Method for drying and burning alkali-containing aluminosilicate slurry

A technology of silicate and slurry, which is applied in the fields of alumina/hydroxide, sustainable manufacturing/processing, and climate sustainability. It can solve problems such as bulky equipment, high equipment maintenance costs, and condensation, and achieve material The effect of sufficient chemical reaction, high capacity per unit volume, and simple process flow

Active Publication Date: 2008-09-17
中铝中州铝业有限公司
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AI Technical Summary

Problems solved by technology

Existing clinker production process devices generally use rotary kilns, and the equipment generally has a diameter of 3-5 meters and a length of 60-120 meters. It needs a large reducer and a high-power motor to drive it to rotate. The flow direction of the drying medium is opposite to that of the drying medium. At the same time, in this equipment, the materials go through four processes of drying, preheating, decomposition and calcination from entering the equipment to leaving the equipment. These four processes are completed in a rotary kiln. This drying and firing process and equipment have many disadvantages: first, the equipment is very bulky and occupies a large area; second, the power consumption is large, and two-thirds of the power is used for the rotation of the equipment body; third, the energy consumption is high. , because the calcined material needs to be cooled before it can be transported into the next process, and the small particles in the piled state have poor heat exchange effect and need to be cooled with a large amount of cooling water, so the heat energy consumption is large and the heat utilization is low
5. Because it is a rotary device, its transmission system wears a lot, the refractory lining is easily damaged, and the maintenance cost of the equipment is high
[0006] For alkaline, Cl - , SO 3 2- The main technical problem in the atomization drying and firing of relatively high slurry is the problem of scabbing. There are three main reasons for scabbing: one is that the slurry is in contact with the wall of the drying furnace before drying, especially the viscous Larger materials are more prone to scarring on the furnace wall; second, due to the high temperature during the firing process, especially those containing alkali, Cl - , SO 3 2- Higher materials, after volatilization, are easy to condense on the lower temperature furnace wall and cause scarring; third, the liquid phase that appears in the low melting point material during the high temperature process is easy to form scarring on the cold furnace wall

Method used

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  • Method for drying and burning alkali-containing aluminosilicate slurry

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0065] 1. Slurry material: raw bauxite slurry, moisture content 36%-43%, sodium oxide 15%-20%, alumina 22%-30%, particle size composition 100# sieve (English sieve number) 20%, 9% under 325# sieve.

[0066] 2. Test condition 1: Firing temperature 500-800℃, high-temperature flue gas flow rate 3-8m / s, negative pressure in the furnace 500-800Pa. After the bauxite dry raw meal is sintered, the particle size distribution of the material is as follows:

[0067] Sieve No. 100# sieve 100-200# sieve 200-325# sieve 325# sieve bottom (English sieve size)

[0068] Percentage 29.2 58.4 8.6 3.8

[0069] 3. Test condition 2: Firing temperature 800-1000℃, high-temperature flue gas flow rate 10-20m / s, negative pressure in the furnace 600-1000Pa. After the bauxite dry raw meal is sintered, the particle size distribution of the material is as follows:

[0070] Sieve No. 100# sieve 100-200# sieve 200-325# sieve 325# sieve bottom (English sieve size)

[0071] Percentage 32.5 52.1 14.2 0.8

...

Embodiment 2

[0077] 1. Slurry material: silicon slag produced in the alumina production process, with a moisture content of 35%-45%, a sodium oxide content of 17%-21%, and a particle size composition of 100# sieve (imperial sieve number) 21%, 325# sieve Down 9%.

[0078] 2. Test condition 1: Firing temperature 500-800℃, high-temperature flue gas flow rate 3-8m / s, negative pressure in the furnace 500-800Pa. After the silicon slag is fired in a suspension fluid state, the particle size distribution of the material is as follows:

[0079] Sieve No. 100# sieve 100-200# sieve 200-325# sieve 325# sieve bottom (English sieve size)

[0080] Percentage 35.0 37.8 18.2 9.0

[0081] 3. Test condition 2: Firing temperature 600-1000℃, high-temperature flue gas flow rate 10-20m / s, furnace negative pressure 600-1000Pa. After the silicon slag is fired in a suspension fluid state, the particle size distribution of the material is as follows:

[0082] Sieve No. 100# sieve 100-200# sieve 200-325# sieve 32...

Embodiment 3

[0089] 1. Slurry material: tailings slurry of tailings after bauxite flotation, containing 44%-50% of alumina.

[0090] 2. Test conditions: drying temperature 600-800°C, high-temperature flue gas flow rate 10-20m / s, negative pressure in the furnace 500-800Pa. The particle size distribution of the dried material is as follows:

[0091] Sieve No. 100# sieve 100-200# sieve 200-325# sieve 325# sieve bottom (English sieve size)

[0092] Percentage 80.4 10.6 5.6 4.4

[0093] 3. Conclusion: The suspension fluid firing system device established by this technical invention is used to carry out the industrial test of drying and activating tailings powdery materials after bauxite flotation. Since the technical device has sufficient gas-solid heat exchange, the furnace The thermal intensity is uniform, the drying and activation time is short, the activation performance of flotation tailings is more than 60% higher than other high-temperature drying equipment, and the particle size distr...

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Abstract

The invention relates to a method of drying and burning alkaliferous aluminosilicate slurry, which is characterized in that the comprises two steps of atomizing drying and circular burning, the atomized slurry fogdrop is to contact with the vertically risen thermal current for drying, and then entering the firing furnace after circulation and growing; the slurry is continuously and circularly burnt in the furnace, the quality is preferably and the product is finished when the agglomerate material with higher specific gravity is out of the firing furnace. The method of the invention has the advantages that the slurry is fully atomized, the powdery material can fully contact with high temperature fume, and the heat exchange is promptly and completely with high heat transfer efficiency and low thermal loss. The sintering time of the powdery material in the furnace is short, the chemical reaction of material is fully, the unit volume productive capacity is higher with simple technological process and equipment, long performance period and low maintenance cost. The powdery material can realize closed feeding and closed discharge with slight dust pollution for environment.

Description

technical field [0001] A method for drying and firing alkali-containing aluminosilicate slurry, relating to an atomization drying and circulation firing method for alkali-containing aluminosilicate slurry, which is used for raw slurry, silicon Drying and firing of slag slurry and red mud slurry, pre-roasting of bauxite, and roasting of aluminum hydroxide. Background technique [0002] Regarding drying technology, there are many mature technologies, such as atomization drying, fluidized drying, flash drying and so on. However, for the drying and firing of alkali-containing materials, there is no mature application technology in the industry at present. For example, the mature dry kiln drying pre-decomposition technology in the cement industry has a great impact on the alkali metal oxide content R in raw materials. 2 O(K 2 O+0.65Na 2 O) the requirements are also very harsh, generally less than 1.0-1.5%, Cl - The content requirement is less than 0.015-0.023%, SO 3 2- The...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F7/02
CPCY02P20/10
Inventor 娄东民王二星李太昌程旭闫禄军莫进超邢体义刘国红赵东峰王松林韩黎明王涛李华栗志林张立宙靳古功胡国清
Owner 中铝中州铝业有限公司
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