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Exhaust purification cellular catalyst for enamelling machine and method of producing the same

A technology of honeycomb catalyst and enamelling machine, applied in physical/chemical process catalysts, chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, etc., can solve high exhaust back pressure and shorten catalyst service life , Catalyst poisoning and other problems, to achieve the effect of improving durable activity, lowering temperature, and small air resistance

Active Publication Date: 2010-06-09
WUXI WEIFU ENVIRONMENT PROTECTION CATALYST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If these solvents are directly volatilized into the atmosphere, the following problems will occur: (1) pollute the environment: benzene, xylene and cresol compounds will cause great damage to people's physical and mental health; (2) waste of energy: three organic compounds have high combustion Calorific value, generally 32406~43208kJ / kg; (3) Potential safety hazards in production: the distillation range of xylene is 130℃~150℃, and the distillation range of cresol is 190~210℃. During the production process, organic matter may condense and accumulate in Pipeline, thus causing production safety accidents
At present, this type of catalyst uses cordierite as a carrier, and then supports noble metal Pd or transition metal oxides, but the cordierite carrier has many micropores, the exhaust back pressure is high, and the temperature of the catalyst bed is 60-100°C higher than the temperature before catalysis. , it is easy to cause high-temperature sintering deactivation of the catalyst; at the same time, hydrocarbons are very easy to deposit on the surface of the honeycomb carrier, so that the catalyst is physically poisoned and the service life of the catalyst is shortened

Method used

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  • Exhaust purification cellular catalyst for enamelling machine and method of producing the same
  • Exhaust purification cellular catalyst for enamelling machine and method of producing the same
  • Exhaust purification cellular catalyst for enamelling machine and method of producing the same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Preparation of enameled machine exhaust gas purification metal honeycomb catalyst M1: Select 50 mesh metal carrier for metal honeycomb, and the shape is a cube of 80mm × 80mm × 80mm, and heat it at 800 ℃ for 2h; The liquid water is separated out, and the weight of the added water is recorded 32g; the palladium nitrate solution containing 5g of palladium is weighed, diluted to 318.4g, and the cerium-zirconium solid solution of 995g of palladium nitrate is supported by the equal volume dipping method; the gamma-alumina of 4000g is weighed; Then weigh 8000 g of deionized water; mix γ-alumina, deionized water and the cerium-zirconium solid solution loaded with palladium nitrate into a container with a stirrer, and stir to obtain a suspension; the suspension is ground by a ball mill to Granularity D 90 = 20 microns; immerse the above-mentioned pretreated metal honeycomb carrier in the slurry, stay for 2 seconds, and pull out at a speed of 30 mm per second; dry the metal hone...

Embodiment 2

[0025] Preparation of enameled machine exhaust gas purification metal honeycomb catalyst M2: The specific preparation method is basically the same as that of Example 1 of this part, the difference is that the metal honeycomb chooses a 200 mesh metal carrier. The results of catalyst activity evaluation and bed temperature test are shown in Table 1.

Embodiment 3

[0027] Preparation of enameled machine exhaust gas purification metal honeycomb catalyst M3: The specific preparation method is basically the same as that of Example 1 of this part, the difference is that the metal honeycomb selects a 600 mesh metal carrier. The results of catalyst activity evaluation and bed temperature test are shown in Table 1.

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PUM

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Abstract

The invention discloses a honeycomb catalyst for purifying the waste gas of enameling machines, which adopts catalytic combustion method to purify the industrial waste gas. The invention also discloses a preparation method of the catalyst. The invention adopts the technical proposal that the honeycomb catalyst for purifying the waste gas of enameling machines adopts the metallic honeycomb or honeycomb ceramics as ceramic frames; a coating made of mixture of ceria-zirconia solid solution and gamma-alumina is covered on the ceramic frames; the ceria-zirconia solid solution is loaded with noble metal palladium, platinum or palladium and platinum. The honeycomb catalyst has the advantages of less liability to deactivation of high temperature sintering and long service life.

Description

technical field [0001] The invention discloses a honeycomb catalyst for purifying waste gas of an enameling machine by using a catalytic combustion method to purify industrial waste gas, and at the same time, the invention also discloses a preparation method of the catalyst. Background technique [0002] The enameled paint used in the production of enameled wires contains a large amount of diluents and organic solvents, and its main components are benzene, xylene and cresol. These organic compounds are volatilized from the paint film when it is heated and cured. If these solvents are directly volatilized into the atmosphere, the following problems will occur: (1) Pollution of the environment: benzene, xylene and cresol compounds cause great damage to people's physical and mental health; (2) Energy waste: three organic compounds have high combustion The calorific value is generally 32406~43208kJ / kg; (3) Hidden danger of production safety: the distillation range of xylene is 1...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/56B01J35/04B01D53/86F23G7/07
Inventor 贾莉伟欧建斌
Owner WUXI WEIFU ENVIRONMENT PROTECTION CATALYST
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