Pretreating method for diesel-fuel of poor quality
A low-quality diesel oil pretreatment technology, applied in the petroleum industry, refined hydrocarbon oil, etc., can solve the problems of inability to remove diesel macromolecule colloids, reduce the service life of filter equipment, and easily block filter screens, so as to reduce bed coking, Easy to operate, simple filter equipment effect
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Embodiment 1
[0022] Dilute analytically pure phosphoric acid with distilled water to a concentration of 40w%, immerse 375ml of this solution on 350g of alumina, and treat it at 150°C for 4 hours after drying to prepare an adsorbent with a phosphoric acid content of 30w%. Put 200ml of this adsorbent into a φ20mm adsorption column, add catalytically cracked diesel oil (raw material A) with a sulfur content of 5868 μg / g, a nitrogen content of 1256 μg / g, and an actual colloid content of 435 mg / 100ml into the lower bottle, and take a trickle flow The method is to inject the adsorption column from the upper part, and carry out adsorption and filtration through the adsorbent bed layer. After 8 hours, the feed is stopped, and the heated flue gas is introduced from the lower part for desorption. After 4 hours, the air intake is stopped, and the oil is fed from the upper part to continue the adsorption. After 10 rounds of such cycle operation, stop feeding, then feed flue gas with an oxygen content o...
Embodiment 2
[0029] Dilute analytically pure potassium chloride with distilled water to a concentration of 30w%, immerse 500ml of this solution on 600g of aluminum silicate, and treat it at 200°C for 4 hours after drying to prepare an adsorbent with a potassium chloride content of 20w%. Put 200ml of this adsorbent into a φ20mm adsorption column, add coked diesel oil (raw material B) with a sulfur content of 7646μg / g, a nitrogen content of 1024μg / g, and an actual colloid content of 257mg / 100ml into the lower bottle, and adopt a trickle method Inject the adsorption column from the upper part, and carry out adsorption and filtration through the adsorbent bed layer. After 10 hours, the feeding is stopped, and the heated flue gas is introduced from the lower part for desorption. After 6 hours, the air intake is stopped, and the oil is fed from the upper part to continue the adsorption. After 8 rounds of this cycle operation, stop feeding, then unload the adsorbent, use flue gas with an oxygen co...
Embodiment 3
[0036]Dilute analytically pure sodium hydroxide to a concentration of 25w% with distilled water, soak 800ml of this solution onto 300g of titanium oxide, and treat it at 180°C for 4 hours after drying to prepare an adsorbent with a sodium hydroxide content of 40w%. Put 200ml of this adsorbent into a φ20mm adsorption column, add thermally cracked diesel oil (raw material C) with a sulfur content of 5465μg / g, a nitrogen content of 1312μg / g, and an actual colloid content of 352mg / 100ml into the lower bottle, and take a trickle flow The method is to inject the adsorption column from the upper part, and carry out adsorption and filtration through the adsorbent bed layer. After 6 hours, the feeding is stopped, and the heated flue gas is introduced from the lower part for desorption. After 3 hours, the air intake is stopped, and the oil is fed from the upper part to continue the adsorption. After 12 rounds of this cycle operation, stop feeding, then unload the adsorbent, use flue gas ...
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