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Graphitized edm wire

a graphitized, wire technology, applied in the field of edm, can solve the problems of large gouges or craters, electrical arc potential, metallurgical flaws, etc., and achieve the effect of facilitating the adhesion of powder particles

Inactive Publication Date: 2013-05-16
TOMALIN DANDRIDGE +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent describes a modified slip casting procedure for bonding an EDM wire to a graphite coating. A slurry of zinc powder, organic binder, colloidal graphite, and a suspension medium is used to coat the wire. The wire is then heat treated to remove the suspension medium and cure the binder, resulting in a metallurgical bond between the wire and the graphite coating. Another embodiment involves using a powder graphite lubricant to facilitate the adherence of powder particles to the wire and the formation of microscopic chemical bonds between the wire surface and the graphite coating. The resulting graphite layer is electrically conductive and adherent to the wire core. Overall, the patent provides techniques for improving the bonding quality and performance of EDM wires.

Problems solved by technology

It is important for flushing to be efficient because inefficient flushing result in conductive particles being built up in the gap, which can create the potential for electrical arcs.
Arcs are very undesirable as they cause the transfer of a large amount of energy, which causes large gouges or craters, i.e., metallurgical flaws, to be introduced into the workpiece and the EDM wire electrode.
Such flaws in the wire could cause the EDM wire to break catastrophically.
Fracture toughness is a measure of the resistance of a material to flaws which may be introduced into the material and that can potentially grow to a critical size to potentially cause catastrophic failure of the material.
Others in the prior art, for instance U.S. Pat. No. 5,762,726, recognized that the higher zinc content phases in the copper-zinc system, specifically gamma phase, would be more desirable for EDM wire electrodes, but the inability to cope with the brittleness of these phases limits the commercial feasibility of manufacturing such wire.
However, epsilon phase was found to be too unstable to be incorporated in the resultant high zinc alloy coating, although the potential for brittle epsilon coatings was acknowledged.
The challenge of incorporating graphite into other EDM wire systems is that of figuring out how to adhere the graphite to the wire.
This approach, however, was only marginally successful for an obvious reason.
In the case of a dense copper oxide coating, the oxide may well be adherent, but the lack of porosity requires the graphite coating to lay on top of the oxide and therefore it cannot be captured by the oxide and is subject to being “peeled” off the surface.
Other inventors, for example those listed in U.S. Pat. No. 5,030,818, have suggested incorporating unrealistically large volume fractions of graphite, e.g., up to 40 weight percent graphite, into a molten bath of copper or brass and “solidify(ing) into wire with a diameter of about 0.002 to about 0.014 inches.” Such a large volume of graphite, however, could never be uniformly dispersed in a molten bath of copper or brass due to the large density difference between graphite and metals.
Even if the graphite could be uniformly incorporated into the melt, the suggestion that wires of diameters ranging between 0.002 and 0.014 inches could be continuously cast is unrealistic.
This method of applying graphite to an epsilon phase brass coating, however, is unsuccessful because no adhesion is formed between the graphite and the epsilon phase brass and, thus, the graphite coating is not adequately secured to the coating.
It has been suggested that other hard inert particles incorporated into coatings will enhance the erosion resistance of the coatings, but one would not expect graphite to function similarly because it is not known to have significant erosion resistance.
The issue with both hard inert particles and graphite is adequately adhering the discrete particles on and into the coating.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0038]Core: 63Cu / 37Zn

[0039]Galvanize 30 μm Zinc at 1.0 mm

[0040]Draw from 1 mm to 0.35 mm at 243° C. in the apparatus illustrated in FIG. 1

[0041]Draw from 0.35 mm to 0.25 mm at 218° C. in the apparatus illustrated in FIG. 1

