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62results about How to "Regular molecular structure" patented technology

Organosilicone modified acrylate emulsion, preparation method thereof and water-based artificial stone prepared from organosilicone modified acrylate emulsion

The invention provides an organosilicon modified acrylate emulsion with a weight-average molecular weight of 201205 and also provides a preparation method of the organosilicon modified acrylate emulsion and an artificial stone prepared from the organosilicon modified acrylate emulsion. According to the specific technical scheme, the preparation method comprises the following steps of: (1) preparing a siloxane intermediate emulsion; (2) preparing a silicon-acrylic copolymer core emulsion; and (3) preparing a silicon-acrylic copolymer shell emulsion. The molecular structure of the organosilicon modified acrylate emulsion has a special core-shell structure design, wherein an innermost core of a particle is made of an organosilicon component, an intermediate layer of the particle is made of a polyacrylate component and the shell of the particle is made of a multi-crosslinked organosilicon and polyacrylate component. The organosilicon modified acrylate emulsion not only has high organosilicon content, but also has high hardness and adhesive force. Compared with a common product, the organosilicon modified acrylate emulsion has higher emulsion hardness and resistance to soiling and water. The artificial stone prepared from the organosilicon modified acrylate emulsion has the advantages of good compatibility, high abrasion resistance, low water absorption, good heat resistance, high fire resistance and low shrinkage rate in an artificial stone formula.
Owner:广东海顺新材料科技有限公司

Novel shape memory spraying polyurethaneurea elastomer resin bathroom product and preparation method thereof

The invention discloses a spraying elastomer raw material composition. The composition comprises an A component raw material and a B component raw material, wherein the A component raw material comprises one or more of polyester polyol having a number-average molecular weight of 400-3000, polyether polyol having a number-average molecular weight of 400-3000, vegetable oil polyol having a number-average molecular weight of 400-2000, amino-terminated polyether having a number-average molecular weight of 200-4000 and polyisocyanate; and the B component raw material comprises polyoxypropylene diamine having a number-average molecular weight of 200-4000, polyoxypropylene triamine having a number-average molecular weight of 400-5000, active aromatic diamine and aromatic diamine. The invention also discloses a prepolymer of a spraying elastomer, a raw material composition and a preparation method of the prepolymer as well as a bathroom product. The spraying elastomer disclosed by the invention is good in various comprehensive properties; and after pressed, the product can memory the original shape, thereby improving the whole comfortable sensation and broadening the use range of the spraying elastomer.
Owner:SHANGHAI MOERSHU CORP DEVING +1

A kind of aqueous polyurethane adhesive and preparation method thereof

The invention relates to a waterborne polyurethane adhesive and a manufacturing method thereof, and belongs to the technical field of polymer materials. The manufacturing method comprises the following processing steps: 1. preparing polyurethane prepolymer; 2. performing a neutralization reaction; 3. preparing a waterborne polyurethane dispersion; 4. preparing waterborne polyurethane; 5. preparing the waterborne polyurethane adhesive. According to the invention, polymeric polyols and isocyanate are pre-polymerized, and pre-chain extension of micromolecular polyols are performed to prepare the prepolymer; processes of highly shearing emulsification in water and chain extension tackification are performed after neutralization; the obtained polyurethane emulsion has a structured molecular structure and good adaptability to bonding process.
Owner:烟台道成化学有限公司

Preparation method of dentritic waterborne polyurethane

The invention discloses a preparation method of dentritic waterborne polyurethane, comprises the following steps: by using diisocyanate, polyol, dimethylolpropionic acid and diethanol amine as main raw materials, preparing single terminated polyurethane prepolymer, grafting the single terminated polyurethane prepolymer with the generational polyamide-amine 1GPAMAM dentritic polymers, and finally adding a neutralizer, forcibly dispersing in the water to obtain the dentritic waterborne polyurethane emulsion. The dentritic waterborne polyurethane has a high-branched dentritic structure, more structured molecular structure, controllable molecular weight, and is free from organic solvent; the water is used as the dispersion medium, so that the product is non-toxic, the use is safe, efficient and environmental friendly; the dentritic waterborne polyurethane is non-flammable, non-explosive and easy to store.
Owner:昇英新材料科技(常州)有限责任公司

