Flame-retardant fiber composite and fabric produced therefrom.

A technology of flame-retardant fibers and composites, applied in the direction of fabrics, non-woven fabrics, textiles, etc., can solve the problems of insufficient bulkiness, insufficient flame retardant and fire resistance of polyurethane foam, lack of gloss and color development, etc.

Active Publication Date: 2006-07-19
KANEKA CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, JP-A-8-218259 describes that by mixing a small amount of heat-resistant fiber and a fiber containing halogen and Sb that can be used for work clothes with cotton, etc., excellent hand feeling and hygroscopicity are obtained. Highly flame-retardant and highly flame-retardant fiber composites, but when used as non-woven fabrics to prevent the polyurethane used in furniture and bedding from igniting, there are difficulties in processing in the manufacture of non-woven fabrics, and bulkiness during honing processing Insufficient performance, lack of luster and color design due to a certain amount of fibers added with a large amount of flame retardants, although it is self-extinguishing when it leaves the fire source, it will be exposed to intense In flames, as a flame-retardant fiber composite, there are still problems such as insufficient flame-retardant and fire-resistant properties of cotton and polyurethane foam used in the above-mentioned bedding and furniture.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

manufacture example 1

[0092] A copolymer composed of 51% by weight of acrylonitrile, 48% by weight of vinylidene chloride, and 1% by weight of sodium p-styrenesulfonate was dissolved in dimethylformamide so that the resin concentration was 30% by weight. 15 parts of antimony trioxide was added to 100 parts of resin weight of the obtained resin solution to form a spinning dope.

[0093] The above-mentioned antimony trioxide has a uniformly adjusted particle diameter of 2 μm or less, which is adjusted in advance to be uniformly dispersed in a diluted resin solution before use.

[0094] Using a nozzle with a nozzle diameter of 0.08mm and a nozzle with a number of 300 holes, extrude the spinning stock solution containing antimony trioxide into a 50% by weight aqueous solution of dimethylformamide, wash it with water, dry it at 120°C, and then elongate it. 3 times, and then heat-treated at 145° C. for 5 minutes to obtain a fiber (A).

[0095] The chlorine content of the obtained fiber was 35.1% by weig...

manufacture example 2

[0097] A copolymer composed of 56% by weight of acrylonitrile, 41% by weight of vinylidene chloride, and 3% by weight of sodium 2-acrylamide-2-methylpropanesulfonate was dissolved in dimethylformamide so that the resin concentration was 20% by weight. . Antimony trioxide was added to the resin weight of the obtained resin solution to form a spinning dope. Table 1 shows the amount of antimony trioxide added.

[0098] The above-mentioned antimony trioxide has a uniformly adjusted particle diameter of 2 μm or less, which is adjusted in advance to be uniformly dispersed in a diluted resin solution before use.

[0099] Using a nozzle with a nozzle diameter of 0.08mm and a nozzle with a number of 300 holes, extrude the spinning stock solution containing antimony trioxide into a 50% by weight aqueous solution of dimethylformamide, wash it with water, dry it at 120°C, and then elongate it. 3 times, and then heat-treated at 145° C. for 5 minutes to obtain a fiber (A).

[0100] The c...

Embodiment 1～7 and comparative example 1～14

[0102] According to the ratio shown in Table 1, the fiber (A) obtained by Manufacturing Example 1, the melamine fiber Basofil (having a distribution of about 1 to 3.5 dtex, and a distribution of 20 to 200 mm in cut length, as the fiber (B), Basofil Fibers Co., Ltd. Manufactured), Visil (1.7dtex, cut length 40mm, manufactured by SATERI Corporation) as silicon-containing cellulose fibers, Technora (1.7dtex, cut length 38mm, manufactured by Teijin Co., Ltd.) as para-type aramid fibers Manufacture), rayon (1.5dtex, cut length: 38mm) as the cellulosic fiber (C), and polyester fiber (6.6dtex, cut length: 51mm) as the fiber (D) were mixed to prepare a sample Non-woven fabrics were subjected to a flame test. The evaluation results are shown in Table 2.

[0103] Example

serial number

Mixing ratio (% by weight) in the flame-retardant fiber composite

Fiber (A)

Fiber (B)

Fiber (C)

Fiber (D)

Melamine

fiber...

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Abstract

A flame-retardant fiber composite which comprises: 20 to 85 wt.% fibers (A) comprising 100 parts by weight of a polymer containing at least 17 wt.% halogen atoms and 0.5 to 50 parts by weight of an antimony compound; 5 to 80 wt.% heat-resistant fibers (B); 0 to 40 wt.% cellulosic fibers (C); and 0 to 40 wt.% flammable fibers (D). When used in applications such as indoor furniture or beddings, the composite further improves the flame retardancy of materials and enables the materials to be used in fields where higher flame retardancy is required.

Description

technical field [0001] The present invention relates to the problem that the previous flame retardant fiber composites were difficult to solve, that is, the flame retardancy of the bedding is further improved, and the processability and bulkiness are improved. In addition, the processability, hand feeling and touch feeling are good. Inexpensive and highly flame retardant fiber composites and fabrics made from them for designer furniture and bedding. Background technique [0002] In order to prevent fires, it is desirable to impart flame retardancy to materials used for living room furniture, bedding, and the like. In order to make furniture and bedding comfortable to use, flammable materials such as cotton or polyurethane foam are usually used, so in order to prevent fire, it is important to prevent this flammable material from being exposed to flames for a long time. In addition, the fireproof material must not impair the comfort and design of furniture and bedding. Vario...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D02G3/04D04H1/42D04H1/425D04H1/4258D04H1/4326D04H1/4334D04H1/4342D04H1/435
CPCD02G3/443D04H1/42Y10T442/696Y10T442/698Y10T442/697D04H1/425D04H1/4266D04H1/43D04H1/4334D04H1/4342D04H1/43835D04H1/4282D04H1/4326D02G3/04
Inventor 见尾渡岩出进丸山茂羽木裕康
Owner KANEKA CORP
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