[0042]FIG. 3 illustrates an optical metallographic cross-section of the graphitized brass wire produced by the process described shown in Example 1 at its final diameter of 0.25 mm. Prior to cross-sectioning, a copper layer was electroplated on the wire so that the details of the coating structure could be preserved and not subjected to edge rounding. This coating is indicated as area “Cu” in the microstructure. The microstructure of the wire consists of an alpha phase brass core (Area “α”), an intermediate layer of gamma phase brass alloy (Area “γ”) formed by the diffusion of copper into the original zinc coating, and an outer layer of graphitized coating (Area “C”). The various areas have been identified so they can be related to the results of subsequent SEM ana...

example 2

[0049]Core: AISI 1006 carbon steel at 1.39 mm dia

[0050]Electroplate 28 μm of nickel

[0051]Cold Draw to 0.35 mm dia in water soluble lubricant

[0052]Etched in 50% diluted HNO3 with 8% HF added and heated to 140° F. prior to being subjected to 36 VDC until gas evolution was observed

[0053]Warm Draw to 0.25 mm dia at 345° C. in the apparatus illustrated in FIG. 1

[0054]The warm drawing was performed in the same apparatus using the same drawing technique of Example 1. FIG. 7 illustrates an optical metallographic cross-section of the resultant wire. Prior to cross-sectioning, this sample was also electroplated with copper to preserve the details of the graphite layer. The graphite layer is thinner than that produced by the process in Example 1 because of the reduced total deformation during the exposure to graphite and heat. However, when the cross-section was analyzed with the EDAX apparatus in a SEM, it was found there was enough interaction between the graphite and substrate nickel electr...

example 3

[0055]In the following example EDM wire was produced by the modified slip casting process of FIG. 2. A 63Cu37Zn brass alloy wire of 0.9 mm diameter was first cleaned by passing it through a hydrogen atmosphere furnace maintained at 500° C. The cleaned wire was then passed through a slurry composed of 90 gms of synthetic graphite powder (UFG-30, ≈10μ), 48.8 gms of Dag® 154 (proprietary suspension of colloidal graphite and organic binders in isopropyl alcohol manufactured by the Henkel Corporation, Madison Heights, Mich.), and 30 ml of isopropyl alcohol. The coated wire was dried in air and sintered in a controlled atmosphere furnace (N2 / 5% H2) at 550° C. for 30 minutes.

[0056]FIG. 9 illustrates the resultant microstructure. The heat treatment employed in this example produced a duplex microstructure of gamma and beta phase brass layers. As heat treated, the wire has a relatively smooth surface as evidenced by its microstructure. The sample was drawn to an intermediate diameter of 0.57...

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Abstract

An electrode wire for use in an electrical discharge machining apparatus includes a core having a surface and one of a metal, an alloy of a metal, and a combination of a metal and alloy of a metal. An adherent coating of graphite is metallurgically bonded to the surface of the core.

Description

RELATED APPLICATIONS[0001]This application claims priority to U.S. Provisional Application No. 61 / 366,963, filed Jul. 23, 2010; U.S. Provisional Application No. 61 / 298,706, filed Jan. 27, 2010; and U.S. Provisional Application No. 61 / 496,639, filed Jun. 14, 2011, the entirety of which are incorporated herein by reference.TECHNICAL FIELD[0002]The present invention relates to electrical discharge machining (EDM) and, more specifically, relates to an electrode wire to be used in discharge machining and to the process for manufacturing an EDM electrode wire having a layer that includes graphite metallurgically bonded to the wire core.BACKGROUND[0003]The process of electrical discharge machining (EDM) is well known. In the field of traveling wire EDM, an electrical potential, i.e., voltage, is established between a continuously moving EDM wire electrode and an electrically conductive workpiece. The potential is raised to a level at which a discharge is created between the EDM wire electr...

Claims

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Application Information

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IPC IPC(8): B23H1/04B23H1/06
CPCB23H7/08B23H1/04B23H1/06C23C2/06Y10T29/49117C23C2/28C23C2/38C23C24/082C23C2/26
Inventor TOMALIN, DANDRIDGESHILLING, LARRY
Owner TOMALIN DANDRIDGE