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Acid-free pre-hydrolysis enzymolysis-free method for preparing bamboo pulp of Dendrocalamus giganteus Munro series

A technology of pre-hydrolysis and bamboo pulp, which is applied in the direction of pulping with inorganic alkali, pulp bleaching, water/steam pretreatment, etc., can solve the problems of restricting the development of pulp industry, low output, high refractory treatment, etc., and achieve clean The effect of chemical production

Inactive Publication Date: 2012-10-17
KUNMING UNIV OF SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The technical route of this process has two major drawbacks: high pollution load of acid prehydrolysis waste liquid, difficult to deal with and low pulp yield of only 1 / 3. Restricts the healthy development of the pulp industry to a large extent
Later, although people incorporated hemicellulose enzymatic technology to replace the acid prehydrolysis process to prepare pulp, the use of expensive hemicellulase could not change the backward status of the high-input, low-output pulp preparation industry.
To seek a low-pollution process and obtain high output at the same time is the goal that the pulp preparation industry has been pursuing for a long time. However, people have not yet made important and substantive breakthroughs in this area, which has also become a constraint. Bottleneck in pulp industry development

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Send the prepared Tianlong bamboo slices into the steaming chamber and steam at 130°C for 15 minutes. The steaming process does not involve any additional acidic medium except saturated water vapor. The steamed bamboo slices are sent to the cooking equipment. The liquid condensed by steaming is pumped into kraft cooking to extract black liquor and enters the alkali recovery system together. The kraft cooking conditions of steamed bamboo chips are based on the absolute dry mass of bamboo chips before steaming, and the amount of alkali used is 22% of the amount of alkali used according to NaOH, the degree of sulfidation is 24%, the amount of anthraquinone is 0.3%, and the amount of surfactant 1.0%, the weight-to-liquid ratio 1: 3.5 including moisture in the bamboo chips after steaming, heat up 150min, maximum temperature 162°C, and keep warm for 180min to carry out kraft cooking according to the cooking curve.

[0033] After cooking, the good pulp that has been washed, se...

Embodiment 2

[0040] Repeat Example 1, with the following differences: the raw material used is Dalong bamboo, and the Dalong bamboo slices are sent into the steaming chamber and steamed for 15min at 135°C; the sulfate cooking NaOH consumption is 24%, the degree of sulfidation is 21%, the temperature rises for 180min, and the highest Temperature 165°C, heat preservation 160min; D1 stage ClO bleached by D1-Eop-D2 2 Dosage 1.25%, D2 segment ClO 2 Dosage 0.3%.

[0041] The results of cooking and pulping: the yield of fine pulp is 41.3%, the Kappa number is 9.2, and the degree of polymerization is 1080.

[0042] Oxygen desizing results: raw material yield 39.4%, kappa number 4.7, whiteness 51%, polymerization degree 830.

[0043] Results of bleached pulp: The yield of raw materials is 38.1%, the whiteness is 87%, and the degree of polymerization is 560.

[0044] Bamboo pulp standard test results: moisture 9.8%, viscosity 11.5mPa·s, first-class cellulose content 96.0%, ash content 0.07%, iron...

Embodiment 3

[0046] Repeat Example 1, the following differences are arranged: the raw material used is Julong bamboo, and the Julong bamboo slices are sent into the steaming chamber and steamed at 125°C for 25min; The temperature is 157°C and the temperature is kept for 240 minutes; the oxygen removal temperature is 95°C for 80 minutes. D1-P-D2 bleached P-stage pulp concentration 15%, H 2 o 2 Dosage 2.5%, NaOH dosage 1.8%, Na 2 SiO 3 Dosage 2.5%, MgSO 4 The dosage is 0.5%, the dosage of complex complexing agent is 0.3%, and the temperature is 80°C for 110min; D2 section ClO 2 Dosage 0.5%.

[0047] The results of cooking and pulping: the yield of fine pulp is 43.1%, the Kappa number is 12.7, and the degree of polymerization is 1180.

[0048] Oxygen desizing results: raw material yield 41.0%, kappa number 6.5, whiteness 47%, polymerization degree 900.

[0049] Results of bleached pulp: the yield of raw materials is 39.2%, the whiteness is 86%, and the degree of polymerization is 620. ...

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Abstract

The invention relates to an acid-free pre-hydrolysis enzymolysis-free method for preparing bamboo pulp of dedrocalamus giganteus manro series, which comprises the following steps: dedrocalamus giganteus manro series raw material which is free from mildew and being damaged by worms is spliced and removed with the bamboo joint to be sent into a bamboo piece steaming cabin and to be steamed for 10 to 30 minutes at a low temperature without the acid medium; the steamed bamboo piece enters a boiling device to be cooked in sulfate to obtain the paper pulp which conforms to the quality requirement, the paper pulp is processed in the traditional procedures of washing, selection and screening to extract the black liquor which is recycled by adding alkaline, the pulp slag is mixed with conventionalpaper pulp boiling link or is ground to be sent into an alkaline furnace, and the good pulp is removed the lignin and is dissolved out the hemicelluous maximally within relevant set technological conditions according to the oxygen delignification, D1 - Eop - D2 or D1 - P - D2 blenching combination procedures so as to finally obtain the bamboo pulp. Not only the acid pre-hydrolysis or the high-temperature pre-hydrolysis procedures in the traditional preparation method of the bamboo pulp can be eliminated, but also the hemicelluous enzymolysis process with high cost can be prevented; moreover, the preparation rate of the bamboo pulp is improved to 38 to 39.7 percent, and the product consumption and the production cost can be obviously reduced while effectively ensuring the clean production.

Description

technical field [0001] The invention relates to a method for preparing dragon bamboo series bamboo pulp without acid prehydrolysis and without enzymatic hydrolysis. Background technique [0002] Pulp is a type of high-purity cellulose pulp with high cleanliness obtained from plant fiber raw materials through a series of lignin and semi-fiber treatments. As the most abundant natural renewable resource in nature, cellulose is inseparable from human social activities all the time. Especially in today's highly developed modern science and technology, cellulose and its derivative materials can penetrate almost everywhere. All-encompassing, such as rayon and rayon for textiles, cellophane, cellulose esters, cellulose ethers and other materials that are widely used are all based on pulp refined from plant fiber raw materials. [0003] As far as the classic technical route of pulp preparation is concerned, it mainly undergoes acid prehydrolysis of plant fiber raw materials to remov...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21C1/02D21C3/02D21C5/00D21C9/10
Inventor 陈克利黄睿周建国李荣杨李军王发荣
Owner KUNMING UNIV OF SCI & TECH
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