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Heavy oil processing combined process capable of using deasphalted oil efficiently

A technology of deasphalted oil and combined process, which is applied in the processing of tar asphalt/petroleum asphalt/natural asphalt, petroleum industry, and treatment of hydrocarbon oil, etc. It can solve the problems of increased yield of dry gas and coke, decreased yield of light oil, Low yield of high-grade road asphalt and other problems, to achieve the effect of reduced carbon residue and impurity content, high aromatic content, and good aging resistance

Inactive Publication Date: 2014-01-22
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This patent realizes the mutual supply of raw materials among the various devices, but it has three disadvantages: first, the deasphalted oil is directly used as the raw material of the catalytic cracking unit, which will reduce the light oil yield of the catalytic cracking unit, and produce dry gas and coke. The second is to mix some deoiled hard asphalt with topped light oil slurry for visbreaking to produce fuel oil, which is of low grade and poor benefit; the third is to use topped heavy oil slurry and deoiled hard asphalt to blend to produce roads Asphalt, easily affected by the properties of crude oil, the aging resistance of road asphalt is poor, and the yield of high-grade road asphalt is low
Since the extracted oil obtained from furfural refining of deasphalted oil is used as aromatic hydrocarbon rubber extension oil, it is not used to blend asphalt. Therefore, in essence, heavy traffic roads obtained by blending catalytic cracking oil slurry for solvent Asphalt still uses heavy oil slurry as a soft component, which does not solve the problem of poor aging resistance of road asphalt produced from deoiled asphalt

Method used

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  • Heavy oil processing combined process capable of using deasphalted oil efficiently
  • Heavy oil processing combined process capable of using deasphalted oil efficiently
  • Heavy oil processing combined process capable of using deasphalted oil efficiently

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] The properties of the vacuum residue of Zhongyuan, Tahe and Kaisajie mixed crude oil are as follows: figure 2 shown. Under the solvent deasphalting process conditions described in this embodiment, the properties of the obtained deasphalted oil 3 and deoiled hard asphalt 4 are shown in image 3 and Figure 4 . by image 3 The deasphalted oil 3 is used as the raw material of the deasphalted oil solvent extraction process 5, and the reverse contact with furfural in the extraction tower is carried out for liquid-liquid extraction, the extraction pressure is normal pressure (gauge pressure), and the extraction temperature is 70 °C , The agent-to-oil ratio (furfural / deasphalted oil) is 2.5:1 (by mass). Obtain extracted oil 6 and raffinate oil 7, its yield and properties are as Figure 5 and Figure 6 shown.

[0054] use Figure 5 The raffinate oil 7 in, the light oil slurry 11 in table 8, the vacuum gas oil and the atmospheric residue are mixed in the ratio of 24:3:5...

Embodiment 2

[0061] Under the solvent deasphalting process conditions described in this embodiment, the properties of the obtained deasphalted oil 3 and deoiled hard asphalt 4 are shown in Figure 12 and Figure 13 .

[0062] With deasphalted oil 3 in table 11 as the raw material of deasphalted oil solvent extraction process 5, carry out liquid-liquid extraction with furfural reverse contact in extraction tower, extraction pressure is 0.4Mpa (gauge pressure), extraction temperature The temperature is 80°C, and the agent-to-oil ratio (furfural / deasphalted oil) is 2.0:1 (mass). Obtain extracted oil 6 and raffinate oil 7, its yield and properties are as Figure 14 and Figure 15 shown.

[0063]With raffinate oil 7 in table 13, light oil slurry 11 in table 16, vacuum gas oil and atmospheric residue are mixed in the ratio of 23:2:56:19 (mass), as catalytic cracking process of the present invention The feed of 8; The deasphalted oil (as shown in table 2) of contrast test is directly used as...

Embodiment 3

[0070] Under the solvent deasphalting process conditions described in this embodiment, the properties of the obtained deasphalted oil 3 and deoiled hard asphalt 4 are shown in Figure 20 and Figure 21 .

[0071] The deasphalted oil 3 in Table 19 is used as the raw material of the deasphalted oil solvent extraction process 5, and N-methylpyrrolidone is reversely contacted in the extraction tower for liquid-liquid extraction, and the extraction pressure is 0.8MPa (gauge pressure) , the extraction temperature is 80°C, and the agent-oil ratio (N-methylpyrrolidone / deasphalted oil) is 2.0:1 (by mass). Obtain extracted oil 6 and raffinate oil 7, its yield and properties are as Figure 22 and Figure 23 shown.

[0072] With raffinate oil 7 in table 21, light oil slurry 11 in table 24, vacuum gas oil and atmospheric residue are mixed in the ratio of 20:4:50:26 (mass), as catalytic cracking process of the present invention The feed of 8; the deasphalted oil (such as figure 2 sho...

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Abstract

The invention discloses a heavy oil processing combined process capable of using deasphalted oil efficiently, which takes a deasphalted oil solvent extraction process as key technology and organically combines a solvent deasphalting process, a catalytic cracking process, a catalytic cracking oil slurry topping process and an asphalt blending process together to realize the mutual raw material supply and optimization among the processes. The heavy oil processing combined process capable of using the deasphalted oil efficiently effectively solves the problem of the application of deoiled hard asphalt generated in the solvent deasphalting process and improves the operating rate of the solvent deasphalting process. Extract oil which is prepared from low-priced deoiled hard asphalt and catalytic cracking oil slurry by using a solvent extraction process is used for preparing high-grade road asphalt products with a high additional value, so that the rationality and flexibility of the heavy oil processing and the entire economic benefits of the heavy oil processing are improved.

Description

technical field [0001] The invention belongs to the technical field of petrochemical industry and relates to a heavy oil processing combined process for efficiently utilizing deasphalted oil. Background technique [0002] Solvent deasphalting process is an important residue decarbonization process, which uses light hydrocarbon solvents to separate the components in atmospheric residue and / or vacuum residue with different solubility under certain conditions. Selectively remove harmful substances such as asphaltenes and heavy metals in residual oil, and obtain deasphalted oil with low metal and carbon residue as raw material for catalytic cracking or other devices, and also obtain a part of oil with high softening point and low penetration deoiled hard asphalt. For the solvent deasphalting process, obtaining high-quality, high-yield deasphalted oil is a universally pursued goal. However, the yield of deasphalted oil and deoiled hard asphalt is always a pair of contradictions....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G55/00C10C3/00
Inventor 赵振辉曹发海任满年况成承杨书显应卫勇张锋黄建林董力军齐文瑞田英爱杨萍杜瑞华况敏梁晓斌
Owner CHINA PETROLEUM & CHEM CORP
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