Method for preparing 2,2-di(3-amido-4-(2,4-dinitrophenoxy) phenyl] propane
A technology of dinitrophenoxy and dinitro, which is applied in 2 fields, can solve problems such as patents or literature reports, and achieve the effects of less types of use, simple operation, high yield and purity
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Embodiment 1
[0028] 25.8 grams (0.10 moles) of 2,2-bis(3-amino-4-hydroxyphenyl) propane, 44.6 grams (0.22 moles) of 2,4-dinitrochlorobenzene, 110.4 grams (0.80 moles) of potassium carbonate , 70 milliliters of N,N-dimethylformamide and 280 milliliters of benzene were put into the reaction kettle, under nitrogen atmosphere, stirred, heated to reflux and separated from water for 18 hours, concentrated the reaction solution, recovered the solvent for recycling, and cooled the reactant system , add water, the solid product is separated out, washed 2 to 3 times with hot water, and dried to obtain 2,2-bis[3-amino-4-(2,4-dinitrophenoxy)phenyl]propane with a purity of 99.2%, according to the amount and theoretical amount of 2,2-bis[3-amino-4-(2,4-dinitrophenoxy)phenyl]propane actually obtained, the calculated 2,2-bis[3- The yield of amino-4-(2,4-dinitrophenoxy)phenyl]propane was 95.3%.
Embodiment 2
[0030] 25.8 grams (0.10 moles) of 2,2-bis(3-amino-4-hydroxyphenyl) propane, 54.4 grams (0.22 moles) of 2,4-dinitrobromobenzene, 55.2 grams (0.40 moles) of potassium carbonate , 150 milliliters of N, N-dimethylacetamide, 200 milliliters of benzene and 15 milliliters of xylene were put into the reaction kettle, under nitrogen atmosphere, stirred, heated to reflux and separated from water for 6 hours, concentrated the reaction solution, recovered the solvent for recycling , cooling the reactant system, adding water, the solid product was precipitated, washed 2 to 3 times with hot water, and dried to obtain 2,2-bis[3-amino-4-(2,4-dinitrophenoxy)phenyl ] propane, the purity is 99.5%, according to the actual amount and theoretical amount of 2,2-bis[3-amino-4-(2,4-dinitrophenoxy) phenyl] propane, calculate 2,2 - The yield of bis[3-amino-4-(2,4-dinitrophenoxy)phenyl]propane was 82.7%.
Embodiment 3
[0032] 25.8 grams (0.10 moles) of 2,2-bis(3-amino-4-hydroxyphenyl) propane, 40.5 grams (0.20 moles) of 2,4-dinitrochlorobenzene, 10.6 grams (0.10 moles) of sodium carbonate , 60 milliliters of N-methyl-2-pyrrolidone, 100 milliliters of benzene and 23 milliliters of dichlorobenzene were put into the reaction kettle, under a nitrogen atmosphere, stirred, heated to reflux for water separation and reacted for 16 hours, concentrated the reaction solution, and recovered the solvent for circulation Use, cool the reactant system, add water, precipitate a solid product, wash 2 to 3 times with hot water, and dry to obtain 2,2-bis[3-amino-4-(2,4-dinitrophenoxy)benzene Base] propane, the purity is 99.0%, according to the amount and theoretical yield of 2,2-bis[3-amino-4-(2,4-dinitrophenoxy)phenyl]propane actually obtained, calculate 2 , The yield of 2-bis[3-amino-4-(2,4-dinitrophenoxy)phenyl]propane was 95.1%.
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