Single-component water-based black paint for automobile and preparation method thereof

ActiveCN108276889APlay the role of dispersion and stabilityInhibit bindingPolyurea/polyurethane coatingsWater basedPolyurethane dispersion
The invention relates to single-component water-based black paint for an automobile and a preparation method thereof. The single-component water-based black paint for the automobile is prepared by mixing three components A, B and C according to the weight ratio of 4 to (4 to 7) to (0.05 to 0.2), wherein the component A is prepared from the following components in parts by weight: 3 to 7.5 parts ofhigh-pigment carbon black, 15 to 35 parts of water, 3 to 10 parts of methyl ethylene glycol, 0.3 to 2.5 parts of base material wetting agent and 1.5 to 7.5 percent of dispersant; the component B is an aliphatic polyurethane dispersion body; the component C is a rheological agent. According to the single-component water-based black paint for the automobile, the compatibility problem of raw materials is remarkably improved, and the flowability, storage stability, luster, blackness and a blue phase are improved.
Owner:GUANGDONG YATU CHEM

Preparation method of aqueous emulsion type neoprene antioxidant system product

The invention relates to a preparation method of aqueous emulsion type neoprene antioxidant system product, which belongs to the field of adhesive technology. The invention chooses p-cresol and dicyclopentadiene butyl reactant as the main antioxidant to coordinate with the composite termination agent made from phenothiazine and N,N-dialkyl hydroxylamine compound to produce a functional antioxidant. With the adoption of the suspension producing process and powder grinding and emulsifying equipment, the functional antioxidant is further produced into an aqueous emulsion type neoprene antioxidant system product. Adding 0.75-1.89% of aqueous emulsion type neoprene antioxidant system product provided by the invention in the process of preparing a neoprene product sample, the appearance and color,mooney viscosity, peeling strength, viscosity performance indexes of the solution are relatively stable in a hot air aging test under the temperature of 70 DEG C.
Owner:NANTONG HAILITE RUBBER & PLASTIC MACHINERY

Preparation method of epoxy chloropropane toughened high-ortho phenolic fiber

A preparation method of an epoxy chloropropane toughened high-ortho phenolic fiber comprises the following steps of heating phenol, methanal, zinc acetate and epoxy chloropropane to boiling for reaction, adding concentrated sulfuric acid for boiling and reaction continuously, washing with high-temperature water, cooling, continuously heating up during pressure reduction and dehydration, obtaining epoxy chloropropane toughened high-ortho phenolic resin, performing melt spinning on the epoxy chloropropane toughened phenolic resin, drawing to form a high-ortho phenolic fiber filament, heating, curing and crosslinking the high-ortho phenolic fiber filament in a coagulating bath containing methanal and HC1, and obtaining the epoxy chloropropane toughened high-ortho phenolic fiber. Compared with the prior art, the method has the advantages of simple and practicable reaction, good spinnability of a stock solution, high curing rate and high mechanical properties.
Owner:ZHONGYUAN ENGINEERING COLLEGE

Halogen-free flame-retardant polyamide resin composition and preparation method thereof

The invention relates to the technical field of polymer materials, in particular to a halogen-free flame-retardant polyamide resin composition and a preparation method thereof. The composition is prepared from polyamide, hyperbranched polymer, carbon fiber tube, antioxygen, surface modifier, thixotropic agent, non-halogen flame-retardant and flame retardant synergist, wherein the hyperbranched polymer is amino-end-group hyperbranched polyamide. The polyamide is adopted as a resin substrate and cooperates with a certain amount of the hyperbranched polymer, the carbon fiber tube, the surface modifier, the non-halogen flame-retardant, the flame retardant synergist and the thixotropic agent, the carbon fiber tube, the non-halogen flame-retardant and the flame retardant synergist are uniformlydispersed in the polyamide, the prepared halogen-free flame-retardant polyamide resin composition has the advantages of being high in strength, good in dimensional stability, good in chemical resistance and excellent in electrical properties, outstanding physical performance can be maintained under severer temperature and humidity conditions, and the composition has high flame retardant performance which reaches UL94V0.
Owner:GUANGDONG GREAT MATERIAL CO LTD

