Acid-free pre-hydrolysis enzymolysis-free method for preparing bamboo pulp of Dendrocalamus giganteus Munro series
A technology of pre-hydrolysis and bamboo pulp, which is applied in the direction of pulping with inorganic alkali, pulp bleaching, water/steam pretreatment, etc., can solve the problems of restricting the development of pulp industry, low output, high refractory treatment, etc., and achieve clean The effect of chemical production
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Embodiment 1
[0032] Send the prepared Tianlong bamboo slices into the steaming chamber and steam at 130°C for 15 minutes. The steaming process does not involve any additional acidic medium except saturated water vapor. The steamed bamboo slices are sent to the cooking equipment. The liquid condensed by steaming is pumped into kraft cooking to extract black liquor and enters the alkali recovery system together. The kraft cooking conditions of steamed bamboo chips are based on the absolute dry mass of bamboo chips before steaming, and the amount of alkali used is 22% of the amount of alkali used according to NaOH, the degree of sulfidation is 24%, the amount of anthraquinone is 0.3%, and the amount of surfactant 1.0%, the weight-to-liquid ratio 1: 3.5 including moisture in the bamboo chips after steaming, heat up 150min, maximum temperature 162°C, and keep warm for 180min to carry out kraft cooking according to the cooking curve.
[0033] After cooking, the good pulp that has been washed, se...
Embodiment 2
[0040] Repeat Example 1, with the following differences: the raw material used is Dalong bamboo, and the Dalong bamboo slices are sent into the steaming chamber and steamed for 15min at 135°C; the sulfate cooking NaOH consumption is 24%, the degree of sulfidation is 21%, the temperature rises for 180min, and the highest Temperature 165°C, heat preservation 160min; D1 stage ClO bleached by D1-Eop-D2 2 Dosage 1.25%, D2 segment ClO 2 Dosage 0.3%.
[0041] The results of cooking and pulping: the yield of fine pulp is 41.3%, the Kappa number is 9.2, and the degree of polymerization is 1080.
[0042] Oxygen desizing results: raw material yield 39.4%, kappa number 4.7, whiteness 51%, polymerization degree 830.
[0043] Results of bleached pulp: The yield of raw materials is 38.1%, the whiteness is 87%, and the degree of polymerization is 560.
[0044] Bamboo pulp standard test results: moisture 9.8%, viscosity 11.5mPa·s, first-class cellulose content 96.0%, ash content 0.07%, iron...
Embodiment 3
[0046] Repeat Example 1, the following differences are arranged: the raw material used is Julong bamboo, and the Julong bamboo slices are sent into the steaming chamber and steamed at 125°C for 25min; The temperature is 157°C and the temperature is kept for 240 minutes; the oxygen removal temperature is 95°C for 80 minutes. D1-P-D2 bleached P-stage pulp concentration 15%, H 2 o 2 Dosage 2.5%, NaOH dosage 1.8%, Na 2 SiO 3 Dosage 2.5%, MgSO 4 The dosage is 0.5%, the dosage of complex complexing agent is 0.3%, and the temperature is 80°C for 110min; D2 section ClO 2 Dosage 0.5%.
[0047] The results of cooking and pulping: the yield of fine pulp is 43.1%, the Kappa number is 12.7, and the degree of polymerization is 1180.
[0048] Oxygen desizing results: raw material yield 41.0%, kappa number 6.5, whiteness 47%, polymerization degree 900.
[0049] Results of bleached pulp: the yield of raw materials is 39.2%, the whiteness is 86%, and the degree of polymerization is 620. ...
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