Nutrient for inhibiting sulfate reducing bacteria in oilfield water and application of nutrient

A nutrient and sulfate technology, which is applied in waste fuel, biological water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problems of increasing construction cost, high-temperature oil reservoir combustion, and increasing the cost of nutrient solution, etc. To achieve the effect of simple implementation process and low cost

Active Publication Date: 2010-06-23
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0014] CN1995694 relates to an oil displacement method in which sewage is injected into original microorganisms for enhanced crude oil recovery. The invention utilizes various microorganisms brought into oil reservoirs during long-term water injection and adapted to the reservoir environment for oil displacement, and avoids the adaptation of microorganisms and oil reservoirs. However, the defect of this invention is that during the construction of the formation, due to the use of aerobic fermentation, aerobic bacteria and anaerobic bacteria compete for survival in the formation, and since denitrifying bacteria are anaerobic bacteria, it is difficult to Medium growth, when beneficial microorganisms are consumed at concentrations below 10-10 3 per mL, it needs to be re-cultivated on the ground to a concentration of 3×10 8 Then re-inject and replenish. This method of using this microorganism to ferment on the ground and re-inject into the formation increases the cost of nutrient solution; secondly, a certain concentration of dissolved oxygen is always required during the construction process. If high-quality crude oil is used as a carbon source, the injected air will aggravate the corrosion of pipelines and equipment, which not only increases the construction cost, but also may cause combustion in high-temperature oil reservoirs; and the injection process requires that the maximum value of sulfate-reducing bacteria be less than 10 3 pcs / mL, the applicable range of water quality is narrower

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Xinjiang Karamay Oilfield, its reservoir geological parameters: effective permeability 2.09×10 -4 μm 2 , the porosity is 19.5%, the salinity of oilfield injection water is 2892.3mg / L, and the reservoir temperature is 65°C; the composition ratio of nutrients is calculated by weight percentage: sugarcane molasses or beet molasses: 90%, ammonium phosphate: 1.5%, Ammonium chloride: 1.8%, ammonium sulfate: 2.5%, ammonium nitrate: 1.5%, sodium nitrate: 1.3%, diammonium hydrogen phosphate: 0.75%, disodium hydrogen phosphate: 0.5%, potassium dihydrogen phosphate: 0.15%, note Water well injection 10M per day 3 , the nutrients are used at 5% of the daily water injection weight; after the above nutrients are dissolved in the water injection well, the pump truck squeezes them into the formation through the water injection well. The construction period is 30 days, and the nutrients are injected twice a year in two rounds. Injected once every 6 months, the sulfate-reducing bacteria...

Embodiment 2

[0031] Xinjiang Karamay Oilfield, its reservoir geological parameters: effective permeability 2.0×10 -3 μm 2 , the porosity is 25.4%, the salinity of oilfield injection water is 7869.3mg / L, and the reservoir temperature is 42°C; the nutrient composition ratio is calculated by weight percentage: sugarcane molasses or beet molasses: 95%, ammonium phosphate: 1%, chlorine Ammonium chloride: 0.65%, ammonium nitrate: 1.5%, sodium nitrate: 0.5%, diammonium hydrogen phosphate: 0.1%, disodium hydrogen phosphate: 1.2%, potassium dihydrogen phosphate: 0.05%, daily water injection of water injection well 15M 3 , the nutrients are used at 3% of the daily water injection weight; after dissolving the above nutrients with the injection water of the injection well, the pump truck squeezes them into the formation through the injection well. The construction period is 27 days, and the nutrients are injected twice a year , injected once every 6 months; before the injection, the sulfate-reducing ...

Embodiment 3

[0033] Xinjiang Karamay Oilfield, its reservoir geological parameters: effective permeability 4.0×10 -3 μm 2 , the porosity is 35.0%, the salinity of oilfield injection water is 3572.5mg / L, and the reservoir temperature is 80°C; the nutrient composition ratio is calculated by weight percentage: sugarcane molasses or beet molasses: 95%, ammonium phosphate: 1.5%, chlorine Ammonium chloride: 0.5%, ammonium nitrate: 1.5%, diammonium hydrogen phosphate: 0.5%, disodium hydrogen phosphate: 1%, water injection well daily 22M 3 , the nutrients are used at 4% of the daily water injection weight; after dissolving the above nutrients with the injection water of the injection well, the pump truck squeezes them into the formation through the injection well. The construction period is 29 days, and the nutrients are injected twice a year , injected once every 6 months. The sulfate-reducing bacteria detected in the production fluid of the oil production well before injection was 105 / mL, and ...

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Abstract

The invention relates to a nutrient for inhibiting sulfate reducing bacteria in oilfield water and application of the nutrient. The nutrient contains the following components by weight percent: 20-95 percent of cane molasses or beet molasses, and / or 1-45 percent of ammonium phosphate, and / or 0.5-10 percent of ammonium chloride, and / or 0.5-2.5 percent of ammonium sulfate, and / or 1-18.5 percent of ammonium nitrate, and / or 0.05-49 percent of sodium nitrate; and / or 0.05-1 percent of diammonium hydrogen phosphate, and / or 0.05-1.2 percent of disodium hydrogen phosphate, and / or 0.5-2 percent of dipotassium phosphate and / or 0.05-1.5 percent of potassium dihydrogen phosphate. The nutrient with weight accounting for 0.5-5 percent of weight of filled water is taken, is dissolved by using constructional injection water or oilfield surface water and is squeezed into stratum by a pump truck through a water injection well. The nutrient can activate nitrifying bacteria flora in source bacteria flora of stratum water or oilfield source water and can inhibit the growth of sulfate reducing bacteria. After 16 hours to 52 days, the content of sulfate reducing bacteria is 0-102 / mL. The yield of crude oil is increased by 10 percent to 30 percent.

Description

technical field [0001] The invention relates to a method for inhibiting sulfate bacteria by using microorganisms, in particular to a nutrient and application thereof for inhibiting sulfate-reducing bacteria by using original microorganisms while improving oil recovery. Background technique [0002] There are a variety of native bacteria in the surface water and formation water of the secondary and tertiary oil recovery processes, among which the most harmful to the oil field surface oil recovery system is the sulfate reducing bacteria (Sulfate Reducing Basteria, abbreviated as SRB), the sulfate reducing bacteria SRB is a group The general term for a variety of bacteria that can reduce sulfate to hydrogen sulfide under anaerobic conditions, including bacteria of the genus Desultphovibrio and Desulphfotomaculum, widely present in oilfield sewage reinjection systems and oil reservoirs in an oxygen-deficient environment. The activity of SRB flora can produce toxic gas H 2 S, t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F3/34C02F3/28
CPCY02E50/30
Inventor 牛春革陈爱华李子叔方新湘于娟帕提古丽陈永立
Owner PETROCHINA CO LTD
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