Resin for alcohol soluble ink vehicle and method for preparing same
An ink binder and alcohol-soluble technology, which can be used in inks, applications, household appliances, etc., can solve the problems of poor gloss, transparency, and resistance, physical and mental health damage of workers in the working environment, and air pollution, and achieve good pigments Wetting and dispersibility, beneficial to market transformation, and the effect of reducing pollution
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Embodiment 1
[0020] The binder resin consists of the following components in parts by weight: 12 parts of acrylic acid, 40 parts of styrene, 120 parts of methyl methacrylate, 25 parts of dimethylaminoethyl methacrylate, butyl acrylate 45 parts of esters, 17 parts of β-hydroxyethyl acrylate, 130 parts of butyl methacrylate, 12 parts of N-diisobutylcyanide, 270 parts of absolute ethanol, 90 parts of ethyl acetate, and 130 parts of isopropanol.
[0021] The preparation method is as follows: pre-mix the components in the above formula, take 1 / 3 as liquid A, and the other 2 / 3 as liquid B; heat liquid A to 60°C in a reactor equipped with a reflux condenser and start slowly dripping Add liquid B; add all liquid B dropwise in 4 hours, and at the same time cool down to control the reaction temperature at 65°C, and keep it at 65°C for 20 hours; the acid value of the material reaches 12mgKOH / g, the viscosity is 9200mPa·s / 25°C, and the viscosity The growth range for 2 consecutive hours is less than 20...
Embodiment 2
[0023] The binder resin consists of the following components in parts by weight: 17 parts of acrylic acid, 60 parts of styrene, 160 parts of methyl methacrylate, 35 parts of dimethylaminoethyl methacrylate, butyl acrylate 55 parts of esters, 23 parts of β-hydroxyethyl acrylate, 170 parts of butyl methacrylate, 15 parts of N-diisobutylcyanide, 350 parts of absolute ethanol, 110 parts of ethyl acetate, and 170 parts of isopropanol.
[0024] The preparation method is as follows: pre-mix the components in the above formula, take 1 / 3 as liquid A, and the other 2 / 3 as liquid B; heat liquid A to 65°C in a reactor equipped with a reflux condenser and start slowly dripping Add liquid B; add all liquid B dropwise in 3 hours, and at the same time cool down to control the reaction temperature at 70°C, and keep it at 70°C for 18 hours; the acid value of the material reaches 23mgKOH / g, the viscosity is 9800mPa·s / 25°C, and the viscosity The growth range for 2 consecutive hours is less than 2...
Embodiment 3
[0026] The composition of the binder resin is the following components in parts by weight: 15 parts of acrylic acid, 50 parts of styrene, 140 parts of methyl methacrylate, 30 parts of dimethylaminoethyl methacrylate, butyl acrylate 50 parts of β-hydroxyethyl acrylate, 20 parts of β-hydroxyethyl acrylate, 150 parts of butyl methacrylate, 14 parts of even N-diisobutylcyanide, 320 parts of absolute ethanol, 100 parts of ethyl acetate, and 150 parts of isopropanol.
[0027] The preparation method is as follows: pre-mix the components in the above formula, take 1 / 3 as liquid A, and the other 2 / 3 as liquid B; heat liquid A to 63°C in a reactor equipped with a reflux condenser and start slowly dripping Add liquid B; finish adding liquid B dropwise in 3.5 hours, and at the same time carry out cooling to control the reaction temperature at 68°C, and keep it at 68°C for 22 hours; the acid value of the material reaches 15mgKOH / g, the viscosity is 8500mPa·s / 25°C, and the viscosity The gro...
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