Electrostatic latent image developing toner and image forming method

An electrostatic latent image and toner technology, which is applied in the directions of developers, electrographics, optics, etc., can solve the problems of density deviation, insufficient charging amount, and the speed of frictional charging cannot catch up with the speed of toner consumption.

Inactive Publication Date: 2007-11-28
ZEON CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] On the other hand, when the amount of toner charge or the distribution of charge amount is inappropriate, for example, the amount of toner developed is too small, the image density is insufficient or density deviation occurs, or the portion of the photoreceptor that should not be developed by the toner Toner development occurs, resulting in blurring of background color contamination of printed matter
[0007] Especially printing that consumes a large amount of toner in a short period of time, such as high-speed mass printing or continuous full-scale (full pattern) printing, or just after the electrostatic latent image developing system has started operating or new toner has just been replenished. In the early stage of printing after the latent image developing system, the triboelectric charging speed of the toner cannot keep up with the consumption speed of the toner, so the above-mentioned insufficient charge amount or uneven charge amount distribution are prone to image development such as insufficient image density, density deviation, and blurring. bad question
[0008] Patent Document 1 describes that by controlling the work function difference between the four color toners to 0.5 in consideration of the balance of charging physical properties of magenta toner, cyan toner, yellow toner and black toner, eV or below can improve the color reproducibility of full-color images. However, no special consideration has been given to solving problems such as insufficient density, density deviation, and blurring of images that occur when the toner consumption rate is high or at the beginning of printing.

Method used

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  • Electrostatic latent image developing toner and image forming method
  • Electrostatic latent image developing toner and image forming method
  • Electrostatic latent image developing toner and image forming method

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0133] In the method for preparing the toner described above, in order to obtain the work function X (eV) of the toner in the work function measurement and the slope A of the normalized photoelectron yield relative to the excitation energy (normalized photoelectron yield / excitation energy) (1 For a toner for developing an electrostatic latent image in the range of 5.350, / eV) is preferably the following method.

[0134] (1) As described above, a suitable amount of phthalocyanine metal salt is dispersed in the polymerizable monomer for the sheath layer, and then the dispersion liquid is added to the aqueous dispersion liquid in which the core layer particles are dispersed, and polymerization is carried out. A sheath layer containing metal phthalocyanine salts is formed on the surface.

[0135] (2) As mentioned above, after mixing the coloring agent and the antistatic resin, the antistatic resin composition prepared in advance contains epoxy compounds with radical polymerizabili...

Embodiment

[0162] The present invention is further described in detail through the following examples, but the present invention is not limited to the following examples. Parts and % are based on weight unless otherwise specified.

[0163]

[0164] The experimental method carried out in this example is as follows.

[0165] (1) Particle size

[0166] Volume average particle size (Dv), particle size distribution that is the ratio of volume average particle size (Dv) to number average particle size (Dp) (Dv / Dp), and the number % of colored particles with a particle size of 4 μm or less Measured with a particle size analyzer (manufactured by Beckman Coulter, trade name "Mulchisizer"). The measurement of this maltoseiza was carried out under the conditions of pore diameter: 100 μm, medium: Isoton II, and number of measured particles: 100,000.

[0167] (2) Average circularity of toner

[0168] 10 ml of ion-exchanged water was placed in the container in advance, 0.02 g of surfactant (alky...

preparation example 1

[0192]100 parts of antistatic resin polymerized by 82 parts of styrene, 11 parts of butyl acrylate, and 7 parts of 2-acrylamide-2-methylpropanesulfonic acid (weight-average molecular weight: 20,000, glass transition temperature: 65°C ) was dispersed in a mixed solvent containing 24 parts of methyl ethyl ketone and 6 parts of methanol, and kneaded with rollers while cooling. While the antistatic resin was wound on a roll, 100 parts of cyan pigment C.I. Pigment Blue 15:3 (manufactured by Claria Anto) was slowly added and kneaded for 1 hour to prepare an antistatic resin composition. At this time, the initial distance between the rollers was 1mm, and then the distance was gradually increased, and the organic solvent (toluene / methanol=4 / 1 mixed solvent) was added in several times while observing the kneading state of the antistatic resin composition (mixed amount: 3 parts) ) and 3 parts glycidyl methacrylate (GMA).

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Abstract

Electrostatic latent image developing toner capable of providing a sufficient image density and being free from incorrect transferring even when a toner consumption speed is high, or an insufficient toner charge amount or a non-uniform charge amount distribution is likely to occur. Electrostatic latent image developing toner containing coloring particles including colorant and binding resin, wherein the work function X(eV) of the toner in work function measuring and the gradient A of standardized photoelectron yield (standardized photoelectron yield / exciting energy) (1 / eV) with respect to exciting energy are within ranges, 5.350.

Description

technical field [0001] The present invention relates to a toner for developing an electrostatic latent image (hereinafter simply referred to as "toner") for developing an electrostatic latent image in electrophotography, electrostatic recording, electrostatic printing, magnetic recording, etc. or magnetic latent images and other latent images having electrostatic properties. More specifically, the present invention relates to a toner for developing electrostatic latent images that can obtain sufficient image density and prevent transfer failure. [0002] The present invention also relates to an image forming method using the above toner for developing an electrostatic latent image. Background technique [0003] The electrophotography method refers to the electrostatic latent image formed on the photoreceptor is developed with an electrostatic latent image developer and toner, and then transferred to a recording material such as paper or OHP sheet, and then the transferred to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03G9/08G03G9/09G03G9/097
CPCG03G9/09G03G9/0823
Inventor 泉水庆太木所广人
Owner ZEON CORP
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