Solar cell manufacturing process for blocking back diffusion by using mask

A solar cell and manufacturing process technology, applied in sustainable manufacturing/processing, circuits, electrical components, etc., can solve problems such as poor electrical performance of cells, insufficient etching, and decreased cell efficiency, to avoid cell damage and The effect of reducing the efficiency, preventing the short circuit of the upper and lower electrodes of the silicon wafer, and improving the photoelectric efficiency

Inactive Publication Date: 2010-11-24
山东力诺太阳能电力股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The plasma dry etching process is to etch the periphery of the silicon wafer through the alternating action of fluorine and oxygen under the condition of glow discharge. In essence, it is a kind of damage to the silicon wafer, which is easy to cause defects such as edge chipping and missing corners. In addition, plasma etching is prone to insufficient etching or excessive etching. The so-called insufficient etching means that the edge PN junction is not completely removed, which will cause poor electrical performance of the cell due to edge leakage.
The so-called excessive etching means that after the PN junction is removed, the etching is continued, so that the etching amount of the silicon wafer is relatively large, especially the etching amount on the front side (light-absorbing surface) of the battery is large, and the PN junction on the front side is destroyed, resulting in a relatively large loss of photocurrent. Large, so that the efficiency of th

Method used

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Embodiment 1

[0021] The present invention is a process for making a silicon nitride mask to block back diffusion

[0022] After the texturing step is completed, a silicon nitride mask is fabricated on the back of the silicon wafer by plasma-enhanced chemical vapor deposition (PECVD). The reaction gas is silane and ammonia, and the reaction gas is introduced according to the volume ratio of 1:10. Control at 200Pa, power 2800W, time 900s, mask thickness 80nm, and then enter the diffusion furnace for diffusion. After the diffusion, use 5-10% HF solution to clean the silicon wafer for 10-15 minutes to remove the phosphosilicate glass ( PSG) and silicon dioxide mask, and then go through steps such as anti-reflection coating on the front of the silicon wafer, screen printing, etc., testing and sorting to obtain finished cells.

Embodiment 2

[0024] The present invention is a process for making a silicon nitride mask to block back diffusion

[0025] After the texturing step is completed, a silicon nitride mask is made on the back of the silicon wafer by plasma enhanced chemical vapor deposition (PECVD). The reaction gases are silane, ammonia and nitrogen, which are injected according to the volume ratio of 1:3:3. The reaction gas, the pressure is controlled at 60Pa, the power is 1800W, the time is 200s, the thickness of the mask is 80nm, and then enters the diffusion furnace for diffusion. After the diffusion, use 5-10% HF solution to clean the silicon wafer for 10-15 minutes, remove Phospho-silicate glass (PSG) and silicon dioxide mask, and then through the steps of anti-reflection coating on the front of the silicon wafer, screen printing and other steps, detection and sorting to obtain finished cells

Embodiment 3

[0027] The present invention is a process for making a silicon dioxide mask to block back diffusion

[0028] After the texturing step is completed, a silicon dioxide mask is made on the back of the silicon wafer by plasma-enhanced chemical vapor deposition (PECVD), and the reaction gas is silane and nitrous oxide to make a silicon dioxide mask with a thickness of 120 nanometers, and then Enter the diffusion furnace for diffusion. After the diffusion, use 5% HF solution to clean the silicon wafer for 4 minutes, remove the phosphosilicate glass (PSG) and silicon dioxide mask, and then coat the front of the silicon wafer with an anti-reflective coating and screen printing. After the steps, detection and sorting are performed to obtain finished battery sheets.

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Abstract

The invention belongs to the field of solar cell manufacturing processes, in particular relates to a solar cell manufacturing process for blocking back diffusion by using a mask. Before a silicon chip is diffused, a silicon dioxide or silicon nitride mask is prepared on the back side of the silicon chip, and a back side mask before diffusion prevents the formation of PN junctions on the back side in a silicon chip diffusion process, so that the problem of short circuits of upper and lower electrodes of the silicon chip can be solved directly, and edge and back side etching processes after diffusion can be eliminated. Therefore, losses such as cell damage, efficiency reduction and the like caused by edge etching are avoided. Moreover, passivation effect can be acted on the back side of the silicon chip when the back side of the silicon chip is masked, so that the photoelectric efficiency of a solar cell can be improved effectively, and the process is suitable for industrial production.

Description

technical field [0001] The invention belongs to the field of solar cell production technology, and in particular relates to a solar cell production process in which a mask blocks back diffusion. Background technique [0002] The traditional manufacturing process of solar cells is roughly divided into several steps such as texturing, diffusion, etching, dephosphorous silicon glass, anti-reflection coating, and screen printing. [0003] In the existing process of diffusing solar cells, a diffusion layer, ie, a PN junction, is inevitably formed on the periphery and the back edge of the silicon wafer. The diffusion layer on the periphery and the back edge makes the upper and lower electrodes of the battery form a short circuit. Any small local short circuit on the periphery will reduce the parallel resistance of the battery, increase the reverse current, and reduce the overall electrical performance of the solar cell. The surrounding PN junctions must be removed to avoid short ...

Claims

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Application Information

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IPC IPC(8): H01L31/18
CPCY02P70/50
Inventor 姜言森刘鹏李玉花杨青天焦云峰任现坤孙晨曦
Owner 山东力诺太阳能电力股份有限公司
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