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Method for removing algae and microcystin from raw water in water plant

A microcystin and raw water technology, applied in chemical instruments and methods, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc., can solve the problems of poor water treatment effect, hysteresis of biodegradation, Low efficiency and other problems, to achieve the effect of high practicability, low price and high safety

Inactive Publication Date: 2012-07-25
INST OF AQUATIC LIFE ACAD SINICA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Physical methods have the disadvantages of low efficiency and high cost; chemical oxidation can quickly remove algal toxins in water, but there are usually secondary pollution problems; there are Adda groups in microcystins, which can be effectively degraded by microorganisms, but biodegradation has a certain hysteresis
On the other hand, the traditional water treatment process mainly focuses on the removal of suspended and colloidal substances, and the turbidity, color and total number of bacteria in the effluent are the main indicators of process control. Although the treatment effect is better for source water with low algae content , but the water treatment effect is not good for water sources with high algae content

Method used

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  • Method for removing algae and microcystin from raw water in water plant
  • Method for removing algae and microcystin from raw water in water plant
  • Method for removing algae and microcystin from raw water in water plant

Examples

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Effect test

Embodiment 1

[0021] A method for removing algae and microcystins in raw water of a waterworks, the steps of which are:

[0022] 1) Filling film at water source 1: Place the selected carrier filler (ZH plastic suspension packing of Φ10×10~20mm) in the water source, and cultivate it in a natural state for 30 or 35 or 40 or 44 or 48 or 52 or 56 or 60 days, transferred to biofilm reactor (biofilm reactor preparation is very easy, those skilled in the art can prepare, biofilm reactor inner diameter is 300-1000mm, high 1000-2000mm), raw water operation 1 or 2 or 3d make the system stable.

[0023] 2) Biofilm reactor treatment 2: use the biofilm in the biofilm reactor (inner diameter 300-1000mm, height 1000-2000mm) to intercept algae cells and the feeding effect of micro-animals in the biofilm to remove algae in the water; Degradation by microorganisms in the membrane removes soluble microcystins. When the chlorophyll a in the raw water is 100 or 110 or 125 or 135 or 145 or 150 μg / L, and the hy...

Embodiment 2

[0032] Microcystins are intracellular toxins. The treatment technology of microcystins in water should not only consider the removal of soluble algal toxins, but more importantly, effectively remove algal cells containing algal toxins. In the above examples, after adding 22.5-45.75 μg / L MC crude extract to the raw water, the concentration of soluble MC in the effluent water is less than 1.0 μg / L, and it can be seen that the removal rate of soluble MC by the biofilm reactor can reach more than 99%. However, the effluent still contains many algae cells, so the removal rate of total toxins is only 86.3%, and the concentration of total toxins is still greater than 1.0 μg / L, which poses a certain threat to the health of drinking water. In order to improve the removal rate of Microcystis by biofilm reactor, oleic acid, which has obvious allelopathic inhibitory effect on Microcystis, was selected to enhance the treatment efficiency of biofilm reactor. The specific steps are: soak the...

Embodiment 3

[0034] There are several stages in the growth of biofilm, such as adaptation, attachment, growth, shedding, and stabilization. In order to ensure the treatment effect of the system on the raw water during the biofilm shedding stage, and to prevent the shedding biofilm from entering the subsequent treatment process, a sedimentation tank (inner diameter: 300mm height: 1000mm) and an activated carbon treatment system (inner diameter: 300mm, 1000mm high, filled with Φ2-3mm, high: 4-8mm granular activated carbon). Activated carbon is used to further treat residual pollutants and small molecular substances in the effluent water of the biofilm reactor. Under the condition that the residence time is 3 hours, the effluent treated by the activated carbon column can meet or exceed the Hygienic Standard for Drinking Water (GB5749-2006).

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Abstract

The invention discloses a method for removing algae and microcystin from raw water in a water plant. The method comprises the following steps of: A, biofilm culturing of fillers: placing selected carrier fillers in a water source site, culturing and transferring to a biofilm reactor; B, treatment through the biofilm reactor: removing algae in water by utilizing the interception effect of a biofilm in the biofilm reactor to algae cells and the ingestion effect of microfauna in the biofilm; C, regulation and control and treatment through oleic acid: regulating and controlling the removal effectof the biofilm reactor to the microcystin by using the oleic acid so as to improve the removal rate of the biofilm reactor to the algae cells; D, treatment through a sedimentation tank; and E, treatment through activated carbon: treating effluent water of the biofilm reactor through the sedimentation tank and thoroughly removing incompletely-degraded microcystin by utilizing the strong adsorptioneffect of the activated carbon so that the effluent water reaches the sanitary standard for drinking water in China. The method for removing algae and microcystin from the raw water in the water plant can be used for effectively removing the microcystin and is highly-efficient, economic, simple and feasible; and by means of the method, the removal rate of the algae cells reaches 90-95 percent, and the microcystin removal ratio reaches 95-100 percent.

Description

technical field [0001] The invention relates to the technical field of drinking water treatment, in particular to a method for removing algae and microcystins in raw water of a waterworks, and is especially suitable for water sources polluted by the growth and reproduction of cyanobacteria. Background technique [0002] China's water environment pollution is becoming more and more serious, and the drinking water safety problems caused by it are increasing day by day. Among them, frequent cyanobacterial blooms have become the main environmental disaster of water eutrophication. China's cyanobacterial blooms are mainly produced by microcystin (microcystin, MC) microcystin. Microcystins have been detected in reservoirs one after another. The survey showed that the primary liver cancer of the residents in the southeast coastal areas of China and the Suiyuan area of ​​Guangxi was closely related to the microcystin content in drinking water sources. More than a dozen countries ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/14
Inventor 肖邦定黄建团
Owner INST OF AQUATIC LIFE ACAD SINICA