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Composite pipeline for hydrogen conveying and hydrogen leakage monitoring method

A composite pipeline and hydrogen technology, applied in the pipeline system, gas/liquid distribution and storage, mechanical equipment, etc., can solve the problems of hydrogen diffusion loss, rapid detection and repair, and different detection accuracy, so as to reduce hydrogen transmission loss and prevent Escape at will and improve the safety factor

Active Publication Date: 2022-04-29
ZHEJIANG UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, Monel alloy is used to produce hydrogen pipelines, which have excellent physical properties of high strength, high corrosion resistance, and wear resistance, but for long-distance hydrogen transmission, the technology of using Monel alloy pipelines is complicated and the cost is too high. high, difficult to mass-produce
[0005] Due to the small size of hydrogen gas molecules, the diffusion speed of hydrogen gas is extremely fast, and it is odorless, colorless, and tasteless. The explosion limit range is extremely wide (4% to 75.6%), and the minimum ignition energy of hydrogen gas is only 0.017mJ. Therefore, pipelines are used to transport hydrogen gas At present, there are the following problems: the diffusion loss of hydrogen at the pipeline connection, the current diffusion loss of hydrogen is about three times that of natural gas; due to the high purity required for hydrogen transportation, it is not suitable to add other gases to make the transport gas visible and audible. Once hydrogen leaks, it will dissipate quickly when it enters the air directly from the leak point, which will easily lead to the situation that the concentration is too low to be monitored by the sensor, and it is difficult to be quickly detected and repaired by the staff; the lower explosion limit of hydrogen is low, and the leakage It is easy to form an explosive mixture in the air, and it is easy to burn and explode in case of open flame, high temperature and high heat
[0007] However, there are certain barriers to each technology
Commonly used non-destructive testing techniques include ultrasonic testing, X or γ-ray testing, magnetic particle testing, and penetrant testing, etc. These testing methods cannot monitor in real time and cannot determine the specific location of defects. The detection has potential safety hazards and high detection cost. Magnetic particle detection is only suitable for steel pipelines, etc.; commonly used state monitoring technologies include monitoring technologies for state parameters such as temperature, pressure, and flow. These monitoring technologies can be monitored in real time, but the detection accuracy will vary with time. Depending on the equipment, it is difficult to achieve the detection accuracy of a small amount of hydrogen leakage; leakage monitoring can be realized by arranging gas sensors on the ground, but this method can only be monitored at fixed points, and hydrogen has the characteristics of fast diffusion, so the leakage of hydrogen diffusion If the final concentration is too low, it is difficult for the sensor to achieve such a high sensitivity, and thus cannot be detected in time

Method used

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  • Composite pipeline for hydrogen conveying and hydrogen leakage monitoring method
  • Composite pipeline for hydrogen conveying and hydrogen leakage monitoring method
  • Composite pipeline for hydrogen conveying and hydrogen leakage monitoring method

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preparation example Construction

[0052] The preparation process of the composite pipeline for hydrogen transportation of the present invention is divided into three steps:

[0053] First, prepare the inner plastic pipe: set the heating temperature of each section of the main barrel and head of the plastic extruder. The overall temperature is within 175~225°C, and the heating temperature adjustment range of each section is ±10°C. After reaching the set temperature, Constant temperature for 90-150 minutes; when the heating temperature of the barrel and each section of the machine head reaches the set temperature (±2°C) and there is no significant change within the constant temperature period, start the machine, first start the main engine screw to run at a low speed (5-10r / min), and then Start the feeder screw to feed at low speed (5-10r / min); add the start-up material first, and then add the conventional production material (PE100) to extrude the pipe after the extrusion is normal; after the extrusion pipe trac...

specific Embodiment 1

[0057] The composite pipeline of the present invention adopted in the pipeline of a certain hydrogen transportation pipeline has an overall structure such as Figure 4shown. Specific parameters of the pipe: the nominal diameter of the inner plastic pipe is 600mm, the outer diameter is 630mm, and the wall thickness is 10mm; the thickness of the polyurethane foam layer in the middle layer is 15mm; the inner diameter of the outer plastic protective layer is 660mm, and the thickness is 10mm. According to the specific parameters, use the factory assembly line to produce composite pipes: First, the production process of the inner plastic pipe: set the heating temperature of each section of the plastic extruder host barrel and head, the overall temperature is within 220 °C, and the heating temperature adjustment range of each section is ±10°C, after reaching the set temperature, keep the temperature constant for 120 minutes; when the heating temperature of the barrel and each section...

specific Embodiment 2

[0060] The structure of a long-distance hydrogen transport pipeline is as follows: Figure 4 As shown, the specific structural dimensions of the pipe are as follows: the nominal diameter of the inner plastic pipe is 300mm, the outer diameter is 325mm, and the wall thickness is 8mm; the thickness of the polyurethane foam layer in the middle layer is 10mm; the inner diameter of the outer plastic protective layer is 345mm , the thickness is 5mm. The specific conditions for the hydrogen transportation of the pipeline are: the pressure is 1.8MPa, and the flow rate is about 2160m3 / h. During the operation of the pipeline, worker B2 heard the alarm sound, and observed the hydrogen concentration curve of the signal receiver and processor at the corresponding time, and found that the equipment detected a jump in the hydrogen concentration. Worker B2 immediately checks the hydrogen concentration curve of the whole pipeline at the corresponding time, such as Figure 9 Shown; After obser...

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Abstract

The invention relates to the field of hydrogen conveying pipelines, in particular to a composite pipeline device for hydrogen conveying and capable of monitoring hydrogen leakage in a full-pipeline mode in real time and a method for monitoring hydrogen leakage in the full-pipeline mode. The novel composite pipeline structure for hydrogen conveying comprises a plastic pipeline, a polyurethane foaming layer and a plastic protection layer, and the plastic pipeline, the polyurethane foaming layer and the plastic protection layer are sequentially arranged from inside to outside. The invention also provides a monitoring system formed by arranging sensors at specific positions by using the composite pipeline device, and provides a monitoring method for a real-time hydrogen conveying pipeline, so that real-time full-pipeline monitoring of the hydrogen conveying pipeline is realized. The composite pipeline for hydrogen conveying can effectively prevent hydrogen leakage and diffusion, reduces hydrogen conveying loss caused by leakage, slows down the situation that hydrogen leaks into air, improves the safety coefficient, avoids the situation that a sensor cannot detect the situation due to the fact that hydrogen escape is too fast and the hydrogen concentration is too low, and improves the safety coefficient. And effective monitoring of the whole pipeline is realized.

Description

technical field [0001] The invention relates to the field of the hydrogen delivery pipeline, in particular to a composite pipeline for hydrogen delivery capable of real-time full-line monitoring of hydrogen leakage, and a device and method for full-line monitoring of hydrogen. Background technique [0002] In recent years, hydrogen energy, as a zero-carbon high-efficiency new energy, has become increasingly prominent in the world's energy transition. Major developed countries in the world have introduced policies to strongly support the development of the hydrogen energy industry in recent years. In 2020, my country will clearly include hydrogen energy in the energy category, which indicates an important step in the development of the hydrogen energy industry. [0003] In the hydrogen energy industry chain, the four very important links are hydrogen production, hydrogen storage, hydrogen transportation and hydrogen utilization. Among them, hydrogen transportation (hydrogen ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F17D5/06F17D5/00
CPCF17D5/06F17D5/005
Inventor 施建峰
Owner ZHEJIANG UNIV
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