Modified phenolic resin and preparation method thereof

ActiveCN112851894ARegular molecular structureLow molecular viscosityBenzeneImide
The invention relates to a modified phenolic resin, and the resin is characterized in that the resin is prepared from the following raw materials in parts by mass: 70 to 110 parts of phenol, 15 to 40 parts of 4-maleimido phenol, 20 to 30 parts of resorcinol, 80 to 110 parts of formaldehyde and 25 to 40 parts of furfural. According to the invention, the selection and proportion of each monomer are screened, 4-maleimido benzene, resorcinol and furfural are added into the formula of common phenolic resin, and two-stage reaction is carried out under different reaction conditions. In the first reaction stage, ammonia water is used as a catalyst at relatively low temperature, and a mixture of resorcinol and formaldehyde is added; in the second reaction stage, barium hydroxide is adopted as a catalyst at a relatively high temperature, and a mixture of resorcinol and furfural is added. Finally, the modified phenolic resin with excellent comprehensive performance is obtained. Compared with common phenolic resin in the current market, the phenolic resin prepared by the preparation method disclosed by the invention is lower in curing temperature, more excellent in heat resistance, higher in residual carbon rate and better in mechanical property.
Owner:BEIJING UNIV OF CHEM TECH +1

Preparation method of boric acid modified high-ortho phenolic fiber

A preparation method of a boric acid modified high-ortho phenolic fiber comprises the following steps: (1) matching phenyl hydroxide and formaldehyde to obtain a solution A, and reacting under the action of sodium carbonate or zinc acetate to obtain a salicylidene phenol solution; (2) adding boric acid in the salicylidene phenol solution to obtain a boric acid modified high-ortho phenolic mother liquor; (3) matching phenyl hydroxide and formaldehyde to obtain a solution B, performing an additive reaction under the action of zinc acetate, mixing the reactant with the high-ortho phenolic mother liquor obtained in the step (2), and adding strong sulfuric to obtain a boric acid modified high-ortho phenolic solution; (4) performing high-temperature water cleaning so as to obtain boric acid modified high-ortho thermoplastic phenolic resin suitable for spinning after temperature reduction; (5) performing melt spinning on the obtained boric acid modified high-ortho thermoplastic phenolic resin to obtain the boric acid modified high-ortho phenolic fiber. Compared with the prior art, the reaction is simple and feasible, the curing rate and the fiber heat resistance are high, the mechanical property is excellent, and the spinning stock solution is prepared by mixing with the mother liquor, so that the spinning performance is improved.
Owner:ZHONGYUAN ENGINEERING COLLEGE

Modified paraffin wax

The invention provides modified paraffin wax, which has the advantages of stable quality, simple production, low cost, and high paper tube qualification rate (no raised edges). The invention adopts a technical scheme that the novel modified paraffin wax is prepared by mixing the following raw materials in percentage by weight: 90 to 94 percent of composite paraffin wax, 2 to 4 percent of polyethylene, 1 to 2 percent of irregular polypropylene and 3 to 4 percent of rosin.
Owner:湖北东神天神实业有限公司

Water-based acrylic resin paint and preparing method thereof

The invention provides water-based acrylic resin paint. The water-based acrylic resin paint is prepared from, by weight, 30-40 parts of acrylic resin, 10-15 parts of filler, 2-4 parts of coupling agent, 1-4 parts of pigment, 0.2-0.8 part of dispersing agent, 20-25 parts of solvent, 0.3-0.8 part of anti-flash-rust agent, 1-2 parts of anti-settling agent, 6-12 parts of water-based polyurethane, 8-10 parts of PCDL and 10-15 parts of porous konilite. The invention further provides a preparing method of the water-based acrylic resin paint. The water-based acrylic resin paint is high in impact resistance, abrasive resistance and scratch resistance.
Owner:SUZHOU T CREATETE TECH

