Polyester film for electrical insulation
A technology of electrical insulation and polyester film, applied in the direction of organic insulators, plastic/resin/wax insulators, layered products, etc., can solve problems such as high cost, poor visibility, and increased leakage, and achieve good apparent density Effect
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Embodiment approach
[0014] The polyester used in the polyester film of the present invention refers to a polymer crystalline thermoplastic resin composition obtained through esterification, and this polyester is obtained by polycondensation of a dicarboxylic acid component and a glycol component .
[0015] As the dicarboxylic acid component, terephthalic acid, isophthalic acid, naphthalene dicarboxylic acid, cyclohexanedicarboxylic acid, diphenylethanedicarboxylic acid, etc. can be used, and as the glycol component, ethylene glycol and propylene glycol can be used. , 1,4-butanediol, cyclohexanedimethanol, etc. Among them, terephthalic acid and naphthalene-2,6-dicarboxylic acid are preferable as the acid component, and ethylene glycol and propylene glycol are preferable as the glycol component.
[0016] The melting point of the polyester is preferably 250° C. or higher from the viewpoint of heat resistance, and preferably 300° C. or lower from the viewpoint of productivity. Examples of such idea...
Embodiment 1~8、 comparative example 2~4
[0057] With the calcium acetate of 0.09 weight part as catalyst, with the dimethyl terephthalate of 85 weight parts and the ethylene glycol of 60 weight parts, carry out transesterification reaction by conventional method, add the trimethyl phosphate containing 0.20 weight % then Ethylene glycol solution, then add the ethylene glycol slurry containing calcium carbonate with an average particle size of 1.1 μm, relative to polyethylene terephthalate, the content of calcium carbonate is as shown in Table 1, then, with 0.03 parts by weight of antimony trioxide is used as a catalyst for polycondensation reaction to prepare polyethylene terephthalate with an intrinsic viscosity of 0.68dl / g.
[0058] After the polyethylene terephthalate was vacuum-dried at 170°C, it was supplied to an extruder heated to 280°C, extruded through a T-shaped die, and cooled and solidified with a cooling drum at 30°C to obtain an unstretched membrane. Then heat the film to 85-95°C, stretch it 3.3-4.1 tim...
Embodiment 9
[0061] With the same method as Example 1, only the polyethylene terephthalate with an intrinsic viscosity of 0.51dl / g was obtained, and samples were prepared with the same calcium carbonate addition and film-making conditions. In addition, when polyethylene terephthalate having an intrinsic viscosity of 1.6 dl / g was used, the stretching stress was too high, so stretching could not be performed at all. Example 10, 11
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