Pattern forming method and method for forming multilayer wiring structure
A pattern and wiring pattern technology, applied in conductive pattern formation, multilayer circuit manufacturing, coating, etc., can solve problems such as fine wiring and achieve high-resolution effects
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[0170] The following examples will be given to illustrate the present invention in detail, but the present invention is not limited to these examples.
Synthetic example 1
[0171] (Synthesis Example 1: Synthesis of Compound A)
[0172] Compound A was synthesized through the following two steps.
[0173] 1. Step 1 (synthesis of compound a)
[0174] Dissolve 24.5 g (0.12 mol) of 1-hydroxycyclohexyl phenyl ketone in a mixed solvent of 50 g DMAc and 50 g THF, and slowly add 7.2 g (0.18 mol) of NaH (60% oil suspension) in an ice bath. 44.2 g (0.18 mol) of 11-bromo-1-undecene (95%) was dripped there, and it reacted at room temperature. After 1 hour the reaction was complete. The reaction solution was poured into ice water and extracted with ethyl acetate to obtain a mixture containing Compound a as a yellow solution. 37 g of this mixture were dissolved in 370 mL of acetonitrile, and 7.4 g of water were added. 1.85 g of p-toluenesulfonic acid monohydrate was added and stirred at room temperature for 20 minutes. The organic phase was extracted with ethyl acetate and the solvent was evaporated off. Compound a was separated by column chromatography (...
Embodiment 1~4
[0189] Monomers 1 to 4 having the following compositions were dissolved in a mixed solution of 1-methoxy-2-propanol / methyl ethyl ketone (1 / 1 weight ratio) to prepare a 10 wt % solution. Then, the above-mentioned photoinitiator-bonded glass substrate was immersed in this solution, and exposed for 1 minute with an exposure machine (UVX-02516S 1LP01, manufactured by Usio Electric Co., Ltd.). After exposure, it was washed well with acetone and pure water. Graft-treated substrates 1 to 4 were obtained as described above.
[0190] [Composition (molar ratio) of the monomers constituting the graft polymer]
[0191] Monomer composition 1: Perfluorooctylethyl methacrylate (FMAC) (50%) / Dimethacrylamide (50%)
[0192] Monomer composition 2: FMAC (50%) / hydroxyethyl methacrylate (25%) / dimethylacrylamide (50%)
[0193] Monomer composition 3: FMAC (50%) / acrylamide (25%) / 2-vinylpyridine (25%)
[0194] Monomer composition 4: FMAC (50%) / acrylamide (40%) / glycidyl methacrylate (10%)
[0195] ...
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