Organic microporous material with metal coordination containing heteroatoms and preparation and application thereof

ActiveCN109134872AImprove oxidation capacityHigh Nitrogen Adsorption CapacityHeteroatomStructural formula
The invention relates to an organic microporous material with metal coordination containing heteroatoms and preparation and application thereof. An organic conjugated precursor of the organic microporous material has a structural formula of I or II. The preparation comprises the steps of preparation of 4-trimethylsilylacetylene-2-bromopyridine or 5-trimethylsilylacetylene-3-bromopyridine, preparation of 4-ethynyl-2-bromopyridine or 5-ethynyl-3-bromopyridine, preparation of bis(2-bromopyridine) acetylene or bis(3-bromopyridine) acetylene, preparation of bis(2-thiophene pyridine) acetylene or bis(3-thiophene pyridine) acetylene, preparation of the organic conjugated precursor, and preparation of the organic microporous material with the metal coordination containing the heteroatoms. The organic microporous material has a controllable form and structure, thereby having different properties and functions, and can be applied to the development of novel functional materials such as gas adsorption and storage, molecular separation, catalysis, sustained release of drugs and the like.
Owner:DONGHUA UNIV

Poly aryl ether nitrile resin, poly aryl ether nitrile fiber and preparation methods thereof

The invention belongs to the technical field of polymer material and particularly relates to poly aryl ether nitrile resin, poly aryl ether nitrile fiber and preparation methods of the poly aryl ether nitrile resin and the poly aryl ether nitrile fiber. The molecular structure of the poly aryl ether nitrile resin contains structural units in the molar ratio of (80-100):(0-20). The poly aryl ether nitrile resin has the number-average molecular weight of 30,000 to 80,000. The poly aryl ether nitrile resin has a regular molecular structure and a large molecular weight and can be used to produce the high-performance poly aryl ether nitrile fiber stably.
Owner:SICHUAN FEIYA NEW MATERIAL

Preparation method of water-in-water emulsion-type cation polysaccharide biological flocculant

The invention relates to a preparation method of a water-in-water emulsion-type cation polysaccharide biological flocculant. The preparation method is characterized in that: an auto-polymer or a copolymer of several types of unsaturated cation monomers is used as a stabilizer, a non-ionic polysaccharide biological flocculant is used as an auxiliary stabilizer, an aqueous solution of inorganic salts is used as a continuous phase, and by virtue of certain technological control, free radical polymerization is performed in an internal phase aqueous solution to form stable and dispersed cation polysaccharide biological flocculant emulsion containing micro polymer particles, wherein the solid content is more than or equal to 30 percent, the appearance viscosity is 300 to 10000 mPa.s, the average particle size is less than or equal to 10 micrometers, and the stability is more than or equal to 6 months. The product is simple in synthetic process, high in solubility, degradable, good in flocculation effect and free from secondary pollution, can be used for treating urban sewage and industrial waste water and dehydrating sludge, can be used as a filter aid and a retention aid in the papermaking industry, can be used for plugging adjustment and sewage treatment in oil fields and the like and is wide in application prospect and high in environmental protection value.
Owner:威海汉邦生物环保科技股份有限公司

Straight-chain polyperfluoroether compound with hydroxyl-containing terminal group and preparation method thereof

The invention provides a straight-chain polyperfluoroether compound with a hydroxyl-containing terminal group and a preparation method thereof. The compound does not contain a branched chain structure, the molecular structure is neater, the compound is smoother, meanwhile, the compound has better viscosity-temperature characteristics, and the application range is wider. The straight-chain polyperfluoroether compound with the terminal group containing the hydroxyl group has a structural formula I shown in the specification; in the structural formula I, m is greater than or equal to 1, and n isgreater than or equal to 1.
Owner:CHINA PETROLEUM & CHEM CORP

Electrostatic spraying type chlorinated rubber anticorrosive paint and preparation method thereof

