Production process of halogen-free flame-retardant socket granules

A production process and socket technology, which is applied to the production process of halogen-free flame retardant socket pellets, can solve the problems of poor flame retardant application effect, etc., and achieve the effects of good processing fluidity, promotion of char formation, and prevention of molten droplets.

Pending Publication Date: 2022-08-09
泰力(安徽)电器股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

For example, CN201611108731.3 discloses the use of a large amount of antimony trioxide in a polycarbonate composition with flame retardant functi

Method used

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  • Production process of halogen-free flame-retardant socket granules

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Example Embodiment

[0019] Example 1

[0020] The first step is to weigh the following components according to parts by weight: 93 parts of LEXAN 101R PC polycarbonate resin, 1 part of Wacker SILRES604 phenyl methyl silicone resin, 1 part of phenyl phosphate, and phenyl phosphate is Suzhou Daba CR-741 bisphenol A bis(diphenyl phosphate), 0.5 part of titanium dioxide, 2 parts of AT-H841 phenolic resin sulfonate sodium salt, 0.5 part of light stabilizer, the light stabilizer is 2-(2 '-Hydroxyphenyl) benzotriazole UV-328, 0.5 part of ADDIMER 697 processing aid, 1.5 part of Dongzhuan ZB-2335 zinc borate; in the second step, the weighed materials are mixed evenly and dried at 100°C, The drying time is 4h; in the third step, the temperature of the first section of the extruder is 155℃, the temperature of the second section is 230℃, the temperature of the other sections is 235℃, the speed of the main machine is 200r / min, and the feeding frequency is 10r / min, extrusion blending and granulation: twin-sc...

Example Embodiment

[0021] Example 2

[0022] The first step, weigh the following components according to weight percentage: 86 parts of LEXAN 101R PC polycarbonate resin, 0.5 part of Wacker SILRES604 phenyl methyl silicone resin, 5 parts of phenyl phosphate, the phenyl phosphate is Suzhou University Eight mixtures of CR-741 bisphenol A bis(diphenyl phosphate) and Lihai Petrochemical triphenyl phosphate by weight of 1:2, 1 part of Chuntai R103 titanium dioxide, 3.2 parts of Taixing HT-207 zinc borate, 4 parts of AT-H841 phenolic resin sulfonic acid sodium salt, 0.1 part of light stabilizer, the light stabilizer is 2-hydroxy-4-n-octyloxybenzophenone brand UV-531, 2-(2'-hydroxyphenyl ) 1:2 mixture of benzotriazole brand UV-328 by weight, 0.2 part of ADDIMER RC75 processing aid; the second step, the weighed material is mixed and dried at 110 ° C, drying time 5h; the third Step. The temperature of the first stage of Zhejiang Wutian Machinery extruder is 180 °C, the temperature of the second stage is...

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Abstract

The invention provides a production process of halogen-free flame-retardant socket granules, and belongs to the technical field of flame-retardant socket materials.According to the production process of the halogen-free flame-retardant socket granules, polycarbonate is adopted as a main raw material, and phenyl methyl silicone resin, phenyl phosphate, phenyl methyl silicone resin and the like are adopted as auxiliary materials for flame-retardant blending extrusion granulation; the high-flame-retardant performance is achieved, the impact resistance and the electrical performance are good, and production and use of the socket are met; phosphorus phenyl phosphate, phenyl methyl silicone resin, phenyl methyl silicone resin and the like are compounded for use, so that the flame retardant has relatively high flame retardant efficiency and heat resistance, and does not volatilize or thermally decompose in the processing process, so that the flame retardant generates a synergistic effect, and V-0-level flame retardance of polycarbonate is realized under the condition of relatively low addition amount of the flame retardant; on the basis of well maintaining the original mechanical properties of PC, the flame-retardant PC alloy has good flame retardance and electrical properties.

Description

technical field [0001] The invention belongs to the technical field of flame-retardant socket materials, in particular to a production process of halogen-free flame-retardant socket pellets. Background technique [0002] PC itself has good flame retardant performance, the oxygen index is about 25%, and it is self-extinguishing. At present, the halogen-free flame retardants used for PC mainly include phosphorus-based flame retardants, sulfonate-based flame retardants, silicon-based flame retardants, and boron-based flame retardants. The above halogen-free flame retardants can basically make the material reach UL94 V0 level. PC needs a higher level of flame retardant in many occasions. Traditional flame retardant polycarbonate materials are often flame retardant with brominated flame retardants. Brominated epoxy oligomer, the flame retardant grade reaches UL94V-0 level, and has little effect on its thermal deformation temperature, and can even increase the impact strength of ...

Claims

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Application Information

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IPC IPC(8): C08L69/00C08L61/14C08L83/04C08K3/38C08K5/523
CPCC08L69/00C08K2003/387C08L2201/02C08L2201/14C08L2201/08C08L2203/20C08L61/14C08L83/04C08K3/38C08K5/523
Inventor 邵景业郑闻超
Owner 泰力(安徽)电器股份有限公司
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