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Poly metal cluster water purifying material and its preparing method and use

A multi-component metal and porous material technology is applied in the preparation of the water purification material and the field of new nano multi-component metal cluster water purification materials, which can solve the problems of limited contact area, excessive bacterial content in the effluent, and short service life, and achieve rapid Removal, concentration reduction, long life effect

Active Publication Date: 2006-08-23
广州净易环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Activated carbon can effectively remove free chlorine in water and can effectively absorb organic pollutants such as color, odor, pesticides, insecticides, detergents, aromatic compounds, and disinfection by-products (DBPs) in water. A large amount of organic matter adsorbed on the surface of activated carbon becomes a breeding ground for bacteria, which easily leads to excessive bacterial content in the effluent, resulting in problems of short service life and bacterial growth, and the removal effect of activated carbon on heavy metal ions in water is not good
Its disadvantage is that the current KDF is only a simple copper and zinc alloy material, and the area in contact with water is very limited when purifying water, so the water treatment effect is limited when the amount of KDF is small and the flow rate is high, and the high price of KDF also limits its use
The weak point of this invention is that one or more particles of medical stone, activated carbon and activated coal are simply bonded and pressed together. Adsorption, there is a filter layer that absorbs organic matter and becomes a breeding ground for bacteria, which easily leads to excessive bacterial content in the effluent, short service life and bacterial growth, and the removal effect of heavy metal ions in water is not good
The disadvantage of the above inventions is that they all use polymer materials as fillers, which have poor stability in long-term use in water, and the water purification effect will be affected.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Use silver nitrate, copper acetate, zinc acetate as silver source, copper source and zinc source, dissolve silver nitrate in deionized water at room temperature, dissolve copper acetate and zinc acetate in deionized water at 80°C, after completely dissolving, put the main body Material granular activated carbon is added to copper acetate and zinc acetate solution, then silver nitrate solution is added, and the temperature of the solution is kept at 80°C. After stirring at a low speed for 4 hours, the residual solution is filtered off, and the main material granular activated carbon loaded with target ions is dried at 120°C. 2 hours, then roasted at 400°C for 2 hours, and then reduced with ethylene glycol as a reducing agent for 2 hours, washed with distilled water, and dried to obtain a copper-zinc-silver multi-metal cluster water purification material.

[0042] The mass consumption ratio of above-mentioned materials is:

[0043] Copper acetate 2 Zinc acetate 2

[0044...

Embodiment 2

[0048] Use copper nitrate and zinc nitrate as copper and zinc sources, dissolve copper nitrate and zinc nitrate in deionized water at 20°C, and after they are completely dissolved, add porous silica powder, the main material, into the solution, stir at a low speed for 8 hours, filter After removing the residual solution and washing with distilled water, the host material porous silica loaded with target ions was dried at 120°C for 2 hours, calcined at 600°C for 2 hours, and washed with H 2 As a reducing agent, it was reduced at 600°C for 1 hour to prepare a nano-copper-zinc multi-metal cluster water purification material.

[0049] The mass consumption ratio of above-mentioned materials is:

[0050] Copper nitrate 10 Zinc nitrate 20

[0051] Porous silica powder 200 Deionized water 1000

[0052] Each kilogram of water purification material can purify 10m of tap water 3 , can remove residual chlorine in water, soluble heavy metal ions Cd 2+ , NO 3 + Wait for effective remo...

Embodiment 3

[0054] Use copper sulfate and zinc sulfate as copper and zinc sources, dissolve copper sulfate and zinc sulfate in deionized water at 60°C, and after they are completely dissolved, add diatomaceous earth powder, the main material, into the solution, and then add nitric acid dissolved in water Lanthanum, keep the solution temperature at 60°C, stir at low speed for 2 hours, filter off the residual solution, wash with distilled water, dry the main material diatomite powder loaded with target ions at 120°C for 2 hours, and bake at 800°C for half an hour, Then use CO as a reducing agent to reduce at 450°C for 2 hours to prepare a nano-rare earth copper-zinc multi-metal cluster water purification material.

[0055] The mass consumption ratio of above-mentioned materials is:

[0056] Copper sulfate 30 Zinc sulfate 30

[0057] Lanthanum nitrate 0.1 Diatomaceous earth powder 200

[0058] Deionized water 1000

[0059] Each kilogram of water purification material can purify 10m of tap...

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PUM

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Abstract

The present invention relates to polynary metal cluster as water purifying material and its preparation process and use. The water purifying material is prepared with porous material in 50-99 wt%, and two or more metals of Ag, Cu, Zn and RE in 1-50 wt%. The preparation process includes: selecting metal source; adding the metal source directly or after being compounded into water solution into the porous material to form combined body; and introducing reductant after roasting. Water to be purified is made to flow through the water purifying material or mixed with the water purifying material for purifying. The water purifying material has great specific surface area, high activity and high homogeneity, and may be used to eliminate water soluble heavy metal ion, micro organic pollutant, residual chlorine and sterilizing side product in high effect.

Description

technical field [0001] The invention relates to a water purification material, in particular to a novel nanometer multi-element metal cluster water purification material. [0002] The invention also relates to the preparation method and application of the water purification material. Background technique [0003] With the development of society and the improvement of living standards, people's requirements for quality of life are getting higher and higher. The impact of clean and safe drinking water on people's quality of life cannot be ignored. Water is the main carrier for the transmission of various germs, and 80% of human diseases are related to water pollution. Access to clean and safe drinking water has become a worldwide issue. On the other hand, water pollution is becoming more and more serious. Surface water such as rivers and lakes and groundwater in some areas are polluted to varying degrees. The problem of water shortage has attracted widespread attention. ...

Claims

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Application Information

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IPC IPC(8): C02F1/46C02F1/50
Inventor 黄肖容隋贤栋
Owner 广州净易环保科技有限公司
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