The invention relates to the technical field of chemical paints, particularly relates to an electrostatic spraying type chlorinated rubber anticorrosive paint and a preparation method thereof. The electrostatic spraying type chlorinated rubber anticorrosive paint mainly comprises an anticorrosive paint and a dedicated electrostatic lacquer diluent which are uniformly mixed, wherein the anticorrosive paint comprises a chlorinated rubber solution which comprises chlorinated rubber with new solvent as a main raw material, and the dedicated electrostatic lacquer diluent comprises a conductive agent and a conductive solvent. The electrostatic spraying type chlorinated rubber anticorrosive paint disclosed herein can be used for electrostatic spraying in construction, thus paints are saved, the labor productivity is greatly raised, and safety and environmental protection are achieved.
Owner:ANHUI JINDUN PAINT

Light-resistant and anti-aging water-based acrylate coating and preparation method thereof

InactiveCN113493622AShorten compounding timePromote absorptionCoatingsEmulsionAcrylic resin
The invention discloses a light-resistant and anti-aging water-based acrylate coating and a preparation method thereof. The preparation method of the water-based acrylate coating comprises the following steps that: 1) in the presence of organosilane, heteropolyacid and composite nanoparticles can be effectively combined, and the heteropolyacid, the composite nanoparticles, an emulsifier and a wetting agent jointly prepare a nanoparticle emulsion with a better dispersion effect; and 2) in the presence of an initiator, the nanoparticle emulsion is mixed with a comonomer and a cross-linking agent, and neutralizing is performed with alkali liquor, the required coating can be obtained. The water-based acrylic resin is modified by adopting multiple monomers, so that the bonding strength of the coating and a substrate can be remarkably improved; and in addition, the light resistance and the aging resistance of the composite nanoparticles modified by the heteropolyacid are enhanced, and the strict requirements of long-term outdoor environment work can be met.
Owner:上海库曜新材料有限公司

Bridge damping support

The invention discloses a bridge damping support, and relates to the field of bridge construction. The bridge damping support sequentially comprises a top plate, a stainless steel plate, a polytetrafluoroethylene plate, a middle steel plate, a rubber block and a bottom basin, the rubber block is arranged in the bottom basin, and sealing rings are arranged between the rubber block and the middle steel plate. The rubber block comprises, by weight, 60-90 parts of natural rubber, 25-40 parts of butadiene rubber, 1-3 parts of sulfur, 3-6 parts of nano zinc oxide, 2-4 parts of stearic acid, 0.8-1.5parts of accelerant, 2-5 parts of silane coupling agent, 20-30 parts of reinforcing agent, 25-35 parts of carbon black and 1-3 parts of lecithin. The bridge damping support is mainly composed of the natural rubber and the butadiene rubber, has outstanding mechanical properties and is high in tensile strength and tearing strength, molecular chain breaking caused by the action of external mechanicalstress is not likely to happen, and the anti-seismic property is excellent. The lecithin serves as a modifier so that the carbon black can carry out in-situ grafting reaction, then the mechanical aging resistance of the rubber block is improved, and the service life is greatly prolonged.
Owner:浙江名博建设有限公司

Preparation method of antifouling and anticorrosive tablecloth material

The invention relates to a preparation method of an antifouling and anticorrosive tablecloth material, and belongs to the technical field of household materials. The method prepares the antifouling and anticorrosive tablecloth material by attaching hydrophobic nanopowder to a needle-punched nonwoven fabric of a polysulfonamide fiber and adding vinyl trimethoxysilane or stearic acid, the hydrophobic nanopowder is composed of nano-silica and nano-alumina, hydroxyl groups on the nano-silica and nano-alumina can react with amino groups in the polyethyleneimine, through a hydrogen bond and a van der Waals force, the surface of the needle-punched nonwoven fabric of the polysulfonamide fiber is adsorbed with a layer of polyethyleneimine monolayer, under the action of dicyclohexylcarbodiimide, thestearic acid can be dehydrated and condensed with the polyethyleneimine and further grafted with a long carbon chain, and a layer of long chain carbon molecules having a hydrophobic effect are grownon the surfaces of the nano-silica and the nano-alumina, thereby improving the hydrophobicity and self-cleaning ability of the needle-punched nonwoven fabric of the polysulfonamide fiber.
Owner:台州科金中高技术转移有限公司

