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High-fraction functional gradient aluminum-based silicon carbide composite material and preparation method thereof

A technology of aluminum-based silicon carbide and functional gradient, which is applied in the direction of manufacturing tools, additive processing, ceramic molding machines, etc., can solve problems such as difficulty in precise forming of complex shapes, insufficient structural strength, and complicated processes, so as to facilitate commercial application, Fast and efficient filling, good infiltration effect

Active Publication Date: 2022-05-13
HUAZHONG UNIV OF SCI & TECH
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Problems solved by technology

However, the high-ratio aluminum-based silicon carbide gradient composites prepared by these methods have low density and many internal defects, and have disadvantages such as complex process, long cycle, high cost, difficult precise control of gradient components, and difficult precise forming of complex shapes, which greatly limit The development and application of high ratio Al-based SiC gradient composites
[0004] Although additive manufacturing technology can prepare complex parts, the structural strength of functionally graded materials is insufficient and cannot be directly used for load-bearing parts.

Method used

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  • High-fraction functional gradient aluminum-based silicon carbide composite material and preparation method thereof

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preparation example Construction

[0024] The invention provides a method for preparing a high-score functionally graded aluminum-based silicon carbide composite material, such as figure 1 As shown, it specifically includes the following steps S1-S5.

[0025] S1: Using additive manufacturing technology to print silicon carbide green blanks according to the three-dimensional structure of the gradient porous structure.

[0026] The first choice is to select the appropriate silicon carbide powder and binder for thorough mixing to obtain a uniformly mixed silicon carbide slurry.

[0027] The average particle size of the silicon carbide powder is 0.5-120 μm, and the mass ratio of the silicon carbide powder to the binder is (5-9):(1-3).

[0028] Further, the binder is preferably an organic binder such as thermoplastic epoxy resin powder, thermoplastic phenolic resin powder, thermoplastic nylon powder, liquid phenolic resin, or liquid photosensitive resin.

[0029] Then construct the three-dimensional structure of t...

Embodiment 1

[0048] In this embodiment, the high-score functionally graded aluminum-based silicon carbide composite material is mainly made of silicon carbide powder and aluminum alloy as the main raw materials, epoxy resin is used as the binder, and polycarbosilane is used as the precursor of the dipping and cracking process.

[0049] (a) choose green silicon carbide micropowder (D1=40 μ m), epoxy resin as the raw material of prefabricated part (wherein the content of epoxy resin accounts for 15% of the sum of epoxy resin and silicon carbide mass), the above-mentioned The said raw materials are poured into the mixer, fully mixed and then sieved to obtain uniformly mixed material powder;

[0050] (b) Use 3D modeling software to design a Primitive-type three-period minimal surface lattice structure with volume fraction gradually increasing from 60% to 40% at 10% intervals along the radius direction. The Primitive-type three-period minimal curved surface lattice structure can be divided into...

Embodiment 2

[0056] In this embodiment, the high-score functionally graded aluminum-based silicon carbide composite material is mainly made of silicon carbide powder and aluminum alloy as the main raw materials, epoxy resin is used as the binder, and polycarbosilane is used as the precursor of the dipping and cracking process.

[0057] (a) choose green silicon carbide micropowder (D2=70 μm), epoxy resin as the raw material of binder (wherein the content of epoxy resin accounts for 8% of the sum of epoxy resin and silicon carbide quality), the above-mentioned The said raw materials are poured into the mixer, fully mixed and then sieved to obtain uniformly mixed material powder;

[0058] (b) Use 3D modeling software to design a Diamond-type three-period minimal surface lattice structure with a volume fraction gradually increasing from 50% to 70% at 5% intervals along the z-axis. The Diamond-type three-period minimum surface lattice structure can be divided into 5 layers along the z-axis dire...

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Abstract

The invention belongs to the related technical field of composite materials, and discloses a high-fraction functional gradient aluminum-based silicon carbide composite material and a preparation method thereof.The method comprises the steps that S1, a silicon carbide biscuit is printed according to a three-dimensional structure of a gradient porous structure through an additive manufacturing technology; s2, sequentially carrying out low-temperature curing and medium-temperature carbonization treatment on the aluminum-based silicon carbide biscuit to obtain a gradient porous structure silicon carbide preform; s3, the gradient porous structure silicon carbide preform is infiltrated in a polycarbosilane solution, a polydimethylsilane solution or a hetero-element polycarbosilane solution and then subjected to high-temperature curing and cracking in sequence to generate a gradient porous structure silicon carbide ceramic body; s4, carrying out pre-oxidation treatment on the gradient porous structure silicon carbide ceramic body; and S5, filling the silicon carbide ceramic body with the gradient porous structure with liquid aluminum alloy to obtain the high-fraction functional gradient aluminum-based silicon carbide composite material. The preparation method can be used for preparing the high-fraction functional gradient aluminum-based silicon carbide composite material with a high-strength complex structure.

Description

technical field [0001] The invention belongs to the technical field related to composite materials, and more specifically relates to a high-score functionally graded aluminum-based silicon carbide composite material and a preparation method thereof. Background technique [0002] Aluminum-based silicon carbide has excellent properties such as high specific modulus, high specific strength, corrosion resistance, high temperature resistance, and fatigue resistance, and has been widely valued by technicians from all over the world. Among them, silicon carbide, the matrix material in aluminum-based silicon carbide, has the advantages of wide source, low cost, and easy synthesis, and has become one of the important choices to replace traditional materials in composite materials. At present, aluminum-based silicon carbide composite materials have been widely used in the development of key components working under special conditions such as complex loads and environments in military ...

Claims

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Application Information

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IPC IPC(8): C22C1/10C22C21/00C22C32/00B28B1/00B33Y10/00B33Y70/10
CPCC22C1/1015C22C1/1036C22C21/00C22C32/0063B28B1/001B33Y10/00B33Y70/10C22C1/1021Y02P10/25
Inventor 闫春泽刘桂宙王长顺杨潇史玉升
Owner HUAZHONG UNIV OF SCI & TECH