylon slice for thin-wall glass fabric composite material as well as preparation method and application of high-flowability flame-retardant nylon slice
  • High-flowability flame-retardant nylon slice for thin-wall glass fabric composite material as well as preparation method and application of high-flowability flame-retardant nylon slice
  • High-flowability flame-retardant nylon slice for thin-wall glass fabric composite material as well as preparation method and application of high-flowability flame-retardant nylon slice

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0059] A preparation method for nylon slices, the method comprising the steps of:

[0060] (1) Mix inorganic hypophosphite, synergistic flame retardant, antioxidant, dispersant, compatibilizer and flow modifier in a high mixer for 2-5 minutes;

[0061] (2) Mix the obtained mixture with nylon 6 slices in a high mixer for 5-15 minutes;

[0062] (3) Put the obtained mixture into a twin-screw extruder, melt blending and extruding and granulate, wherein, when melt blending and extruding, the temperature of the melting section is set as: feeding port 220°C, conveying section 250°C ℃, meshing section 240-245℃, exhaust section 210℃, machine head 235℃, feeding speed 15-35r / min, host speed 250-400 r / min, cutting speed 1500-3500r / min.

[0063] The application of nylon slices, the nylon slices are used to prepare thin-walled glass fiber cloth composite materials, the specific method is: after the nylon slices are dried, the nylon slices are pressed with the glass fiber cloth by a tableti...

Embodiment 1

[0066] A high-flow flame-retardant nylon chip used for glass fiber cloth composite materials, by weight, includes the following components:

[0067]

[0068] A kind of preparation method for the high-flow flame-retardant nylon slice that is used for glass fiber cloth composite material comprises the steps:

[0069] Step 1: Mix the above-mentioned inorganic hypophosphite, synergistic flame retardant, antioxidant, dispersant, compatibilizer, and flow modifier A in a high-speed mixer for 2-5 minutes.

[0070] Step 2, the mixture obtained in the above step 1 is mixed with nylon in a high mixer, and the mixing time is 5-15min.

[0071] Step 3, the mixture obtained in the above step 2 is melt blended and extruded by a twin-screw extruder and pelletized.

[0072] The preparation method of the above-mentioned halogen-free flame-retardant masterbatch, wherein, the temperature of the melting section during the melt blending and extrusion of the step 3 is set as the feeding port-220°...

Embodiment 2

[0074] A high-flow flame-retardant nylon chip used for glass fiber cloth composite materials, by weight, includes the following components:

[0075]

[0076] The preparation method of high-flow flame-retardant nylon chip, step is the same as embodiment 1

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Abstract

The invention relates to a high-flowability flame-retardant nylon slice for a thin-wall glass fabric composite material and a preparation method and application thereof, the nylon slice is prepared from the following raw materials in parts by mass: 50-90 parts of nylon slice, 14-45 parts of inorganic hypophosphite, 2-8 parts of synergistic flame retardant, 1-8 parts of antioxidant, 1-8 parts of dispersing agent, 1-8 parts of compatilizer and 1-8 parts of flow modifier A, the nylon slice is applied to the preparation of the thin-wall glass fabric composite material, and the specific method comprises the following steps: drying the nylon slice, and pressing the nylon slice and glass fabric through a tabletting device to form the thin-wall glass fabric composite material. Compared with the prior art, the halogen-free flame-retardant glass fiber reinforced nylon prepared by the invention has an excellent flame-retardant effect, can reach the flame-retardant standard of UL94-V0 (0.2-1mm), and has excellent mechanical properties.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a high-flow flame-retardant nylon slice for a thin-walled glass fiber cloth composite material and a preparation method and application thereof. Background technique [0002] With the development of polymer material science, polymer materials are more and more widely used in people's daily production and life. At present, in the field of new energy vehicles and aerospace, flame-retardant composite materials of glass fiber mat or carbon fiber mat have more and more uses. In the case of ensuring mechanical strength, flame-retardant composite materials of glass fiber mat or carbon fiber mat are relatively Or ceramic materials are lighter and cheaper. [0003] The materials used for composite glass fiber mat or carbon fiber mat are mainly divided into thermosetting plastics and thermoplastics. The processing conditions of thermosetting plastic composite products are relat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08K3/32C08K5/5313B29B9/06
CPCC08K3/32C08K5/5313B29B9/06C08L2201/02C08L77/02
Inventor 付常俊王俊锦古哈尔娅·伊孜丁袁丽菊
Owner 上海安凸塑料添加剂有限公司
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