Synthesis method and application of poly(p-phenylene terephthamide)

The invention relates to the technical field of polymer synthesis, and particularly discloses a synthesis method and application of poly(p-phenylene terephthamide). According to the synthetic method of the poly(p-phenylene terephthamide), a p-phenylenediamine solution and a terephthaloyl chloride melt are mixed in a closed manner and then are subjected to a condensation polymerization reaction in a single-order twin-screw extruder to generate the poly(p-phenylene terephthamide), the content of solvent impurities is low, and the influence on the reaction is small. The overall polymerization reaction rate is controlled by adjusting the ratio of the content of calcium chloride to the content of p-phenylenediamine in the p-phenylenediamine solution, so that the high-quality poly-p-phenylene terephthamide resin is produced, the technological process is simple, reaction dead zones are reduced, the product quality is stable, continuous production can be realized, the problem that continuous and stable polymerization of the poly-p-phenylene terephthamide cannot be carried out in an existing poly-p-phenylene terephthamide synthesis method is solved, and the method has a wide market prospect.
Owner:AFCHINA CORP CO LTD

Complementary food of12-15-month-old babies and processing method

The invention discloses complementary food of 12-15-month-old babies and a processing method. The complementary food which is scientific and reasonable, is abundant in nutrients and has flavor and taste is provided for babies at different months old. In the invention, a formula and a method of the complementary food are specially designed for the 12-15-month-old babies, and no detailed design is on the market at present; raw materials are materials with the excellent class from a pollution-free base, and grains, vegetables and meat that are digested and absorbed easily are selected. In the whole processing process, magnetized purified water or mineral water is adopted for washing and adding, so that a molecular structure of a product is magnetized; the magnetized purified water is used, so that the chance of pollution caused by heavy metals, pesticide residues and microorganisms is avoided, the original complementary food is more regular in structure, and the entropy is smaller; and therefore, the complementary food is more favorable for the babies.
Owner:DALIAN GAISHI FOOD

Method of preparing polymer network by utilizing controllable click chemical reaction system

InactiveCN103694470ASimple and convenient to disperseRegular molecular structurePolymer scienceChemical reaction
The invention discloses a method of preparing polymer network by utilizing a controllable click chemical reaction system. The method comprises the following steps: generating a free radial by utilizing a free radial initiator to initiate at a certain temperature; reducing high-valence-state metal ions into low-valence-state metal ions; and synchronously catalyzing an azide compound and an alkynyl compound to carry out click reaction. The method disclosed by the invention utilizes controllability of the free radial initiation efficiency under the temperature to synthesize the polymer network with a regular structure by the polyfunctional-group micromolecule or macromolecule azide compound and the alkynyl compound, so that generation macroscopic defects of the polymer network is avoided, formation of micro defects is reduced and regularity of the polymer network is improved, and therefore, strength of the polymer network is improved.
Owner:SOUTHEAST UNIV

Polyurethane asphalt composite emulsion and use method thereof

The invention relates to the field of preparation and application of composite materials, in particular to polyurethane asphalt composite emulsion and a use method thereof. The polyurethane asphalt composite emulsion is prepared from components A, B and C; the component A is polyurethane prepolymer emulsion; the component B is mixed emulsion of petroleum asphalt, fatty acid ethyl ester, carbodiimide, triethylene diamine, light calcium carbonate and a plasticizer; the component C is a mixed solution of a quaternary ammonium salt surfactant and low mass molecule alcohol. In the preparation and implementation processes, no organic solvents are used; meanwhile, the petroleum asphalt is low in toxicity and has small influence on the environment and the health of human; furthermore, the composite emulsion disclosed by the invention and a construction method thereof are higher in applicability to a base material, have a low requirement on the drying performance of the base material, and can be used in irregular surfaces. The method can promote rapid breakage of the composite emulsion, quick precipitation of particles and generation of crosslinking solidification, so that a composite coating film with high intensity, high low-temperature toughness and high watertightness can be obtained.
Owner:SICHUAN UNIV

