Blend of carbon dioxide-epoxypropane co-polymer and polycaprolactone and poly butylene succinate and preparation method
A technology of propylene oxide and carbon dioxide, which is used in the field of providing blends of PPC, PCL and PBS and its preparation, can solve the problems of downstream manufacturers' application impact, hindering market promotion, easy agglomeration during storage and transportation, and achieve product performance. Excellent, suitable for industrial production, the effect of ordinary equipment
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Embodiment 1
[0015] Take by weighing 2000 grams of PPC (manufactured by Mengxi High-tech Group Company, glass transition temperature is 35 ℃), 20 grams of maleic anhydride, 20 grams of lipophilic modified light calcium carbonate (particle size is 800 mesh), 20 grams of stearic acid grams, 50 grams of PCL, and 50 grams of PBS were added to a high-speed mixer respectively, and stirred for 5 to 10 minutes at a temperature not exceeding 35°C. According to the equipment, the speed of the mixer could be 500 to 1500 rpm; Cold mixing, extruding and granulating with a single-screw extruder or a twin-screw extruder, the heating temperature of each zone is set according to the extrusion situation, and the maximum does not exceed 170°C. The obtained pellets were measured with a differential scanning calorimeter (DSC), and the glass transition temperature was found to be 51.2°C.
Embodiment 2
[0017] Take by weighing PPC (with embodiment 1) 2000 grams, maleic anhydride 30 grams, lipophilic modified light calcium carbonate (particle size is 1250 order) 50 grams, epoxy soybean oil 10 grams, PCL is 100 grams, PBS is 100 grams, cold mixing and extrusion granulation are the same as in Example 1. The obtained pellets were measured with a differential scanning calorimeter (DSC), and the glass transition temperature was 57.05°C.
Embodiment 3
[0019] Take by weighing PPC (with embodiment 1) 2000 grams, maleic anhydride 20 grams, light calcium carbonate (particle size is 1250 order) 100 grams, stearic acid 20 grams, PCL is 160 grams, PBS is 40 grams, cold mix Extrusion granulation situation is the same as embodiment 1. The obtained pellets were measured with a differential scanning calorimeter (DSC), and the glass transition temperature was found to be 57.3°C.
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