Poly metal cluster water purifying material and its preparing method and use
A multi-component metal and porous material technology is applied in the preparation of the water purification material and the field of new nano multi-component metal cluster water purification materials, which can solve the problems of limited contact area, excessive bacterial content in the effluent, and short service life, and achieve rapid Removal, concentration reduction, long life effect
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Embodiment 1
[0041] Use silver nitrate, copper acetate, zinc acetate as silver source, copper source and zinc source, dissolve silver nitrate in deionized water at room temperature, dissolve copper acetate and zinc acetate in deionized water at 80°C, after completely dissolving, put the main body Material granular activated carbon is added to copper acetate and zinc acetate solution, then silver nitrate solution is added, and the temperature of the solution is kept at 80°C. After stirring at a low speed for 4 hours, the residual solution is filtered off, and the main material granular activated carbon loaded with target ions is dried at 120°C. 2 hours, then roasted at 400°C for 2 hours, and then reduced with ethylene glycol as a reducing agent for 2 hours, washed with distilled water, and dried to obtain a copper-zinc-silver multi-metal cluster water purification material.
[0042] The mass consumption ratio of above-mentioned materials is:
[0043] Copper acetate 2 Zinc acetate 2
[0044...
Embodiment 2
[0048] Use copper nitrate and zinc nitrate as copper and zinc sources, dissolve copper nitrate and zinc nitrate in deionized water at 20°C, and after they are completely dissolved, add porous silica powder, the main material, into the solution, stir at a low speed for 8 hours, filter After removing the residual solution and washing with distilled water, the host material porous silica loaded with target ions was dried at 120°C for 2 hours, calcined at 600°C for 2 hours, and washed with H 2 As a reducing agent, it was reduced at 600°C for 1 hour to prepare a nano-copper-zinc multi-metal cluster water purification material.
[0049] The mass consumption ratio of above-mentioned materials is:
[0050] Copper nitrate 10 Zinc nitrate 20
[0051] Porous silica powder 200 Deionized water 1000
[0052] Each kilogram of water purification material can purify 10m of tap water 3 , can remove residual chlorine in water, soluble heavy metal ions Cd 2+ , NO 3 + Wait for effective remo...
Embodiment 3
[0054] Use copper sulfate and zinc sulfate as copper and zinc sources, dissolve copper sulfate and zinc sulfate in deionized water at 60°C, and after they are completely dissolved, add diatomaceous earth powder, the main material, into the solution, and then add nitric acid dissolved in water Lanthanum, keep the solution temperature at 60°C, stir at low speed for 2 hours, filter off the residual solution, wash with distilled water, dry the main material diatomite powder loaded with target ions at 120°C for 2 hours, and bake at 800°C for half an hour, Then use CO as a reducing agent to reduce at 450°C for 2 hours to prepare a nano-rare earth copper-zinc multi-metal cluster water purification material.
[0055] The mass consumption ratio of above-mentioned materials is:
[0056] Copper sulfate 30 Zinc sulfate 30
[0057] Lanthanum nitrate 0.1 Diatomaceous earth powder 200
[0058] Deionized water 1000
[0059] Each kilogram of water purification material can purify 10m of tap...
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