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Rubber sealing material for bearing and resisting mixed fuel system and preparation process of rubber sealing material

A hybrid fuel system and rubber sealing technology, applied in the field of rubber sealing materials, can solve the problems of low hardness, not meeting the basic requirements of sealing materials, etc., and achieve the effects of improving aging resistance, enhancing oil resistance, and excellent mechanical properties.

Pending Publication Date: 2022-01-07
南阳天一密封股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The NBR / PVC composition has good tolerance to n-hexane, linseed oil and 2# kerosene, but its hardness is too low and does not meet the basic requirements of sealing materials

Method used

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  • Rubber sealing material for bearing and resisting mixed fuel system and preparation process of rubber sealing material
  • Rubber sealing material for bearing and resisting mixed fuel system and preparation process of rubber sealing material
  • Rubber sealing material for bearing and resisting mixed fuel system and preparation process of rubber sealing material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Weigh the raw materials shown in Table 1 and Table 2 respectively, and set them aside; add NBR rubber and PVC resin to the internal mixer, heat up to 80°C, pre-mix at 70r / min for 25min, continue to heat up to 155°C, 200r / min Mix for 12 minutes to obtain the first mixture; keep the temperature constant, add vulcanizing agent and activator to the first mixture, and mix for 8 minutes; continue to add protective agent, reinforcing agent and softener, and mix for 8 minutes; then add Filler and other additives, mixed for 8 minutes; at the temperature of the rollers of the mill at 50°C±5°C, the speed ratio of the rollers of the mill is 1:1.27, the line speed of the front roller is 23.44m / min, and the vulcanization aid is added , kneading for 2 minutes, the left and right three-quarter cutters each three times, then adjust the roller distance below 1mm, thin pass and make a triangle bag six times, loosely fall off, the thickness of the rubber material is controlled between 3-4mm...

Embodiment 2

[0038] Weigh the raw materials shown in Table 1 and Table 2 respectively, and set them aside; add NBR rubber and PVC resin to the internal mixer, heat up to 75°C, pre-mix at 80r / min for 20min, continue to heat up to 145°C, 300r / min Mix for 15 minutes to obtain the first mixture; keep the temperature constant, add vulcanizing agent and activator to the first mixture, and mix for 10 minutes; continue to add protective agent, reinforcing agent and softener, and mix for 5 minutes; then add Filler and other additives, mixed for 5 minutes; at the temperature of the roll of the mill at 50°C±5°C, the speed ratio of the roll of the mill is 1:1.27, the line speed of the front roll is 23.44m / min, add the vulcanization aid , kneading for 2 minutes, the left and right three-quarter cutters each three times, then adjust the roller distance below 1mm, thin pass and make a triangle bag six times, loosely fall off, the thickness of the rubber material is controlled between 4-5mm, and stand stil...

Embodiment 3

[0040] Weigh the raw materials shown in Table 1 and Table 2 respectively, and set them aside; add NBR rubber and PVC resin to the internal mixer, heat up to 85°C, pre-mix at 50r / min for 30min, continue to heat up to 160°C, 120r / min Mix for 10 minutes to obtain the first mixture; keep the temperature constant, add vulcanizing agent and activator to the first mixture, and mix for 5 minutes; continue to add protective agent, reinforcing agent and softener, and mix for 10 minutes; then add Filler and other additives, mixed for 10min; at the temperature of the roll of the mill at 50°C±5°C, the speed ratio of the roll of the mill is 1:1.27, the line speed of the front roll is 23.44m / min, add vulcanization aid , kneading for 2 minutes, the left and right three-quarter cutters each three times, then adjust the roller distance below 1mm, thin pass and make a triangle bag six times, loosely fall off, the thickness of the rubber material is controlled between 3.5-4.5mm, and stand for 24 h...

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Abstract

The invention provides a rubber sealing material for a bearing and resisting a mixed fuel system, and belongs to the technical field of rubber sealing materials. The rubber sealing material for bearing and resisting the mixed fuel resistant system is prepared from NBR rubber, PVC resin, a vulcanizing agent, a vulcanizing auxiliary agent, an activator, a protective agent, a reinforcing agent, a softener, a filler and other auxiliary agents. The vulcanizing agent is at least one of sulfur and 1,3-bis(tert-butylperoxydiisopropyl)benzene. The vulcanizing auxiliary agent is at least one of tetramethylthiuram disulfide, N-cyclohexyl-2-benzothiazole sulfenamide, dibenzothiazole disulfide and N-tert-butyl-2-benzothiazole sulfenamide. The activating agent is at least one of zinc oxide and stearic acid. The protective agent is at least one of N-phenyl-alpha-naphthylamine, N-isopropyl-N'-phenyl-p-phenylenediamine and 4,4'-bis(alpha,alpha-dimethyl benzyl)diphenylamine. According to the technical scheme, the oil resistance is improved.

Description

technical field [0001] The invention belongs to the technical field of rubber sealing materials, and in particular relates to a rubber sealing material for bearing mixed fuel systems and a preparation process thereof. Background technique [0002] With the development of the automobile industry in the direction of high performance, low fuel consumption, low emission, low noise and long service life, automobile fuel oil, lubricating oil, refrigerant, etc. are also continuously improved. In recent years, due to the increasing shortage of petroleum resources and people's higher requirements for automobile exhaust emission standards, automobile fuels have been diversified. In addition to traditional automobile fuels (gasoline and diesel), there have also been gaseous fuels ( Natural gas, petroleum liquefied gas, hydrogen, etc.), oxygenated fuels (methanol, dimethyl ether, etc.), biodiesel and mixed fuels (alcohol-containing gasoline, emulsified diesel, etc.) and other new altern...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L9/02C08L27/06C08K3/06C08K5/14C08K3/04C08K7/26C08K5/12C08K5/18C08K13/04
CPCC08L9/02C08L2201/08C08K2201/014C08L27/06C08K3/06C08K5/14C08K3/04C08K7/26C08K5/12C08K5/18C08K13/04
Inventor 樊红星刘元英刘彩虹李江涛马雷曹正理朱建波李蕾
Owner 南阳天一密封股份有限公司
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