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High isolation protection material and preparation method thereof

A protective material and high barrier technology, applied in protective clothing, chemical instruments and methods, lamination, etc., can solve the problems of bulky materials, airtightness, condensation, etc., and achieve excellent corrosion resistance, wide application, and simple process Effect

Inactive Publication Date: 2008-05-28
THE QUARTERMASTER EQUIPMENT RESEARCH INSTITUTE OF THE GENERAL LOGISITIC DEPARTME +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But the disadvantage is that the material is bulky and airtight. When used in hot conditions, sweat evaporation is hindered, and "heat accumulation" occurs, and the human body is prone to overheating and heatstroke; produce "condensation"
The commonly used breathable nuclear, biological and chemical protective clothing usually uses activated carbon coating method or activated carbon fiber layer to achieve the purpose of nuclear, biological and chemical protection, but the use time of these protective materials is limited, usually not more than 6 to 8 hours
Especially for some chemicals or poisons with strong penetrating ability and corrosion ability, such as unsymmetrical dimethylhydrazine, dinitrogen tetroxide, red smoke nitric acid, etc., these protective materials cannot prevent the entry of poisonous gas and poisonous agents well, and the protective Clothing is too big for protection

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] (1) Preparation of tear-resistant layer

[0032] Carry out pure spinning of aramid fiber 1313 to obtain flame-retardant fibers, and then pad-roll the finishing solution comprising organic fluorine oil-proof and waterproof finishing agent 40g / l and DMDHEU10g / l, the liquid-rolling rate is 40%, and finally dry and dry at temperature Bake at 140°C for 0.5 minutes to obtain a tear-resistant fabric layer with functions such as oil and water repellency;

[0033] (2) Preparation of bonding layer

[0034] The adhesive layer is made of a microporous polytetrafluoroethylene film material with a film thickness of 10 μm and a certain barrier effect by a method commonly used by those skilled in the art;

[0035] (3) Preparation of high barrier layer

[0036] The high barrier layer consists of an oxygen transmission rate of 9cm 3 / m 2 .24h, ethylene-vinyl alcohol copolymer film material with a high barrier effect and a film thickness of 10 μm is made by a method commonly used by t...

Embodiment 2

[0043] (1) Preparation of tear-resistant layer

[0044] Blend arylsulfone to obtain flame-retardant fibers, then pad-roll the finishing solution comprising 120g / l of organic fluorine oil-proof and waterproof finishing agent and 40g / l of hexamethylolmelamine, the rolling rate is 80%, and finally dry , and baked at a temperature of 180°C for 3 minutes to obtain a tear-resistant fabric layer with functions such as oil and water repellency;

[0045] (2) Preparation of bonding layer

[0046] The bonding layer is made of a microporous polytetrafluoroethylene composite membrane material with a film thickness of 50 μm and a certain barrier effect, using methods commonly used by those skilled in the art;

[0047] (3) Preparation of high barrier layer

[0048] The high barrier layer consists of an oxygen transmission rate of 9cm 3 / m 2 .24h, the polyvinylidene chloride film material with high barrier effect and film thickness of 90 μm is made by the method commonly used by those ski...

Embodiment 3

[0055] (1) Preparation of tear-resistant layer

[0056] Blending polyphenylene sulfide to obtain flame-retardant fibers, then padding the finishing liquid comprising 80 g / l of organic fluorine oil-proof and waterproof finishing agent and 20 g / l of epoxy resin, the liquid rolling rate is 60%, and finally drying, And baked at a temperature of 160°C for 1.5 minutes to obtain a tear-resistant fabric layer with functions such as oil and water repellency;

[0057] (2) Preparation of bonding layer

[0058] The adhesive layer is made of a TPU film material with a certain barrier effect with a film thickness of 50 μm using methods commonly used by those skilled in the art;

[0059] (3) Preparation of high barrier layer

[0060] The high barrier layer is made of a polyacrylonitrile film material with a film thickness of 30 μm and a high barrier effect, using the methods commonly used by those skilled in the art, which not only prevents the intrusion of poisonous gas, but also prevents...

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Abstract

The invention relates to a protective material with high barrier property and a method of preparation of the material. The protective material is composed of an anti-tear layer, an adhesive layer, a high barrier layer, and a seal layer from outer to inner successively, wherein, the high barrier layer can prevent biochemical toxic agent and toxic gas from passing and has the function of corrosion resistance; the seal layer is made of film materials with better thermal stability and mechanical strength, and has the protective effect for high barrier layer; the adhesive layer can mainly increase the binding force between fabric and barrier film, and prevent delamination; the anti-tear layer is made of fabric which is flame retardant or non-flame retardant and can increase the anti-tear function of the composite layer and strength force of all directions of the composite material. The layers are adhered together by adhesive, and then made into protective materials with high barrier property which has multilayer and various protective functions. The protective material has the advantages of excellent anti-tear property, excellent corrosion resistance, and light weight, which can be used for emergency rescue clothing, biochemical protective clothing, risk chemical dealer protective clothing, missile and rocket inflowing protective clothing, etc.

Description

technical field [0001] The invention relates to a protective material, in particular to a high-barrier protective material and a preparation method thereof. Background technique [0002] In the prior art, the double-sided coated tape of butyl rubber or chlorobutyl rubber is usually used as the isolated nuclear, biological and chemical protection material, which mainly relies on its rubber layer or plastic layer to isolate nuclear dust and slow down the biological and chemical agents. permeation of. The material has good protection against persistent poisons such as mustard gas, Viex, and soman, and has good cold resistance, anti-aging, and decontamination resistance. But the disadvantage is that the material is bulky and airtight. When used in hot conditions, the evaporation of sweat is hindered, and the phenomenon of "heat accumulation" will occur, and the human body is prone to overheating and heatstroke; "Condensation" occurs. Commonly used breathable nuclear, biologic...

Claims

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Application Information

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IPC IPC(8): A41D31/02B32B5/00B32B7/10B32B27/08B32B27/12B32B37/12B32B38/08B32B38/16
Inventor 郝新敏张建春梁高勇王岩
Owner THE QUARTERMASTER EQUIPMENT RESEARCH INSTITUTE OF THE GENERAL LOGISITIC DEPARTME
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