Method for preparing 1,4,5,8-tetraaminonaphthalene tin chloride hydrochloride

The invention discloses a method for preparing 1,4,5,8-tetraaminonaphthalene tin chloride hydrochloride and relates to a method for preparing hydrochloride. The method aims at solving the technical problems of more by-products, high cost, low yield, tedious after-treatment and difficulty in industrial large-scale production of the existing method for preparing 1,4,5,8-tetraaminonaphthalene tin chloride hydrochloride. The method disclosed by the invention comprises the following steps: firstly, preparing high-purity 1,4,5,8-tetranitronaphthalene; and secondly, preparing high-purity 1,4,5,8-tetraaminonaphthalene tin chloride hydrochloride. Due to the method, high-purity 1,4,5,8-tetranitronaphthalene which is difficult to synthesize by virtue of the conventional method can be successfully prepared and 1,4,5,8-tetraaminonaphthalene tin chloride hydrochloride is prepared from stannous chloride and concentrated hydrochloric acid in high efficiency by virtue of adding catalytic addictives and the operation process is simplified. The method has the advantages of inexpensive and available selected raw materials, high yield, low cost and environmental friendliness and is suitable for industrial scale-up. The method is applied in the field of preparation of organic intermediate.
Owner:HARBIN INST OF TECH

Preparation method of polyether polyol with efficient catalytic activity

The invention belongs to the technical field of chemical industry synthesis, and particularly relates to a preparation method of a polyether polyol with efficient catalytic activity. The preparation method comprises: using a polyol compound as a starting agent, adding an alkali metal aqueous solution, carrying out distillation dehydration, adding an epoxy compound, carrying out a polymerization reaction, adding an alkali metal aqueous solution after completing the reaction, and carrying out distillation dehydration again to prepare the polyether polyol. According to the present invention, withthe application of the prepared polymer in the preparation of high-resilience polyether polyol, the characteristics of high reaction activity, short production period and high stability can be achieved; with the application of the prepared polyether polyol with efficient catalytic activity as the base polyether in the preparation of high-activity and high molecular-weight polyether polyol, the use of other catalysts is not required, the reaction activity of the whole polymerization system is significantly improved, and the product has characteristics of strong catalytic activity, fast reaction and low reaction temperature; and the preparation method is scientific, reasonable, simple and easy-performing.
Owner:SHANDONG BLUSR DONGDA CHEM

Preparation method of bisphenol A polyether polyol

The invention belongs to the technical field of chemical synthesis, and particularly relates to a preparation method of bisphenol A polyether polyol. The preparation method of the bisphenol A polyether polyol comprises the following steps: by adopting bisphenol A as an initiator and solid potassium hydroxide as a catalyst, firstly adding part of epoxypropane to carry out dissolving pre-reaction, then carrying out polymerization reaction with epoxypropane, and after the reaction is finished, refining the obtained polymer to obtain the bisphenol A polyether polyol. When the method provided by the invention is used for industrial production of bisphenol A polyether polyol, the method has the characteristics of high product quality stability, high production efficiency, short production period and no damage to production equipment. By adopting the preparation method provided by the invention, the universal bisphenol A polyether polyol which is regular in molecular structure, narrow in molecular weight distribution, stable in product quality and high in cost performance can be prepared. The preparation method is scientific, reasonable, simple and easy to implement.
Owner:SHANDONG BLUSR DONGDA CHEM

A method for preparing precise polymer networks

The invention discloses a method for preparing an accurate polymer network. The number of azide functional groups at the tail end of a polymer is controlled accurately by using a method combining reversible addition-fragmentation chain transfer (RAFT) and click chemistry, so that the number of crosslinking points is controlled and a regular polymer cross-linked network structure is prepared. In the method disclosed by the invention, gel in the polymer network is generated by performing a click reaction on two or more accurately-controlled functional end group azide or alkyne functional groups (E) at the tail end of a polymer chain and two or more end alkynyl or azide functional groups (E) via multiple steps of RAFT. The method has the advantages of accurate controllability of the number of crosslinking points and density of a polymer cross-linked network structure and suitability for various polymer network structures containing different functional groups.
Owner:SOUTHEAST UNIV
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